基于OpenFOAM的投影法磁流体求解器开发与验证

在开源计算流体力学C++工具包OpenFOAM环境下开发了低磁雷诺数条件下的磁流体求解器,并进行了验证。采用投影算法求解动量方程和压力泊松方程;采用非结构网格同位相容守恒算法求解电势泊松方程、感应电流和洛伦兹力;采用边界耦合方法求解流固耦合电势场。通过对均匀磁场下导电方管和导电圆管内的完全发展磁流体层流的数值模拟和解析解的对比,对求解器进行了验证。进一步对非均匀强磁场作用下导电方管和导电圆管内完全发展磁流体层流进行了数值模拟,并与ALEX实验结果进行了比较。数值解和实验结果吻合良好。所开发的求解器可用于复杂结构强磁场作用下磁流体的数值模拟研究。     

Synthesis of onio-, dionio-, and trionio-substituted phosphines; the nucleophilic behavior of DBN and DBU toward main group electrophiles

1,5-Diazabicyclo[4.3.0]non-5-ene (DBN) and 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) react with chloro- and dichloro-phosphines leading to onio- and dionio-substituted phosphines. Similarly, onio-substituted silicon and tin derivatives are prepared; they are used as onio-substituent transfer reagents in the synthesis of a trionio-substituted phosphine.     

ChemInform Abstract: Tetrakis(tetramethylammonium) Tricarbonatodioxidouranate Octahydrate.

Single crystals of (Me₄N)₄ [UO₂(CO₃)₃]·8H₂O are grown by slow evaporation (25 °C, 6 weeks) of an aqueous solution of uranyl 1‐hydroxyethane‐1,1‐diphosphonate and Me₄NOH.     

Monitoring kinetic processes in polymer solutions with time dependent static light scattering (TDSLS)

An overview of recent developments in TDSLS and auxiliary techniques is given. This includes background theory, and examples of results and applications for online monitoring of polymerization reactions, kinetics and structural determinations from degrading polymers, aggregation, and dissolution of dry polymer powders. Also, automatic dilution techniques allow for continuous characterization of the equilibrium states of multi-component solutions. Illustrations are given for the case where the change in polyelectrolyte dimensions, interactions and hydrodynamics can be probed.