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91.
Rajamohan R Swaminathan M 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2011,83(1):207-212
Spectral characteristics of diphenylamine (DPA) have been investigated in β-cyclodextrin (β-CDx) solution. The formation of the complex was revealed by UV, steady state and time-resolved fluorescence spectroscopy. The stoichiometry of DPA:β-CDx complex, determined using Benesi-Hildebrand equation and Job's continuous variation method is 1:1. The binding constants calculated from various methods are reported. This inclusion complex formation from DPA and β-CDx was also confirmed by the FT-IR spectral study and SEM image analysis of solid complex prepared by co-precipitation method. 相似文献
92.
Peddikotla Prabhakar Dasari Ramesh Singanaboina Rajaram Dorigondla Kumar Reddy Yenamandra Venkateswarlu 《Helvetica chimica acta》2011,94(8):1481-1487
A new, simple, and short route for the synthesis of simplactones A ( 1 ) and B ( 2 ) was achieved from a synthetically prepared chiral auxiliary, i.e., the Oppolzer camphor‐derived sultam 4 , and (4‐methoxybenzyl)‐protected 3‐hydroxypropanal, in 52 and 48% overall yield, respectively, and with high diastereoselectivity (Schemes 2 and 3). 相似文献
93.
Molecular Diversity - Acetylcholinesterase enzyme is responsible for the degradation of acetylcholine and is an important drug target for the treatment of Alzheimer’s disease. When this... 相似文献
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97.
Vikas Thakur U. P. Verma Poolla Rajaram 《Journal of Sol-Gel Science and Technology》2013,66(2):280-287
Zinc oxide thin films were prepared from three different solvents using the sol–gel technique. Zinc acetate was used as the source of Zn, and the solvents ethanol, 2-methoxy ethanol and ethylene glycol were used to prepare the sols. ZnO thin films were deposited on glass microslides by pre-heating dip coated sol layers, following which they were finally annealed at 450 °C for half an hour. The films were characterized using structural, morphological and optical techniques. XRD studies show that the films grown from all the three solvents were single phase, highly oriented (along the c axis) ZnO having the wurzite structure. Optical transmission and photoluminescence spectra confirm the good quality of the ZnO films. SEM and AFM images show that the surfaces of the ZnO films, obtained using the first two (more volatile) solvents, consist of striations or ridges of height around 100–400 nm and are made up of nanoparticles 20–40 nm in size. The surfaces of the films produced from the less volatile third solvent are however smooth and devoid of striations although they are also covered with nanoparticles. 相似文献
98.
Sandeep Vasantrao Rohokale Santosh Rajaram Kote Santosh Rangnath Deshmukh Shankar Ramchandra Thopate 《Chemical Papers》2014,68(4):575-578
Naturally occurring organic acids are reported to be highly efficient promoters of the Beckmann rearrangement. Citric, oxalic, tartaric, malic, succinic, malonic, and fumaric acids efficiently promote the Beckmann rearrangement under solvent-free conditions and thermal and microwave irradiation. Tartaric acid was found to be the best promoter of the Beckmann rearrangement under conventional conditions as well as under microwave irradiation. Compared with conventional heating, microwave irradiation provides higher reaction rate and slightly higher yields. 相似文献
99.
Palladium catalyzed arylation of dialkyl itaconate in presence of Pd(OAc)2/PPh3 as a catalyst, afforded trisubstituted olefins stereo selectively. These alkenes are useful intermediates for the synthesis of anthraquinone carboxylic acid derivatives. A new coumarin is also synthesized using this protocol. 相似文献
100.
Rajaram Nityananda 《Pramana》1979,12(3):257-262
The possibility of extending the well known Poincare sphere representation of polarised light to include phase is considered.
Any attempt to define the zero of phase for each vibration represented on the Poincare sphere runs into discontinuities at
at least one point. These are shown to be inevitable using a topological argument. 相似文献