A <Emphasis Type="Italic">VU</Emphasis>-decomposition method for a second-order cone programming problem

A vu-decomposition method for solving a second-order cone problem is presented in this paper. It is first transformed into a nonlinear programming problem. Then, the structure of the Clarke subdifferential corresponding to the penalty function and some results of itsvu-decomposition are given. Under a certain condition, a twice continuously differentiable trajectory is computed to produce a second-order expansion of the objective function. A conceptual algorithm for solving this problem with a superlinear convergence rate is given.     

Collinear Velocity-map Photoelectron Imaging Spectrometer for Cluster Anions

We describe a collinear velocity-map photoelectron imaging spectrometer, which combines a Wiley-McLaren time-of-flight mass analyzer with a dual-valve laser vaporization source for investigating size-selected cluster and reaction intermediate anions. To generate the reaction anions conveniently, two pulsed valves and a reaction channel are employed instead of premixing carrier gas. The collinear photoelectron imaging spectrometer adopts modified velocity-map electrostatic lens, and provides kinetic energy resolution better than 3%. The performance of the instrument is demonstrated on the photodetachment of Si₄^- at 532 and 355 nm, and Si₃C^- at 532 nm, respectively. In both cases, photoelectron spectra and anisotropy parameters are obtained from the images. For Si₄^-, the spectra show two well-resolved vibrational progressions which correspond to the ground state and the first excited state of the neutral Si₄ with peak spacing of 330 and 312 cm^-1, respectively. Preliminary results suggest that the apparatus is a powerful tool for characterizing the electronic structure and photodetachment dynamics of cluster anions.     

金属钾和碳酸钠高压合成金刚石

以金属钾和碳酸钠为反应原料, 在压力为2 GPa, 温度为500 ℃的密封白金坩埚中反应18 h, 所得产物通过粉末X射线衍射和显微拉曼分析进行了表征, 证实合成出了微米级的金刚石. 对金刚石的合成机理进行了研究, 推测其反应过程为碳酸钠在铂和钾的作用下分解出CO2, CO2与钾反应得到金刚石. 研究结果表明金刚石可以在温和的条件下合成.     

约束含参分岔问题的分类

约束边界与分岔参数有关的约束分岔问题,称为约束含参分岔问题．通过引入适当的变换,将约束含参分岔问题转化为新变量的非约束分岔问题,推导出了约束含参分岔问题转迁集的一般形式,结果表明只有约束分岔集受约束含参的影响,其它转迁集与不含参约束分岔的转迁集相同．以含参约束树枝分岔为例分析了此类问题的分岔分类,讨论了约束含参对分岔分类的影响．     

一类拟线性椭圆障碍问题极小正解的存在性

该文使用Ｌｉｏｎｓ的集中紧性原理和变分方法,证明了一类非齐次拟线性椭圆型方程对应的障碍问题中极小正解的存在性．     

大豆中的化学

大豆和豆制品中具有种类繁多的化学成分如大豆皂甙、大豆异黄酮、植物雌激素、大豆磷脂、大豆低聚糖等,它们具有广泛的生理功效,可防治癌症、防骨质疏松症、防心血管疾病、降低血脂、抗动脉粥样硬化症、改善妇女更年期综合症、防止鼻出血综合症等,因而决定了它可在食品、药品和化妆品中得到广泛的应用。目前国外研究较为深入,有的已用于生产实际,而国内尚无这方面的报道。我国东北素以生产优质大豆而闻名中外,倘若能充分利用豆渣、豆皮等废料加工,提取大豆中的有效成分,将有非常可观的社会和经济效益。     

Molecular Component Structures Mediated Formation of Self-assemblies

IntroductionThe basis of molecular recognition is the expression of information stored in the interact-ing components. In the process of self-assembly, the information is expressed by acomponent's potential for entering into noncovalent relationships with its partners and by itssteric requirements. Thus, it could be expected that suitably designed molecular components...containing proper information would generate self-assemblies with definite architect.re.[1'2J.There have been many examples …     

对羟基苯乙酮及其类似物的烷羰C————C键的断裂

甲基、乙基、正丙基和苄基对羟苯基酮和6－羟基甲氢萘－1－酮经证实在合成乙二醇缩酮的条件下发生烷羰C－C键的断裂,而对羟基二苯酮、对羟基苯异丁酮和5－羟基二氢茚－1－酮却不发生这一断键反应。经推论这一断键反应首先是发生羟醛缩合,继以在酚羟基参与下引发烷羰C－C键断裂的;还应指出,也是由于对位羟基的参与,这些烷基对羟苯基酮不形成它们的乙醇缩酮。     

Mo2C膜表面粗糙化规律的计算机模拟

引入晶粒边界修正,改进了Mo2C膜表面粗糙化物理模型,将DT2模型推广到包括有温度的情况,对Mo2C膜表面形态进行计算机模拟并统计模拟图的高度分布,确定表面粗糙度随沉积时间和基底温度的变化规律。结果表明：引入晶粒边界修正大大促进了理论与实验结果的一致,Mo2C膜表面粗糙化属快速粗造化,粗造度随基底温度升高而非线性地增大。     

CO氧化反应耦合下SrFe1.125Co0.375Oy的氧渗透行为

报道SrFe1.125Co0.375Oy致密陶瓷膜在高氧梯度下的氧渗透行为。将膜的一端置于空气中,另一端引入CO,通过CO的氧化反应降低氧分压,增大膜两端的氧分压梯度。研究发现：900℃时氧渗透率高达16.0×10-7mol/cm2s。在850℃以上,氧渗透率与温度的依赖关系不显著,而氧渗透量与CO分压成线形关系,并且与膜的厚度变化基本无关。这表明在该膜材料的氧渗透过程是受表面反应控制的。