全文获取类型
收费全文 | 762篇 |
免费 | 36篇 |
国内免费 | 4篇 |
专业分类
化学 | 624篇 |
晶体学 | 7篇 |
力学 | 9篇 |
数学 | 96篇 |
物理学 | 66篇 |
出版年
2023年 | 4篇 |
2022年 | 17篇 |
2021年 | 21篇 |
2020年 | 26篇 |
2019年 | 17篇 |
2018年 | 13篇 |
2017年 | 10篇 |
2016年 | 32篇 |
2015年 | 37篇 |
2014年 | 20篇 |
2013年 | 39篇 |
2012年 | 50篇 |
2011年 | 61篇 |
2010年 | 39篇 |
2009年 | 28篇 |
2008年 | 39篇 |
2007年 | 51篇 |
2006年 | 41篇 |
2005年 | 37篇 |
2004年 | 32篇 |
2003年 | 29篇 |
2002年 | 18篇 |
2001年 | 9篇 |
2000年 | 13篇 |
1999年 | 16篇 |
1998年 | 10篇 |
1997年 | 10篇 |
1996年 | 10篇 |
1995年 | 3篇 |
1994年 | 3篇 |
1993年 | 5篇 |
1992年 | 6篇 |
1990年 | 6篇 |
1989年 | 10篇 |
1988年 | 5篇 |
1987年 | 3篇 |
1986年 | 4篇 |
1985年 | 4篇 |
1984年 | 3篇 |
1983年 | 2篇 |
1982年 | 5篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1979年 | 3篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1973年 | 2篇 |
1923年 | 1篇 |
排序方式: 共有802条查询结果,搜索用时 15 毫秒
91.
Regina Kleine 《Results in Mathematics》1989,15(1-2):81-103
92.
We investigate the tail behavior of the sojourn-time distribution for a request of a given length in an M/G/1 Processor-Sharing
(PS) queue. An exponential asymptote is proven for general service times in two special cases: when the traffic load is sufficiently
high and when the request length is sufficiently small. Furthermore, using the branching process technique we derive exact
asymptotics of exponential type for the sojourn time in the M/M/1 queue. We obtain an equation for the asymptotic decay rate
and an exact expression for the asymptotic constant. The decay rate is studied in detail and is compared to other service
disciplines. Finally, using numerical methods, we investigate the accuracy of the exponential asymptote.
AMS 2000 Subject Classifications Primary:60K25,Secondary: 60F10,68M20,90B22 相似文献
93.
Semiempirical molecular orbital calculations for the porphyrins tetrakis(4-N-methyl pyridyl)porphine (H2TMpyP-4) and tetrakis(2-N-methyl pyridyl)porphine using the MNDO and AM -1 Hamiltonians suggest that twisting one or more of the pyridinium rings results, at considerable energy expense, in highly nonplanar macrocycle configurations as the exocyclic ring(s) approach coplanarity. The results imply that the mechanism of intercalation of H2TMpyP-4 into DNA cannot require twisting the exocyclic rings anywhere close to coplanarity with the central porphine core, but involves, instead, the inherent flexibility of DNA itself. © 1993 John Wiley & Sons, Inc. 相似文献
94.
Summary The technical PCB mixtures Aroclor 1242, Aroclor 1254 and Aroclor 1260 have been analyzed by capillary gas chromatography using the new methyl n-octylpolysiloxane phase (SB-Octyl 50) with electron capture- and mass-selective detection. The selectivity of this new stationary phase in the separation of PCB is superior to that of the methyl-polysiloxanes. A pronounced separation according to the out-of-plane orientation of the PCB congeners is observed.
Kongeneren-spezifische Identifizierung der technischen PCB-Gemische durch HRGC/ECD und HRGC/MSD mit einer n-Octyl-methyl-silicon-Phase相似文献
95.
Regina Aragn 《Mathematical Logic Quarterly》1995,41(4):485-504
We consider the theory Thprin of Boolean algebras with a principal ideal, the theory Thmax of Boolean algebras with a maximal ideal, the theory Thac of atomic Boolean algebras with an ideal where the supremum of the ideal exists, and the theory Thsa of atomless Boolean algebras with an ideal where the supremum of the ideal exists. First, we find elementary invariants for Thprin and Thsa. If T is a theory in a first order language and α is a linear order with least element, then we let Sentalg(T) be the Lindenbaum-Tarski algebra with respect to T, and we let intalg(α) be the interval algebra of α. Using rank diagrams, we show that Sentalg(Thprin) ? intalg(ω4), Sentalg(Thmax) ? intalg(ω3) ? Sentalg(Thac), and Sentalg(Thsa) ? intalg(ω2 + ω2). For Thmax and Thac we use Ershov's elementary invariants of these theories. We also show that the algebra of formulas of the theory Tx of Boolean algebras with finitely many ideals is atomic. 相似文献
96.
Ana C.D. Midões Pedro E. Aranha Mirian P. dos Santos Érica Tozzo Sandra Romera Regina H. de A. Santos Edward R. Dockal 《Polyhedron》2008
The crystal structure, spectroscopic properties and catalytic property of the copper(II) complex, prepared by the reaction between copper(II) diacetate with the bidentate Schiff base, SalAHE (SalAHE = salicylaldehydeimine-1-hydroxyethane), are reported. This complex is able to oxidize 3,5-di-tert-butylcatechol to the respective o-quinone. The oxidation reaction was studied in CH3CN with molecular oxygen at 0, 5, 15 and 25 °C. The progress of the catalytic reaction was followed by gas chromatographic analyses (GC). 相似文献
97.
J. Henrique Teles Johann-Peter Melder Klaus Ebel Regina Schneider Eugen Gehrer Wolfgang Harder Stefan Brode Dieter Enders Klaus Breuer Gerhard Raabe 《Helvetica chimica acta》1996,79(1):61-83
Stable carbenes derived from thiazole, 1H-imidazole, and 4H-1,2,4-triazole are efficient catalysts for benzointype condensations of formaldehyde. Catalysts derived from N-substituted thiazolium salts trimerize formaldehyde to dihydroxyacetone ( II ). Catalysts based on 1,4-disubstituted 4H-1,2,4-triazol-1-ium salts give glycolaldehyde ( I ) as the main product and no II , whereas N,N′-disubstituted 1H-imidazol-3-ium salts yield mixtures of both products. The isolation of several intermediates in the catalytic cycle provide a better insight into the reaction mechanism. 相似文献
98.
Regina C. Elandt-Johnson 《Journal of multivariate analysis》1978,8(2):244-254
We call a set of univariate distributions with the same mathematical form but different parameter values a family . Consider a bivariate Gumbel Type A survival distribution, S12(x1, x2), defined in (2.1), for which both marginal distributions, S1(x1), S2(x2), belong to the same family, of distributions. It is proved in this paper that subject to weak conditions, the crude hazard rates, h1(t) and h2(t), are proportional if and only if the marginal hazard rates, λ1(t) and λ2(t), are proportional (Theorem 1). It is also shown that the survival functions of W = min(X1, X2), and of the identified minimum, Wi = Xi, for Xi < Xj, j ≠ i, belong to the same family as do S1(x1), S2(x2) (Corollary 1). Counter-examples of distributions other than Gumbel Type A, for which these properties do not hold, are given. Some applications to the analysis of competing risks, using a family of Gompertz distributions, are discussed. 相似文献
99.
100.
Regina Kühn Volker Luckow und Doris Keppeler 《Fresenius' Journal of Analytical Chemistry》1984,317(6):668-669
Ohne Zusammenfassung
Capillary gas-chromatographic determination of glycerol trinitrate in plasma相似文献