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201.
Dr. Subramani Rajkumar Mengyao Tang Prof. Dr. Xiaoyu Yang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(6):2353-2357
An efficient method for the asymmetric synthesis of 4H-3,1-benzoxazines was developed by kinetic resolution of 2-amido benzyl alcohols using chiral phosphoric acid catalyzed intramolecular cyclizations. A broad range of benzyl alcohols (both secondary and tertiary alcohols) were kinetically resolved with high selectivities, with an s factor of up to 94. Mechanistic studies were performed to elucidate the mechanism of these reactions, wherein the amide moieties reacted as the electrophiles. Gram-scale reaction and facile transformations of the chiral products demonstrate the potential of this method in asymmetric synthesis of biologically active chiral heterocycles. 相似文献
202.
The point of departure for this analysis is Bjørndal and Lindroos [2012], who developed an empirical bioeconomic model to analyze cooperative and noncooperative management of Northeast Atlantic cod. In their analysis, only constant strategies were analyzed for noncooperative games. In this paper, nonconstant strategies are considered. Moreover, the fishery in question is characterized by cooperative management. What may happen in the real world is that one nation breaks the cooperative agreement by fishing in excess of its quota. Often, it takes time for the other agent to detect this and respond. In this paper, we allow this kind of delayed response into a two‐agent noncooperative game so that, if country 2 exceeds its quota, there will be a time lag before this is detected by country 1; moreover, there may also be a delay until country 1 is able to respond. Results show that the outcome critically depends on the length of these two lags as well as initial conditions. 相似文献
203.
HanSol Kim Eun Jo Jang Narendra V. Sankpal Madhumita Patel Rajkumar Patel 《Macromolecular bioscience》2023,23(3):2200346
Over the years, scientists have studied the behavior and anatomy of many animals to understand the own species. However, despite the continuous efforts, it is often difficult to know for certain how the brain works due to the differences between the brains of animals and the human brain. While the use of animal models for research continues, the origin of human cognition and neurological disorders needs further elucidation. To that end, in vitro organoids that exhibit in vivo characteristics of the human brain have been recently developed. These brain-like organoids enable researchers to dive deeper into understanding the human brain, its neurological structures, and the causes of neurological pathologies. This paper reviews the recent developments in the regeneration of brain-like organoids using Matrigel and other alternatives. Further, gel-free methods that may enhance the regeneration process of organoids are discussed. Finally, the vascularized brain organoid growth and development in both in vitro and in vivo conditions are detailed. 相似文献
204.
Meera Moydeen Abdul Hameed Syed Ali Padusha Mohamed Khan Badr M. Thamer Nirmala Rajkumar Hany El-Hamshary Mohamed El-Newehy 《先进技术聚合物》2023,34(1):6-23
Electrospinning procedures such as blend electrospinning, coaxial electrospinning, and emulsion electrospinning have been used for the fabrication of electrospun nanofibers (ENFs) for biomedical applications. These ENFs are attracted great interest especially in drug delivery applications due to their small size, high surface area-to-volume, and porosity. The aim of this review is to focus on the controlled release mechanism among the different electrospinning methods, and the selectivity of hydrophilic, water-soluble polymers as a carrier for drug. The mechanism for the drug delivery depends mainly on the method of drug loading, polymeric interactions, and the nature of polymer swelling, erosion, or degradation. This review compressed on the literature survey about the fabrication of nanofibers by different electrospinning methods, factors affecting the nanofiber morphologies, selectivity of polymeric blends for successful controlled release behavior, and the mechanism involved in the drug release steps. 相似文献
205.
206.
Amol H. Kategaonkar Rajkumar U. Pokalwar Sandip A. Sadaphal Pravin V. Shinde Bapurao B. Shingate Murlidhar S. Shingare 《Heteroatom Chemistry》2009,20(7):436-441
A simple and convenient method is developed for the synthesis of new O,O‐diethyl O‐(substituted tetrazolo[1,5‐a]quinolin‐4‐yl)methyl phosphorothioates, which has been synthesized for the first time from tetrazolo[1,5‐a] quinolines via tetrazolo[1,5‐a]quinolin‐4‐ylmethanol derivatives. The structures of the all newly synthesized compounds were elucidated by analytical and spectral methods. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 20:436–441, 2009; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20570 相似文献