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1.
2.
The X-ray structures of 4,10-di-tert-butyl-5,9-diisopropyl-4,5,9,10-tetraazatetracyclo[6.2.2.2(3,6)]tetradecane (s4iPr) and its 4,9-di-tert-butyl-5,10-diisopropyl isomer (a4iPr) are reported. Both compounds are in conformations having their in-N-alkyl groups (directed toward the central CH-CH bond of the molecule) anti to each other, as expected from previous work. The principal feature of interest is that one in-isopropyl group in each compound is in an eclipsed conformation, NN,C(alpha)Me twist angle -0.5(5) degrees for s4iPr and -6.4(4) degrees for a4iPr. Low energy (somewhat less) eclipsed in-isopropyl conformations are predicted by both molecular mechanics (MM2) and semiempirical quantum mechanical (AM1) calculations. The asymmetry of the potentially C(2) symmetric a4iPr because the two in-isopropyl groups are in different rotamers is apparently not a result of crystal packing forces, because a conformation with different isopropyl rotamers is the more stable one by at least 1.0 kcal/mol in solution, determined by (13)C-NMR spectroscopy. This result is not predicted by either calculation method. The "monomer", 2-tert-butyl-3-isopropyl-2,3-diazabicyclo[2.2.2]octane (3), proves to be a poor model for the conformations of 4iPr. 相似文献
3.
Considered are modifications of a rank test of randomness for the one- and multi-dimensional regular design cases as well as for the one- and multi-dimensional random design cases. The null hypothesis is that all observations are independent and identically distributed. The main result is the proof of consistency of the test in each of the above cases against two general alternatives.Alternative 1: there exists a pairwise disjoint partion U
i
=1
m
D
i
=D, where D d1, is a bounded domain inside which one makes observations, such that (1) if an observation point falls insideD
i
, then the corresponding observed value is the realization of a random variable i
i = l,...,m; (2) there exists an ordering % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiGc9yrFr0xXdbba91rFfpec8Eeeu0x% Xdbba9frFj0-OqFfea0dXdd9vqaq-JfrVkFHe9pgea0dXdar-Jb9hs% 0dXdbPYxe9vr0-vr0-vqpWqaaeaabiGaciaacaqabeaadaqaaqGaaO% qaamXvP5wqonvsaeHbfv3ySLgzaGqbaiab-Tha7jabe67a4Hqbdiab% +LgaPnaaBaaaleaacaWGRbaabeaakiab-1ha9naaDaaaleaacaWGRb% Gaeyypa0JaaGymaaqaaiaad2gaaaaaaa!4C2D!\[\{ \xi i_k \} _{k = 1}^m \], where % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiGc9yrFr0xXdbba91rFfpec8Eeeu0x% Xdbba9frFj0-OqFfea0dXdd9vqaq-JfrVkFHe9pgea0dXdar-Jb9hs% 0dXdbPYxe9vr0-vr0-vqpWqaaeaabiGaciaacaqabeaadaqaaqGaaO% qaaiabe67a4nXvP5wqonvsaeHbfv3ySLgzaGqbdiab-LgaPnaaBaaa% leaacaWGRbaabeaaaaa!454D!\[\xi i_k \] is stochastically smaller than % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiGc9yrFr0xXdbba91rFfpec8Eeeu0x% Xdbba9frFj0-OqFfea0dXdd9vqaq-JfrVkFHe9pgea0dXdar-Jb9hs% 0dXdbPYxe9vr0-vr0-vqpWqaaeaabiGaciaacaqabeaadaqaaqGaaO% qaaiabe67a4nXvP5wqonvsaeHbfv3ySLgzaGqbdiab-LgaPnaaBaaa% leaacaWGRbaabeaakmaaBaaaleaacqGHRaWkcaaIXaaabeaakiaacY% cacaWGRbGaeyypa0JaaGymaiaacYcacaGGUaGaaiOlaiaac6cacaGG% SaGaamyBaiabgkHiTiaaigdaaaa!509B!\[\xi i_k _{ + 1} ,k = 1,...,m - 1\], (3) the partition is independent of the number of observation points. Note thatm, this ordering, and the sets D
i
are not known a priori: one tests only for the existence of such a partition. Note also that in the one-dimensional case the initial sequence need not be stochastically monotone under the alternative.Alternative 2: there exists an arbitrary asymptotically continuous trend in location. Asymptotically continuous means that the trend converges to some continuous, not identically constant function as the number of data points goes to infinity. This function need not be monotone.A numerical example illustrating the use of the obtained results for image analysis (edge detection) is presented. 相似文献
4.
V. K. Burichenko E. I. Ramm N. I. Koryakina L. I. Mar'yash R. R. Kamilova 《Chemistry of Natural Compounds》1989,25(3):338-344
A study has been made by the CD method of the conformational potentialities of the polypeptides (Gly-Lys-Gly)n and (Ala-Lys-Ala)n and fragments of the terminal sections of histones H4 (the sequence 1–16), H2B (1–21), and H1 (152–184), and they have been used as models of histones in complex formation with DNA under various conditions of the medium.V. I. Nikitin Institute of Chemistry, Tadzhik SSR Academy of Sciences, Dushanbe. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 391–398, May–June, 1989. 相似文献
5.
A method is proposed to create materials with a desired refraction coefficient, possibly negative one. The method consists of embedding into a given material small particles. Given n0(x), the refraction coefficient of the original material in a bounded domain , and a desired refraction coefficient n(x), one calculates the number N(x) of small particles, to be embedded in D around a point xD per unit volume of D, in order that the resulting new material has refraction coefficient n(x). 相似文献
6.
Alexander G. Ramm Alexandra B. Smirnova Angelo Favini 《Annali di Matematica Pura ed Applicata》2003,182(1):37-52
A nonlinear operator equation F(x)=0, F:H→H, in a Hilbert space is considered. Continuous Newton’s-type procedures based on a construction of a dynamical system with
the trajectory starting at some initial point x
0 and becoming asymptotically close to a solution of F(x)=0 as t→+∞ are discussed. Well-posed and ill-posed problems are investigated.
Received: June 29, 2001; in final form: February 26, 2002?Published online: February 20, 2003
This paper was finished when AGR was visiting Institute for Theoretical Physics, University of Giessen. The author thanks
DAAD for support 相似文献
7.
8.
Tim Haslett Simon Moss Charles Osborne Paul Ramm 《Nonlinear dynamics, psychology, and life sciences》2000,4(1):67-86
This paper examines the imposition of local rules in five mail delivery centres of Australia Post. Local rules are patterns of behaviour used by subunits of an organization to optimise their payoff. These local rules may ultimately benefit the total organization. Fitness landscapes are used to examine the emergence of local rules in this workplace. This research examined the relationship between the time taken to sort the mail and the volume of this mail. Work rates show a clear catastrophe shift; that is, work rates suddenly drop when the volume of mail exceeds a certain level, as Postal Delivery Officers apply local rules to maximise gains inherent in the pay structures. Such behaviour is close to that predicted by Kauffman (1995) in computer simulations of lattices and may be indicative of the application of local rules in organizations. The implications of the use of local rules are that behaviour in social systems may be dictated by systemic and emergent processes which are outside immediate management control. A further implication is that organizations may be structured to a significant extent by such local rules. 相似文献
9.
A bistatic ultrasound imaging system is demonstrated that uses two 32-element linear phased array transducers oriented at an angle of 40 degrees to one another. The system simultaneously acquires and displays in real time one conventional backscatter image and one "angular scatter" image formed using side-scattered echoes from the same B-mode sector region. Experiments are presented that show differences in the magnitudes of backscatter and angular scatter signals acquired from three nylon monofilaments with diameters less than one wavelength and from soft tissue structures in vivo. The relative magnitudes of angular scatter signals from the monofilaments are qualitatively consistent with a theoretical analysis of acoustic scattering from elastic cylinders. Larger tissue features are more clearly defined in angular scatter images. This result is attributed to the orientation of specularly reflecting surfaces and the expected influence of scattering angle on the system's sensitivity to different scatterer spacings. 相似文献
10.
A. G. Ramm 《Journal of statistical physics》2007,127(5):915-934
If A
q(β, α, k) is the scattering amplitude, corresponding to a potential , where D⊂ℝ3 is a bounded domain, and is the incident plane wave, then we call the radiation pattern the function , where the unit vector α, the incident direction, is fixed, β is the unit vector in the direction of the scattered wave,
and k>0, the wavenumber, is fixed. It is shown that any function , where S
2 is the unit sphere in ℝ3, can be approximated with any desired accuracy by a radiation pattern: , where ∊ >0 is an arbitrary small fixed number. The potential q, corresponding to A(β), depends on f and ∊, and can be calculated analytically. There is a one-to-one correspondence between the above potential and the density
of the number of small acoustically soft particles D
m⊂ D, 1≤ m≤ M, distributed in an a priori given bounded domain D⊂ℝ3. The geometrical shape of a small particle D
m is arbitrary, the boundary S
m of D
m is Lipschitz uniformly with respect to m. The wave number k and the direction α of the incident upon D plane wave are fixed. It is shown that a suitable distribution of the above particles in D can produce the scattering amplitude , at a fixed k>0, arbitrarily close in the norm of L
2(S
2× S
2) to an arbitrary given scattering amplitude f(α ', α), corresponding to a real-valued potential q∊ L
2(D), i.e., corresponding to an arbitrary refraction coefficient in D.
MSC: 35J05, 35J10, 70F10, 74J25, 81U40, 81V05, 35R30.
PACS: 03.04.Kf. 相似文献