Influence of stereoerrors on the formation of helices during early stage crystallization of isotactic polyproyplene

Coarse-grained, on-lattice Monte Carlo simulations are performed to investigate the role of stereotacticity defects along an isotactic polypropylene chain on the formation of 3₁-helices, which form the basic crystalline order within the chain. For this reason, systems with various stereoerror configurations are studied and are compared to neat isotactic polypropylene. All systems are equilibrated above the melting temperature and are cooled to lower temperatures in a stepwise manner, making sure each system is equilibrated at every temperature. Results indicate that chain ends have the lowest probability of being found in helices. Addition of a single stereoerror (mrm) decreases the probability of five repeat units' participation in helices (the repeat unit that contains the stereoerror and two nearest repeat units on both sides). The probability profile becomes more complicated when the number of stereoerrors increases, however, the results indicate that the effects of many stereoerrors can be explained by a simple addition of the effect of each stereoerror considered individually. The results also indicate that the presence of even a single stereoerror eliminates (within the temperature range studied) the transition to longer, more stable helices observed in neat isotactic polypropylene. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3349–3360, 2007     

Trace element changes during hibernation of Drosophila melanogaster by WDXRF analyses at chilling temperature

Fruit flies (Drosophila melanogaster) were exposed to low temperature (4 °C, 3d), after controlled acclimation (15 °C, 1d) and passed to artificial hibernation. The concentrations of elements in almost 1000 mature flies were measured by Wavelength-Dispersive X-ray Fluorescence (WDXRF) spectrometry. Concentration changes of Zn, K, S, Ca (33.5%, 11.2%, 10.3% and 7.5%, respectively) and especially Cr and Mn (99.90 and 99.60) were observed. Concentrations of Cr, Zn, S and Ca increased significantly, but concentrations of Mn and K decreased in with comparison to the control group.     

An in-syringe La-coprecipitation Method for the Preconcentration of Oxo-anion Forming Elements in Seawater Prior to an ICP-MS Measurement

A lanthanum (La) coprecipitation method with low sample consumption was explored for the preconcentration of oxo-anion forming elements prior to a measurement by inductively coupled plasma mass spectrometry (ICP-MS). The preconcentration procedure was composed of two main steps: (1) the formation of a coprecipitate with the lowest possible La and (2) the redissolution of target analytes with minimal use of nitric acid, and the elimination of high concentration La from the analysis sample. Each step was performed in a 25 mL-volume syringe to reduce the sample consumption and to avoid contamination from the experimental environment. Various parameters, such as the concentration and volume of La added into the sample solution, the precipitation pH, the aging time, and the volume of HNO(3) were optimized to obtain good recoveries and high detection sensitivities for V, As, Sb, and W, which could be hardly recovered by solid-phase extraction using a chelating resin. The obtained method was evaluated through the analysis of seawater reference materials (CASS-4 and NASS-5). The recoveries exceeded 80%, and the observed values were in good agreement with the certified values.     

Pairwise-stability and Nash equilibria in network formation

Suppose that individual payoffs depend on the network connecting them. Consider the following simultaneous move game of network formation: players announce independently the links they wish to form, and links are formed only under mutual consent. We provide necessary and sufficient conditions on the network link marginal payoffs such that the set of pairwise stable, pairwise-Nash and proper equilibrium networks coincide, where pairwise stable networks are robust to one-link deviations, while pairwise-Nash networks are robust to one-link creation but multi-link severance. Under these conditions, proper equilibria in pure strategies are fully characterized by one-link deviation checks. We thank William Thomson, an associate editor and two anonymous referees for their suggestions that led to substantial improvements. We also thank Sjaak Hurkens, Bettina Klaus, Jordi Massó and Giovanni Neglia for helpful conversations. The first author gratefully acknowledges the financial support from the Spanish Ministry of Education and FEDER through grant SEJ2005-01481/ECON, the Fundación BBVA and the Barcelona Economics Program of XREA. The second author is grateful to the Netherlands Organization for Scientific Research (NWO) for its support under grant VIDI-452-06-013.     

Multielement determination of trace metals in seawater by ICP-MS with aid of down-sized chelating resin-packed minicolumn for preconcentration

The multielement determination of trace metals in seawater was carried out by inductively coupled plasma mass spectrometry (ICP-MS) with aid of a down-sized chelating resin-packed minicolumn for preconcentration. The down-sized chelating resin-packed minicolumn was constructed with two syringe filters (DISMIC 13HP and Millex-LH) and an iminodiacetate chelating resin (Chelex 100, 200-400 mesh), with which trace metals in 50 mL of original seawater sample were concentrated into 0.50 mL of 2 M nitric acid, and then 100-fold preconcentration of trace metals was achieved. Then, 0.50 mL analysis solution was subjected to the multielement determination by ICP-MS equipped with a MicroMist nebulizer for micro-sampling introduction. The preconcentration and elution parameters such as the sample-loading flow rate, the amount of 1 M ammonium acetate for elimination of matrix elements, and the amount of 2 M nitric acid for eluting trace metals were optimized to obtain good recoveries and analytical detection limits for trace metals. The analytical results for V, Mn, Co, Ni, Cu, Zn, Mo, Cd, Pb, and U in three kinds of seawater certified reference materials (CRMs; CASS-3, NASS-4, and NASS-5) agreed well with their certified values. The observed values of rare earth elements (REEs) in the above seawater CRMs were also consistent with the reference values. Therefore, the compiled reference values for the concentrations of REEs in CASS-3, NASS-4, and NASS-5 were proposed based on the observed values and reference data for REEs in these CRMs.     

Vibration control of a structure with ATMD against earthquake using fuzzy logic controllers

In this paper, fuzzy logic and PD controllers are designed for a multi-degree-of freedom structure with active tuned mass damper (ATMD) to suppress earthquake-induced vibrations. Fuzzy logic controller (FLC) is preferred because of its robust character, superior performance and heuristic knowledge use effectively and easily in active control. A fifteen-degree-of-freedom structural system is modeled with two types of actuators. These actuators are installed on the first storey and fifteenth storey which has ATMD. The system is then subjected to Kocaeli Earthquake vibrations, which are treated as disturbances. In control, linear motors are used as the active isolators. At the end of the study, the time history of the storey displacements and accelerations, ATMD displacements, control voltages, frequency responses of the both uncontrolled and the controlled structures are presented. Performance of the designed FLC has been shown for the different loads and disturbances using ground motion of the Kobe Earthquake. The results of the simulations show a good performance by the fuzzy logic controllers for different loads and the earthquakes.     

Investigation of ion-selective electrodes with neutral ionophores and ionic sites by EIS. I. Theory

Models of an ion selective electrode involving an ionophore and mobile sites in a membrane are proposed. The first model, called the phase boundary potential model, supposed thermodynamic equilibrium; it allows the concentrations of the various species to be calculated. Then, a kinetic model, which takes into account the ionic transfer at the membrane|solution interfaces, was derived. The impedance of the membrane was calculated. It shows that a membrane with nernstian behavior shows only one capacitive loop in the impedance diagram, which is related to the conductivity and dielectric properties of the material of the membrane. Non-nernstian behavior is related to slow ionic transfer at the membrane|solution interfaces or/and transport limitation of the species in the membrane. Finite rate constants of the ionic transfer lead to a capacitive loop in the middle frequency range, whereas finite rate transport leads to a diffusional impedance in the low frequency range.     

Studium des resonanz falles bei systemen linearer gewöhnlicher differentialgleichungen

Ohne Zusammenfassung