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981.
Raymond K. Sheline B. Singh P. C. Sood S. Y. Chu 《Czechoslovak Journal of Physics》1999,49(7):1047-1066
Energies of the first 2+, 3− and 4+ states of even-even nuclei are plotted against proton and neutron number. Using this systematics, shell effects and the corresponding
quadrupole and hexadecapole collectivity and deformation effects are compared and contrasted. Also, the correspondingB(E2),B(E3) andB(E4) values are plotted against neutron number and their very different systematics compared. Among the new results are the
presence of hexadecapole collectivity at the 82 proton and neutron closed shells and the presence of the maximum values ofB(E4) at neutron numbers 10, 90–92 and 140–146. Finally, the systematics of the hexadecapole (K=4+) vibrations is compared with that of the quadrupole (K=2+) gamma vibrations in the quadrupole deformed rare earth region.
This research has been supported by the National Sciences and Engineering Research Council of Canada at McMaster University
and by the Department of Atomic Energy, Government of India, at Banaras Hindu University. 相似文献
982.
The thermal lensing effect of the Copper Vapor Laser (CVL) was studied by considering both its windows and the active medium. The equivalent combined focal length of the active medium and windows was measured to be 52 mts under operating conditions for a 35W CVL. The variation of focal length with the operating parameters was studied. 相似文献
983.
Hina Bhargava N. Lakshmi Ram Kripal Sharma K. Venugopalan 《Hyperfine Interactions》2008,183(1-3):155-161
Low temperature Mössbauer and AC susceptibility have been used to study relaxation phenomena in nano-sized particles of Cr0.25Co0.25Zn0.5Fe2O4. From these studies, the energy density constant for this system has been estimated to be 4 x 106 erg/cm3. Cation distribution has also been determined and the observed results are correlated to calculated relaxation times. 相似文献
984.
Girija S. Singh 《Journal of heterocyclic chemistry》2000,37(5):1355-1356
Titled compounds undergo selective N‐C cleavage on treatment with sodium hydroxide in ethanol affording a series of novel isatin‐based spiroazetidinones. 相似文献
985.
The near-surface region of 4145 steel following boron implantation was investigated by x-ray photoelectron spectroscopy (XPS). The steel surface was implanted with11B+ ions to a constant dose of 1.0×1017 ions cm–2 at energies of 30 and 135 keV. The XPS spectrum of the implanted surface showed a shift in the B(1s) level towards the higher binding energy. The observed 188.0 eV binding energy of the B(1s) level was found to be in good agreement with the characteristic binding energy of the B(1s) level corresponding to iron boride (Fe2B). Hence the increase in surface hardness reported previously is related to the formation of an iron boride layer in the near-surface region known for its hardening capabilities. 相似文献
986.
We consider here the problem of the existence of a quasi-invariant which is linear in the momenta for Hamiltonians in three
degrees of freedom. We show that such quasi-invariants are more constrained in their structure than in the two degrees of
freedom case. We also show that some of these quasi-invariants have to be interpreted as ‘pseudo-translations’, i.e., as translations
in a non-orthogonal system of coordinates. 相似文献
987.
Considering a Robertson-Walker line element, exact solutions are obtained for radiation-filled cosmological differential equations of Brans-Dicke theory with the assumption that the radius of curvatureQ of the universe varies directly as thenth power of time. The solution is found to be valid for closed space only and the coupling constantw of the scalar tensor theory is necessarily negative. The radius of curvature of increases linearly with respect to the age of the universe, while the gravitational constantk varies directly as the square of the radius of the universe. The solution obtained is in contradiction to Dirac's hypothesis, in which the gravitational constant should decrease with time in an expanding universe. 相似文献
988.
The electric field gradient (EFG) and the asymmetry parameter (η) due to transition metal impurities in the host metals Al,
Cu and V are investigated. The valence EFG is formulated using dielectric screening theory in conjunction with pseudopotential
theory. The size EFG is evaluated in the elastic continuum limit for a screened point charge model of the host metal. The
detailed calculations are carried out forAl (Sc, Fe, Cr),Cu (Ni, Pd, Pt) andV (Ti, Cr, Fe, Nb, Ta, W) alloys. 相似文献
989.
We consider the model of the one-dimensional cookie random walk when the initial cookie distribution is spatially uniform
and the number of cookies per site is finite. We give a criterion to decide whether the limiting speed of the walk is non-zero.
In particular, we show that a positive speed may be obtained for just three cookies per site. We also prove a result on the
continuity of the speed with respect to the initial cookie distribution.
相似文献
990.
Kinetic and thermodynamic investigations were performed for a mixed aqueous-organic, 1:1 (v/v) water–1,4-dioxane medium, which was found to be an efficient solvent for the interaction of a neutral dichlorotris(triphenylphosphine) ruthenium(II), RuCl2(PPh3)3 complex with carbon monoxide at atmospheric pressure. During the interaction, RuCl2(PPh3)3 dissociates to a neutral complex dichlorobis(triphenylphosphine) ruthenium(II), RuCl2(PPh3)2, by losing a coordinated PPh3 ligand and RuCl2(PPh3)2 coordinates with CO to form an in situ carbonyl complex RuCl2(CO)(PPh3)2. The in situ formed carbonyl complex RuCl2(CO)(PPh3)2 was thoroughly characterized by equilibrium, spectrophotometric, IR, and electrochemical techniques. Under equilibrium conditions, the rate and dissociation constants for the dissociation of PPh3 from RuCl2(PPh3)3 were found to be favorable for the formation of the carbonyl complex RuCl2(CO)(PPh3)2. The rates of complexation for the formation of RuCl2(CO)(PPh3)2 were found to follow an overall second-order kinetics being first order in terms of the concentrations of both carbon monoxide and RuCl2(PPh3)2. The determined activation parameters corresponding to the rate constant (ΔH# = 35.9 ± 2.5 kJ mol−1 and ΔS# = −122 ± 6 J K−1 mol−1) and thermodynamic parameters corresponding to the formation constant (ΔH° = −33.5 ± 4.5 kJ mol−1, ΔS° = −25 ± 8 J K−1 mol−1, and ΔG° = −25.7 ± 2.0 kJ mol−1) were found to be highly favorable for the formation of the complex RuCl2(CO)(PPh3)2. © 2008 Wiley Periodicals, Inc. Int J Chem Kinet 40: 359–369, 2008 相似文献