全文获取类型
收费全文 | 4384篇 |
免费 | 186篇 |
国内免费 | 12篇 |
专业分类
化学 | 3070篇 |
晶体学 | 34篇 |
力学 | 95篇 |
数学 | 462篇 |
物理学 | 921篇 |
出版年
2023年 | 52篇 |
2022年 | 53篇 |
2021年 | 80篇 |
2020年 | 100篇 |
2019年 | 88篇 |
2018年 | 93篇 |
2017年 | 108篇 |
2016年 | 165篇 |
2015年 | 102篇 |
2014年 | 210篇 |
2013年 | 369篇 |
2012年 | 321篇 |
2011年 | 336篇 |
2010年 | 227篇 |
2009年 | 187篇 |
2008年 | 243篇 |
2007年 | 197篇 |
2006年 | 139篇 |
2005年 | 192篇 |
2004年 | 139篇 |
2003年 | 141篇 |
2002年 | 132篇 |
2001年 | 40篇 |
2000年 | 38篇 |
1999年 | 29篇 |
1998年 | 36篇 |
1997年 | 39篇 |
1996年 | 33篇 |
1995年 | 29篇 |
1994年 | 29篇 |
1993年 | 32篇 |
1992年 | 25篇 |
1991年 | 33篇 |
1990年 | 26篇 |
1989年 | 24篇 |
1988年 | 27篇 |
1987年 | 25篇 |
1986年 | 27篇 |
1985年 | 31篇 |
1984年 | 39篇 |
1983年 | 33篇 |
1982年 | 24篇 |
1981年 | 24篇 |
1980年 | 27篇 |
1979年 | 20篇 |
1978年 | 23篇 |
1977年 | 32篇 |
1976年 | 14篇 |
1975年 | 19篇 |
1974年 | 18篇 |
排序方式: 共有4582条查询结果,搜索用时 15 毫秒
11.
The paper describes the possibility of designing matched interacting semiconductor quantum wells. It is shown that for a given eigenstate of a quantum well (QW), it is always possible to find another QW in such a way that the coupling leaves the original eigenstate of the host QW unperturbed irrespective of the strength of interaction. For rectangular QWs, the condition is met with whenever the second QW has appropriate width and depth so that phase travelled by an electron wave through it is an integral multiple of π. 相似文献
12.
The 8-mol percentage Y2O3-stabilized Porous Zirconia was prepared using sol–gel method. Zirconium oxalate gel was prepared by the addition of appropriate
amount of oxalic acid solution into the 1 M aqueous solution of zirconium-oxy chloride. A cubic phase zirconia powder was
obtained by calcination and milling of the zirconium oxalate gel. Crystallization temperature was found about 450 °C from
the Differential thermal analysis. The phase analysis by X-ray diffraction shows the presence of cubic phase. Pellets sintered
at 1,350 °C were highly porous, and the electrical conductivity was found with lower value due to the porosity, and the hardness
was about 8.0 GPa.
Paper presented at the Third International Conference on Ionic Devices (ICID 2006), Chennai, Tamilnadu, India, Dec. 7–9, 2006. 相似文献
13.
Alejandro F. Ramı́rez 《Comptes Rendus Mathematique》2002,334(2):139-144
Consider an infinite dimensional diffusion process with state space , where T is the circle, and defined by an infinitesimal generator L which acts on local functions f as . Suppose that the coefficients ai and bi are smooth, bounded, of finite range, have uniformly bounded second order partial derivatives, that ai are uniformly bounded from below by some strictly positive constant, and that ai is a function only of ηi. Suppose that there is a product measure ν which is invariant. Then if ν is the Lebesgue measure or if d=1,2, it is the unique invariant measure. Furthermore, if ν is translation invariant, it is the unique invariant, translation invariant measure. The proofs are elementary. Similar results can be proved in the context of an interacting particle system with state space , with uniformly positive bounded flip rates which are finite range. To cite this article: A.F. Ram??rez, C. R. Acad. Sci. Paris, Ser. I 334 (2002) 139–144 相似文献
14.
Friedel-Crafts alkylation of indoles with epoxides to afford 3-alkyl indole derivatives at room temperature with moderate to good yields and high regioselectivity using nanocrystalline titanium(IV) oxide catalyst is described. 相似文献
15.
16.
The elastic constants of dilute alloys based on bcc metals have been calculated using the Green’s function method obtaining
explicit expressions for change in elastic constants in terms oft-matrix. The crystal impurity problem is discussed within an impurity model containing central and non-central force constant
changes extended up to second neighbours of the impurity. The effect of volume change on elastic constants and a contribution
from electron pressure term are considered. Numerical results for changes in three elastic moduli have been presented for
a number of dilute alloys based on Mo, Nb, W, Ta and V. 相似文献
17.
L. Barral J. Cano A. J. López J. López P. Nogueira C. Ramírez 《Journal of Thermal Analysis and Calorimetry》1995,45(5):1167-1174
Using dynamic mechanical analysis (DMA) we have studied thermal degradation for a system containing a diglycidyl ether of bisphenol A (DGEBA) and 1,3-bisaminomethylcylohexane (1,3-BAC). The changes of dynamic mechanical properties during thermal degradation indicated a shift of the glass transition temperature (T g) to higher temperatures and a decrease in the peak value of the dynamic loss factor (tan δ) with an increasing of aging time. The value of dynamic storage modulus (E′) at the rubbery state showed an increase with aging time, whiteE′ at the glassy state only underwent a moderate change with increased thermal degradation. From these results it can be argued that thermal degradation during the stage prior to the onset of the severe degradation involves structural changes in the epoxy system, as further crosslinking and loss of dangling chains in the crosslinked network. 相似文献
18.
Ram C. Maurya Deen D. Mishra Surendra K. Jaiswal Sudipta Mukherjee 《Transition Metal Chemistry》1992,17(5):381-383
Some new low-spin hexacoordinated cyanonitrosyl complexes of Cr1 of the type [Cr(NO)(CN)2(L)2(H2)], where L is an aromatic aldehyde oxime or Mannich base, have been prepared by the interaction or K3[Cr(NO)(CN)5]· H2O with L in aqueous AcOH, and characterized by a range of physico-chemical techniques, I.r. data suggest that all the oxime
derivatives and Mannich bases act as monodentate ligands by coordinating through the aromatic nitrogen.
TMC 2564 相似文献
19.
Ram K. Ganesh 《国际流体数值方法杂志》1991,13(5):557-578
The total drag force on the surface of a body, which is the sum of the form drag and the skin friction drag in a 2D domain, is numerically evaluated by integrating the energy dissipation rate in the whole domain for an incompressible Stokes fluid. The finite element method is used to calculate both the energy dissipation rate in the whole domain as well as the drag on the boundary of the body. The evaluation of the drag and the energy dissipation rate are post-processing operations which are carried out after the velocity field and the pressure field for the flow over a particular profile have been obtained. The results obtained for the flow over three different but constant area profiles—a circle, an ellipse and a cross-section of a prolate spheroid—with uniform inlet velocity are presented and it is shown that the total drag force times the velocity is equal to the total energy dissipation rate in the entire finite flow domain. Hence, by calculating the energy dissipation rate in the domain with unit velocity specified at the far-field boundary enclosing the domain, the drag force on the boundary of the body can be obtained. 相似文献
20.
Ram Kripal 《Solid State Communications》2005,133(1):23-28
The ESR spectrum of Mn2+ doped potassium hydrogen sulphate at liquid nitrogen temperature (77 K) has been analyzed and site of entered Mn2+ in the lattice has been discussed. The values of the zero field parameters that give good fit to the observed ESR spectra have been obtained. The obtained g, A, B, D, E and a values are 2.0002, 66×10−4 cm−1, 26×10−4 cm−1, 59×10−4 cm−1, 32×10−4 cm−1 and −8×10−4 cm−1, respectively. The percentage of covalency of the metal-ligand bond has also been estimated. From the optical absorption study at room temperature, the distortion has been suggested. The observed bands are assigned as transitions from the 6A1g(S) ground state to various excited quartet levels of Mn2+ ion in a cubic crystalline field. The electron repulsion and crystal field parameters B, C, Dq and α providing good fit to the observed optical spectra have been evaluated and the values obtained for the parameters are B=627 cm−1, C=2580 cm−1 , Dq=790 cm−1 and α=76 cm−1. 相似文献