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51.
M.S. Sethi P.S. Raghavan B.S. Garg R.P. Singh Mahendra K. Gadia 《Microchemical Journal》1981,26(2):210-216
Polarography of 1,2-acenaphthaquinone monoxime has been carried out in buffers (pH 3.5–13.0) of constant ionic strength 0.5 M and 40% alcohol at 25 ± 0.5 °C. The oxime group underwent diffusion-controlled reduction (4e) over the whole pH range. The number of electrons involved in the reduction was found by coulometric method as well as by incorporating the values of diffusion coefficients, obtained by using a McBain-Dawson cell, into the Ilkovi? equation. Koutecky's method has been used to compute the kinetic parameters (αnaand ?log Kf.h) for the reduction of the oxime group and a reduction mechanism is proposed. 相似文献
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B. Raghavan M. L. Shankaranarayana S. Nagalakshmi C. P. Natarajan 《Mikrochimica acta》1972,60(6):818-822
Summary Sinalbin (Sinapinp-hydroxybenzylglucosinolate) is present in white mustard seed(sinapis alba) and on enzymatic hydrolysis liberates a sharp, hot, pungent and flavoury compound,p-hydroxybenzyl isothiocyanate (p-HBI). A new sensitive colorimetric method has been developed in which thep-HBI is reacted with sodium hydroxide to givep-hydroxybenzyl alcohol and sodium thiocyanate. The thiocyanate is converted into cyanogen bromide by reacting it with bromine. The cyanogen bromide is then treated with pyridine—benzidine reagent to give a red colour which has an absorption maximum at 518 nm. The red complex solution obeys Beer's law over the concentration range 0.1–0.5 g of SCN per ml of the solution. One mole of sinalbin gives rise to one mole of thiocyanate ion. Recovery is 90%.
Zusammenfassung Sinalbin (Sinapin-p-hydroxybenzylglucosinolat) ist ein Inhaltsstoff des Samens von weißem Senf (Sinapis alba) und bildet bei enzymatischer Hydrolyse eine scharf schmeckende, würzig riechende Verbindung, p-Hydroxybenzyl-isothiocyanat (p-HBI). Ein neues kolorimetrisches Verfahren wurde entwickelt, das auf der Reaktion von p-HBI mit Natronlauge beruht, wobei p-Hydroxybenzylalkohol und NaCNS entstehen. Dieses wird mit Brom zu Bromcyan umgesetzt, das seinerseits mit Pyridin-Benzidin eine Rotfärbung mit dem Absorptionsmaximum bei 518 nm gibt. Die Lösung dieser roten Komplexverbindung folgt dem Beer'schen Gesetz von 0,1–0,5 g SCN–/ml. Ein Mol Sinalbin entspricht einem Grammion Thiocyanat. Die Ausbeute beträgt etwa 90%.相似文献
54.
S.N. Ganguli A. Gurtu P.K. Malhotra R. Raghavan A. Subramanian M. Cerrada J. Diaz J.A. Garzon R. Hamatsu L. Montanet Ch. Defoix L. Dobrzynski P. Ladron de Guevara R. Nacash P. Petitjean B. Adeva M. Aguilar-Benitez R. Pazzi 《Nuclear Physics B》1981,183(3):295-329
annihilations, leading to the production of at least one neutral K meson in the final state, have been studied in the incident momentum region of 700–760 MeV/c. Topological cross sections and cross sections for the various exclusive final states are presented. Detailed analyses of the different final states have been carried out to study the importance of resonance production and of quasi two-body and quasi three-body processes. A detailed study of the system in the four-body final states shows that the F1 meson is a spurious effect due to systematic biases. In the momentum range investigated, the C = +1 final states are strongly suppressed. 相似文献
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S Srinivasa Raghavan 《Pramana》1979,13(2):159-162
The suitability of a soft-core radial wave function in4He calculations is tested by computing the charge form factor of the alpha particle. The free parameter in the radial function
is fixed in a photo-disintegration calculation. The results show that the soft-core function is suitable and the ground state
of4He may be described reasonably well if a suitable potential model is used with it. 相似文献
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Hong Y Webb BL Su H Mozdy EJ Fang Y Wu Q Liu L Beck J Ferrie AM Raghavan S Mauro J Carre A Müeller D Lai F Rasnow B Johnson M Min H Salon J Lahiri J 《Journal of the American Chemical Society》2005,127(44):15350-15351
This paper describes G-protein-coupled receptor (GPCR) microarrays on porous glass substrates and functional assays based on the binding of a europium-labeled GTP analogue. The porous glass slides were made by casting a glass frit on impermeable glass slides and then coating with gamma-aminopropyl silane (GAPS). The emitted fluorescence was captured on an imager with a time-gated intensified CCD detector. Microarrays of the neurotensin receptor 1, the cholinergic receptor muscarinic 2, the opioid receptor mu, and the cannabinoid receptor 1 were fabricated by pin printing. The selective agonism of each of the receptors was observed. The screening of potential antagonists was demonstrated using a cocktail of agonists. The amount of activation observed was sufficient to permit determinations of EC50 and IC50. Such microarrays could potentially streamline drug discovery by helping integrate primary screening with selectivity and safety screening without compromising the essential functional information obtainable from cellular assays. 相似文献
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