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31.
Utility of the Pfitzinger Reaction in the Synthesis of Novel Quinoline Derivatives and Related Heterocycles
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Derviş Gök Rahmi Kasımoğulları Mustafa Cengiz Samet Mert 《Journal of heterocyclic chemistry》2014,51(1):224-232
2‐(2‐Amino‐3,5‐dinitrophenyl)‐2‐oxoacetic acid ( 2 ) was obtained from hydrolysis of 5,7‐dinitroisatin ( 1 ) in alkaline media. A novel quinoxaline derivative ( 3 ) was synthesized from the reaction of the same compound ( 1 ) with o‐phenylenediamine. Reacting 2 with ethyl 3‐oxo‐3‐phenylpropanoate yields 6,8‐dinitro‐2‐phenylquinoline‐3,4‐dicarboxylic acid ( 4 ). Then, 4 was converted into new quinoline‐diacylchloride, quinoline‐ester, quinoline‐dicarboxamide, pyridazine, and pyrroledione derivatives ( 5 , 6a , 6b , 6c , 6d , 7a , 7b , 7c , 7d , 8 , 9 , 10a , 10b , 10c , 10d , 11a , 11b , 12 ) with SOCl2, alcohols, amines, and hydrazines, respectively. The structures of synthesized compounds were clarified by 1H NMR, 13C NMR, IR, mass and elemental analysis methods. 相似文献
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In this paper, the dynamic behaviour of a non-linear eight degrees of freedom vehicle model having active suspensions and passenger seat using Permanent Magnet Synchronous Motor (PMSM) controlled by a Neural Network (NN) controller is examined. A robust NN structure is established by using principle design data from the Matlab diagrams of system functions. In the NN structure, Fast Back-Propagation Algorithm (FBA) is employed. The user inputs a set of 16 variables while the output from the NN consists of f1–f16 non-linear functions. Further, the PMSM controller is also determined using the same NN structure. Various tests of the NN structure demonstrated that the model is able to give highly sensitive outputs for vibration condition, even using a more restricted input data set. The non-linearity occurs due to dry friction on the dampers. The vehicle body and the passenger seat using PMSM are fully controlled at the same time. The time responses of the non-linear vehicle model due to road disturbance and the frequency responses are obtained. Finally, uncontrolled and controlled cases are compared. It is seen that seat vibrations of a non-linear full vehicle model are controlled by a NN-based system with almost zero error between desired and achieved outputs. 相似文献
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An analytical formula is obtained for the temperature dependence of the anisotropy parameter of the upper critical field of a two-band superconductor in the context of the generalized Ginzburg-Landau theory for layered superconductors. The theoretical results are compared with the experimental data for new superconductor LiFeAs. 相似文献
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Sibel Alkan Bülent Zeybek Alev Doğan Rahmi Kasımoğulları Yunus Erdoğan Esma Kılıç 《Monatshefte für Chemie / Chemical Monthly》2009,140(4):381-386
Abstract Stoichiometric ionization constants of some pyrazole carboxylic acids [4-benzoyl-1-(3-nitrophenyl)-5-phenyl-1H-pyrazole-3-carboxylic
acid, 4-benzoyl-1-(4-nitrophenyl)-5-phenyl-1H-pyrazole-3-carboxylic acid, 4-(ethoxycarbonyl)-1,5-diphenyl-1H-pyrazole-3-carboxylic
acid, 4-(ethoxycarbonyl)-1-(3-nitrophenyl)-5-phenyl-1H-pyrazole-3-carboxylic acid, 4-(ethoxycarbonyl)-1-(4-nitrophenyl)-5-phenyl-1H-pyrazole-3-carboxylic
acid] were determined in ethanol–water mixtures of 50, 60, 70% ethanol (v/v) by a potentiometric titration method. Titrations
were performed in an ionic strength of 0.10 M NaCl at 25.0 ± 0.1 °C using an Orion 960 automatic titrator under a nitrogen
atmosphere. Using the potentiometric titration data, ionization constants were calculated in three different ways. The effects
of structure and solvent on the acidity of pyrazole carboxylic acids are also discussed.
Graphical abstract
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Disease spread in most biological populations requires the proximity of agents. In populations where the individuals have spatial mobility, the contact graph is generated by the “collision dynamics” of the agents, and thus the evolution of epidemics couples directly to the spatial dynamics of the population. We first briefly review the properties and the methodology of an agent-based simulation (EPISIMS) to model disease spread in realistic urban dynamic contact networks. Using the data generated by this simulation, we introduce the notion of dynamic proximity networks which takes into account the relevant time-scales for disease spread: contact duration, infectivity period, and rate of contact creation. This approach promises to be a good candidate for a unified treatment of epidemic types that are driven by agent collision dynamics. In particular, using a simple model, we show that it can account for the observed qualitative differences between the degree distributions of contact graphs of diseases with short infectivity period (such as air-transmitted diseases) or long infectivity periods (such as HIV). 相似文献
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Tuncay TuncÛ Habibe Tezcan Musa Sar Orhan Büyükgüngr Rahmi Ya?basan 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(9):o528-o529
Molecules of the title compound (alternative name: p‐nitrobenzaldehyde phenylhydrazone), C13H11N3O2, adopt an E configuration about the azomethine C=N double bond. Molecules are approximately planar and the dihedral angle between the planes of the phenyl rings is 11.62 (9)°. Hydrogen bonding links molecules related by 42 screw axes to form helices with a pitch of 7.7186 (8) Å. 相似文献
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The electron paramagnetic resonance (EPR) spectra of Cu2+-doped RbH2 PO4 at elevated temperatures indicate a phase transition at 358 K. The EPR-silent state at this temperature is attributed to a so-called polymeric phase transition. After the transition when the temperature is lowered to 293 K, the EPR signal does not appear; therefore, the transition is irreversible. This result seems to be in agreement with the other observations. The EPR spectra for the sample indicate the presence of two sites for Cu2+, and the values of EPR parameters are in accord with the literature on Cu2+-doped single crystals. Any other phase transitions could not to be observed at low temperatures down to 113 K. 相似文献
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