全文获取类型
收费全文 | 626篇 |
免费 | 7篇 |
国内免费 | 8篇 |
专业分类
化学 | 340篇 |
晶体学 | 2篇 |
力学 | 30篇 |
数学 | 66篇 |
物理学 | 203篇 |
出版年
2018年 | 6篇 |
2016年 | 6篇 |
2015年 | 7篇 |
2014年 | 11篇 |
2013年 | 32篇 |
2012年 | 24篇 |
2011年 | 33篇 |
2010年 | 27篇 |
2009年 | 27篇 |
2008年 | 38篇 |
2007年 | 26篇 |
2006年 | 27篇 |
2005年 | 22篇 |
2004年 | 27篇 |
2003年 | 21篇 |
2002年 | 18篇 |
2001年 | 11篇 |
2000年 | 18篇 |
1999年 | 6篇 |
1998年 | 6篇 |
1997年 | 7篇 |
1996年 | 12篇 |
1995年 | 7篇 |
1994年 | 5篇 |
1993年 | 9篇 |
1992年 | 11篇 |
1991年 | 15篇 |
1990年 | 14篇 |
1989年 | 8篇 |
1988年 | 7篇 |
1987年 | 6篇 |
1986年 | 5篇 |
1984年 | 11篇 |
1983年 | 5篇 |
1981年 | 9篇 |
1980年 | 11篇 |
1979年 | 8篇 |
1978年 | 6篇 |
1977年 | 7篇 |
1976年 | 12篇 |
1975年 | 7篇 |
1974年 | 3篇 |
1973年 | 5篇 |
1972年 | 4篇 |
1971年 | 3篇 |
1970年 | 3篇 |
1968年 | 3篇 |
1967年 | 3篇 |
1935年 | 3篇 |
1933年 | 4篇 |
排序方式: 共有641条查询结果,搜索用时 0 毫秒
621.
Bjerring Thomas Trier Rasmussen Kourosh Marjani Weissensteiner Alex 《Computational Management Science》2018,15(2):139-159
Computational Management Science - We investigate whether the returns of some industry portfolios predict the returns of other industry portfolios. We find a strong lead-lag structure which is... 相似文献
622.
Lars Eilstrup Rasmussen 《Random Structures and Algorithms》1997,11(4):395-411
We present a very simple, randomized approximation algorithm for determining the number of cliques in a random graph. © 1997 John Wiley & Sons, Inc. Random Struct. Alg., 11 , 395–411 (1997) 相似文献
623.
Nils Henry Williams Rasmussen 《Archiv der Mathematik》2011,97(2):135-140
We give a geometric construction of sub-linear systems on a K3 surface consisting of smooth curves C with infinitely many ${g^1_{{\rm gon}(C)}}$ ??s. 相似文献
624.
A three-step synthesis of the norneolignan skeleton involving the Carroll rearrangement as the key step has been developed and used for synthesis of the norneolignan skeleton, 1,3-diphenylpenta-1,4-diene and hinokiresinol. 相似文献
625.
Rasmussen SB Bañares MA Bazin P Due-Hansen J Ávila P Daturi M 《Physical chemistry chemical physics : PCCP》2012,14(7):2171-2177
A monolithic vanadia-titania based catalyst has been subjected to studies with in situ FTIR spectroscopy coupled with mass spectrometry, during the SCR (Selective Catalytic Reduction) reaction. A device based on a transmission reactor cell for monolithic samples was constructed, dedicated to the study of surface species during reaction. After analysing the steady state SCR activity under industrially relevant conditions, NH(3) chemisorption phenomena as a function of temperature and the subsequent SCR reaction of NO + O(2) with chemisorbed ammonia and ammonium ion species were also investigated. The observations reported here serve as a demonstration of the great potential for the application of operando spectroscopy on monolithic systems. This cross disciplinary approach aims to identify reaction pathways, active sites, intermediate- and spectator-species for catalytic reactions under truly industrial conditions in a shaped monolithic catalyst based on monitoring chemical profiles along its channels. In particular, by demonstrating the feasibility of the approach using the technically challenging operando transmission FTIR spectroscopy methodology, we foresee easy future adaption of this approach with other surface or bulk sensitive techniques, e.g. Raman and UV-vis spectroscopy. 相似文献
626.
GY Gor CJ Rasmussen AV Neimark 《Langmuir : the ACS journal of surfaces and colloids》2012,28(33):12100-12107
The mechanisms of hysteretic phase transformations in fluids confined to porous bodies depend on the size and shape of pores, as well as their connectivity. We present a Monte Carlo simulation study of capillary condensation and evaporation cycles in the course of Lennard-Jones fluid adsorption in the system of overlapping spherical pores. This model system mimics pore shape and connectivity in some mesoporous materials obtained by templating cubic surfactant mesophases or colloidal crystals. We show different mechanisms of capillary hysteresis depending on the size of the window between the pores. For the system with a small window, the hysteresis cycle is similar to that in a single spherical pore: capillary condensation takes place upon achieving the limit of stability of adsorption film and evaporation is triggered by cavitation. When the window is large enough, the capillary condensation shifts to a pressure higher than that of the isolated pore, and the possibility for the equilibrium mechanism of desorption is revealed. These finding may have important implications for practical problems of assessment of the pore size distributions in mesoporous materials with cagelike pore networks. 相似文献
627.
Vanadium complex of 2-(2'-Pyridyl)-4,5-dicyanoimidazole showing spermicidal and cytotoxic properties
Less GB Ockwig NW Rasmussen PG Smith GD Keller LM Drach JC 《Inorganic chemistry》2006,45(18):7105-7110
Two complexes having the formulas VO(DCIPy)2(H2O).1.5H2O and VO(DCIPy)2(H2O).2MeOH have been synthesized and characterized (DCIPy = 2-(2'-pyridyl)-4,5-dicyanoimidazolato). The methanol solvated species has been studied by X-ray diffraction, and single crystals form in the space group P2(1)/n. The hydrated species was studied by electron paramagnetic resonance spectroscopy in both the solid state and in a frozen solution, and the values of A( parallel) examined using the additivity relationship. The hydrated species was shown to exhibit both spermicidal and cytoxic properties. 相似文献
628.
Since 1999, substantial research has been devoted to the development of liquid-phase microextraction (LPME) based on porous hollow fibers. With this technology, target analytes are extracted from aqueous samples, through a thin supported liquid membrane (SLM) sustained in the pores in the wall of a porous hollow fiber, and further into a microL volume of acceptor solution placed inside the lumen of the hollow fiber. After extraction, the acceptor solution is directly subjected to a final chemical analysis by liquid chromatography (HPLC), gas chromatography (GC), capillary electrophoresis (CE), or mass spectrometry (MS). In this review, LPME will be discussed with focus on extraction principles, historical development, fundamental theory, and performance. Also, major applications have been compiled, and recent forefront developments will be discussed. 相似文献
629.
We study the linear elastic response of multiblock copolymer melts in the lamellar phase, where the molecules are composed of tethered symmetric AB diblock copolymers. We use a self-consistent field theory method, and introduce a real space approach to calculate the tensile and shear moduli as a function of block number. The former is found to be in qualitative agreement with experiment. We find that the increase in bridging fraction with block number, that follows the increase in modulus, is not responsible for the increase in modulus. It is demonstrated that the change in modulus is due to an increase in mixing of repulsive A and B monomers. Under extension, this increase originates from a widening of the interface, and more molecules pulled free of the interface. Under compression, only the second of these two processes acts to increase the modulus. 相似文献
630.
The properties of reduced rutile TiO2(110) surfaces, as well as the adsorption, diffusion, and dissociation of molecular oxygen are investigated by means of density functional theory. The O2 molecule is found to bind strongly to bridging oxygen vacancies, attaining a molecular state with an expanded O-O bond of 1.44 A. The molecular oxygen also binds (with somewhat shortened bond lengths) to the fivefold coordinated Ti atoms in the troughs between the bridging oxygen rows, but only when vacancies are present somewhere in the surface. In all cases, the magnetic moment of O2 is lost upon adsorption. The expanded bond lengths reveal together with inspection of electron density and electronic density of state plots that charging of the adsorbed molecular oxygen is of key importance in forming the adsorption bond. The processes of O2 diffusion from a vacancy to a trough and O2 dissociation at a vacancy are both hindered by relative large barriers. However, we find that the presence of neighboring vacancies can strongly affect the ability of O2 to dissociate. The implications of this in connection with diffusion of the bridging oxygen vacancies are discussed. 相似文献