Study of slag content and properties after plasma melting of incineration ash

The paper presents the investigation of plasma melting of the mixed bottom and fly incineration ash at various mixing ratios of the components. Chemical compound of the bottom and fly ash as well as the slag after its melting was analyzed by different methods, and the content of toxic components in them was determined. It is demonstrated that the direct disposal of the fly and bottom incineration ash may cause dioxin and heavy metal contamination of the environment. The influence of melted ash basicity on the resulting slag compound was studied. The mass balance of the melting process was defined. The tests were performed to determine the heavy-metals leaching from the ash and slag. It is also shown that the slag after plasma melting is dioxin-free and environmentally friendly.     

Low-threshold singly-resonant continuous-wave optical parametric oscillator based on MgO-doped PPLN

We present a 532 nm-pumped singly-resonant cw optical parametric oscillator based on MgO-doped PPLN with a minimum threshold pump power of 0.3 W. The OPO with a two-mirror standing-wave cavity is optimized by using a tunable diode laser on the path of the resonant signal beam. The maximum output power is 200 mW at an idler wavelength near 1330 nm at a pump power of 2 W. We report the degradation of the output power and beam characteristics at high pump power indicating a strong thermal lensing in the crystal. The continuous tuning range of the OPO is measured to be 800 MHz which is close to 90% of the free spectral range of the OPO cavity.     

Suppression of samarium diffusion in top seeded melt growth processed Y123 superconductors using a Sm123 seed

To suppress the samarium diffusion from a SmBa₂Cu₃O_7?y (Sm123) seed into an YBa₂Cu₃O_7?y (Y123) compact during a top seeded melt growth (TSMG) process, Y211 buffer disks of various thicknesses (t) were inserted at the seed/compact interface. The effectiveness of the Y211 buffer insert on the suppression of samarium diffusion was estimated from the susceptibility curve and composition analysis for the three top surface regions (region just below the seed/buffer, intermediate region between the buffer and compact edge and compact edge). The difference in the superconducting temperature (T_c) and the superconducting transition width (ΔT) in the three regions was large, when no buffer or thin buffers (t is smaller than 1 mm) were used. As a buffer disk of an appropriate thickness was inserted into the seed/compact interface, the difference in T_c and ΔT in the three regions was much reduced. The composition analysis across the seed/buffer/compact region clearly revealed that the T_c decrease was caused by the samarium diffusion from a seed, which led to the formation of Y_1?xSm_xBa₂Cu₃O_7?y in the Y123 compact region. The buffer insert technique was demonstrated to insure the uniform superconducting properties of the top surface of TSMG processed Y123 superconductors.     

Effects of calcium doping on the superconducting properties of top-seeded melt growth processed Y1.5Ba2−xCaxCu3Oy superconductors

The effect of calcium doping on the superconducting properties of top seeded melt growth (TSMG) processed Y_1.5Ba_2?xCa_xCu₃O_y superconductors was studied in terms of calcium content (X_ca). YBa_2?xCa_xCu₃O_7?δ (X_ca = 0, 0.005, 0.01, 0.02, 0.04, 0.1, 0.3) powders were synthesized by the powder calcination method. YBa_2?xCa_xCu₃O_7?δ powders were mixed with 0.25 mole Y₂O₃ powder and 1 wt.% CeO₂ as Y₂BaCuO₅ (Y211) refiner, and finally made into Y₁.₅Ba_2?xCa_xCu₃O_y (Y1.5) + 1 wt.% CeO₂ composition. The single Y123 growth on the top surface was observed up to X_ca = 0.1, while the multiple Y123 growth was observed at X_ca ? 0.1. The superconducting transition temperature (T_c) and critical current density (J_c) of TSMG processed Y1.5 samples were inversely proportional to X_ca. The Y211 size increased with increasing X_ca due to the enhancement of Y211 coarsening by calcium doping. No Y211 refining effect by CeO₂ was observed in the calcium doped samples. The T_c and J_c decrease by calcium doping are likely to be due to the calcium incorporation with the Y123 lattice and formation of coarse Y211 particles.     

Thermal conductivity of VLS-grown rough Si nanowires with various surface roughnesses and diameters

In this paper, we synthesize VLS-grown rough Si nanowires using Mn as a catalyst with various surface roughnesses and diameters and measured their thermal conductivities. We grew the nanowires by a combination vapor-liquid-solid and vapor-solid mechanism for longitudinal and radial growth, respectively. The surface roughness was controlled from smooth up to about 37 nm by the radial growth. Our measurements showed that the thermal conductivity of rough surface Si nanowires is significantly lower than that of smooth surface nanowires and decreased with increasing surface roughness even though the diameter of the smooth nanowire was lower than that of the rough nanowires. Considering both nanowires were grown via the same growth mechanism, these outcomes clearly demonstrate that the rough surface induces phonon scattering and reduces thermal conductivity with this nanoscale-hole-free nanowires. Control of roughness induced phonon scattering in Si nanowires holds promise for novel thermoelectric devices with high figures of merit.     

Characterization of mitochondria isolated from normal and ischemic hearts in rats utilizing atomic force microscopy

Mitochondria play critical roles in both the life and the death of cardiac myocytes. Various factors, such as the loss of ATP synthesis and increase of ATP hydrolysis, impairment in ionic homeostasis, formation of reactive oxygen species (ROS), and release of proapoptotic proteins are related to the generation of irreversible damage. It has been proposed that the release of cytochrome c is caused by a swelling of the mitochondrial matrix triggered by the apoptotic stimuli. However, there is a controversy about whether or not the mitochondria, indeed, swell during apoptosis. The major advantages of atomic force microscopy (AFM) over conventional optical and electron microscopes for bio-imaging include the fact that no special coating and vacuum are required and imaging can be done in all environments--air, vacuum or aqueous conditions. In addition, AFM force-distance curve measurements have become a fundamental tool in the fields of surface chemistry, biochemistry, and material science. In this study, we used AFM to observe the morphological and property changes in heart mitochondria that were isolated from a rat myocardial infarction model. From the shape parameters of the mitochondria in the AFM topographic image, it seemed that myocardial infarction caused the mitochondrial swelling. Also, the results of force-distance measurements showed that the adhesion force of heart mitochondria was significantly decreased by myocardial in infarction. Therefore, we suggested that myocardial infarction might be the cause of mitochondrial swelling and the changes in outer membrane of heart mitochondria.     

Ultrawidely tunable single-mode fiber acousto-optic filter

A single-mode fiber (SMF) acousto-optic tunable filter (AOTF) with a tuning range of more than 300 nm is demonstrated. The SMF used in the experiment has a ring of symmetric holes within the cladding, which causes a larger mode-index difference between the first and the second higher-order antisymmetric modes than those of a conventional SMF. As a result, the difference in beatlengths between the core mode and the higher-order modes is highly increased, which makes it possible for the SMF AOTF to exhibit a single resonance peak in the transmission spectrum over the wavelength range of 1.3-1.6 μm for given acoustic frequencies of 3.1-3.8 MHz.     

Photonic temporal integration of broadband intensity waveforms over long operation time windows

We propose and experimentally demonstrate a novel design for temporal integration of microwave and optical intensity waveforms with combined high processing speed and a long operation time window. It is based on concatenating in series a discrete-time (low-speed) photonic integrator and a high-speed analog time-limited intensity integrator. This scheme is demonstrated here using a cascaded fiber-based interferometers' system (as a passive eight-point discrete-time integrator) and an analog time-limited intensity integrator. The latter is based on temporal intensity modulation of the input waveform with a rectangular-like incoherent energy spectrum followed by linear dispersion. Using this setup, we experimentally achieve accurate time integration of intensity signals with ~36 GHz bandwidths over an operation time window of ~4 ns, corresponding to a processing time-bandwidth product of >144.     

Relaxation structure analysis of Li inserted γ-Fe2O3

γ-Fe₂O₃ has a spinel structure with cation vacancy and is expected to perform as a favorable electrode material for secondary lithium-ion battery. When lithium is inserted electrochemically into γ-Fe₂O₃, prolonged potential change is observed after the insertion. In this study, we inserted various amount of Li into γ-Fe₂O₃ (x = 0.66, 1.1, 1.5 in terms of Li_XFe₂O₃), then made the circuit open, measured X-ray diffraction (XRD) patterns at various elapsed time, and analyzed the crystal structure change of γ-Fe₂O₃ with time by the Rietveld method. The X-ray Rietveld analysis revealed that the iron occupancy of 8a site decreased and that of 16c site increased with lithium insertion process and after lithium insertion, the iron occupancy of 8a site increased and that of 16c site decreased gradually with relaxation time. It is indicated that lithium prefer 8a site to occupy kinetically, on the other hand, prefer 16c site thermodynamically.     

Preparation of Ga-doped ZnO films by pulsed dc magnetron sputtering with cylindrical rotating target for thin film solar cell applications

Applicability of Ga-doped ZnO (GZO) films for thin film solar cells (TFSCs) was investigated by preparing GZO films via pulsed dc magnetron sputtering (PDMS) with rotating target. The GZO films showed improved crystallinity and increasing degree of Ga doping with increasing thickness to a limit of 1000 nm. The films also fulfilled requirements for the transparent electrodes of TFSCs in terms of electrical and optical properties. Moreover, the films exhibited good texturing potential based on etching studies with diluted HCl, which yielded an improved light trapping capability without significant degradation in electrical propreties. It is therefore suggested that the surface-textured GZO films prepared via PDMS and etching are promising candidates for indium-free transparent electrodes for TFSCs.