Two-photon excitation of 2,5-diphenyloxazole using a low power green solid state laser

This Letter concerns two-photon excitation of 2,5-Diphenyloxazole (PPO) upon illumination from a pulsed 532 nm solid state laser, with an average power of 30 mW, and a repetition rate of 20 MHz. A very agreeable emission spectrum position and shape has been achieved for PPO receiving one- and two-photon excitation, which suggests that the same excited state is involved for both excitation modes. Also, a perfect quadratic dependence of laser power in the emission intensity function has been recorded. We tested the application of a small solid state green laser to two-photon induced time-resolved fluorescence, revealing the emission anisotropy of PPO to be considerably higher for two-photon than for one-photon excitation.     

Structural Transformations and Spin-Crossover in [FeL2]2+ Salts (L=4-{tert-Butylsulfanyl}-2,6-di{pyrazol-1-yl}pyridine): The Influence of Bulky Ligand Substituents

4-(tert-Butylsulfanyl)-2,6-di(pyrazol-1-yl)pyridine (L) was obtained in low yield from a one-pot reaction of 2,4,6-trifluoropyridine with 2-methylpropane-2-thiolate and sodium pyrazolate in a 1:1:2 ratio. The materials [FeL₂][BF₄]₂⋅solv ( 1[BF₄]₂ ⋅solv) and [FeL₂][ClO₄]₂⋅solv ( 1[ClO₄]₂ ⋅solv; solv=MeNO₂, MeCN or Me₂CO) exhibit a variety of structures and spin-state behaviors including thermal spin-crossover (SCO). Solvent loss on heating 1[BF₄]₂ ⋅x MeNO₂ (x≈2.3) occurs in two steps. The intermediate phase exhibits hysteretic SCO around 250 K, involving a “reverse-SCO” step in its warming cycle at a scan rate of 5 K min⁻¹. The reverse-SCO is not observed in a slower 1 K min⁻¹ measurement, however, confirming its kinetic nature. The final product [FeL₂][BF₄]₂⋅0.75 MeNO₂ was crystallographically characterized, and shows abrupt but incomplete SCO at 172 K which correlates with disorder of an L ligand. The asymmetric unit of 1[BF₄]₂ ⋅y Me₂CO (y≈1.6) contains five unique complex molecules, four of which undergo gradual SCO in at least two discrete steps. Low-spin 1[ClO₄]₂ ⋅0.5 Me₂CO is not isostructural with its BF₄⁻ congener, and undergoes single-crystal-to-single-crystal solvent loss with a tripling of the crystallographic unit cell volume, while retaining the P space group. Three other solvate salts undergo gradual thermal SCO. Two of these are isomorphous at room temperature, but transform to different low-temperature phases when the materials are fully low-spin.     

Borrowing titania’s photoinduced electrons for molecular switching

正When exposed to light,titanium dioxide(titania,TiO_2)can act as a powerful catalyst for degrading a variety of organic compounds.Anatase—one of the polymorphs of TiO_2—has a band gap of 3.2 e V;exposing it to ultraviolet light causes the formation of electron-hole pairs,which,in the presence of water,can generate hydroxyl radicals—strong oxidizing agents.The photocatalytic behavior of titania has enabled     

Middle ear reconstruction estimated by recurrence plot technique

Middle ear surgery techniques have enabled to improve hearing destroyed by a disease. Despite huge improvement in instrumentation and techniques the results of hearing improvement surgery are still difficult to predict. This paper presents the results of vibrations measurements in a human middle ear obtained at the Medical University of Lublin. Vibrations of the stapes in the case of the intact ossicular chain, after cement incus rebuilding and incus interpositions are compared each other. In this aim a new approach of ossicles vibrations observation is introduced in order to complete information obtained from classical approach which bases on the transfer function. Measurements of ossicular chain vibrations are performed on fresh human temporal bone specimen using the laser doppler vibrometer. Next, after classical research, the extended analysis with the recurrence plots technique is performed.     

Cutting process of composite materials: An experimental study

This paper focuses on experimental research of milling process of the epoxide-polymer matrix composite reinforced carbon fibers (EPMC—carbon composite). An influence of two control parameters, namely feed and rotational speed, on cutting forces is investigated. The experiment is conducted on a CNC machine with feed rate ranging from 200 to 720 mm/min and rotational speed from 2000 to 8000 rpm. The experimental time series are analysed by means of the delay coordinates method in order to find stable cutting regions and to recognize the kind of behaviour. Using this information, a new model for the cutting forces is proposed that can be used to build a new regenerative vibration model for EPMC milling.     

An influence of temperature on reconstructed middle ear with shape memory prosthesis

In the paper idea of reconstructed middle ear with a prosthesis made of shape memory alloy is proposed. The new design of shape memory prosthesis is used to enable adjusting its length to individual patient’s needs which is a novel contribution of the paper. In order to make a proper fit of prosthesis, a surgeon has to adjust its size and position by cutting step by step classical prosthesis. It takes time of a operation and enlarges a period of patient’s esthesia. Therefore, a shape memory prosthesis (SMP) is proposed to shorten operation time and improve fitting through precisely selected length. A reconstructed middle ear is modelled as a two degree of freedom system with nonlinear shape memory element. Finding advisable periodic and undesirable a periodic and irregular behaviour in various temperature is the main aim of the paper. Results of the study should give an answer whether SMP can be useful in medical practice and should also explain dynamics of the middle ear with SMP. The properties of the shape memory prosthesis, in the form of helical spring, are described here by a polynomial dependence. Firstly, free vibrations are investigated and equilibrium points, next forced vibrations are studied under different parameters of external excitations and temperature range. Bifurcation analysis and stability of periodic solutions are performed in order to reveal the system behaviour. Finally, interesting dynamical findings of chaotic vibrations pure regular and regular oscillations with fluctuation are presented. However, from practical point of view only harmonic response of the stapes is advisable. That can be achieved at the normal temperature of a human body only for small excitation amplitude.     

(13)C-(13)C distance measurements in U-(13)C, (15)N-labeled peptides using rotational resonance width experiment with a homogeneously broadened matching condition

In this publication, we introduce a version of the rotational resonance width experiment with a homogeneously broadened matching condition. The increase in the bandwidth is achieved by the reduction of the proton decoupling power during mixing, which results in the reduction of zero-quantum relaxation, and broadens the rotational resonance condition. We show that one can achieve recoupling of the carbonyl-aliphatic side chain dipolar interactions band selectively, while avoiding the recoupling of strongly interacting C'-Calpha and C'-Cbeta spin pairs. The attenuation of the multi-spin effects in the presence of short zero-quantum relaxation enables a two-spin approximation to be employed for the analysis of the experimental data. The systematic error introduced by this approximation is estimated by comparing the results with a three-spin simulation. The experiment is demonstrated in [U-(13)C,(15)N]N-acetyl-L-Val-L-Leu dipeptide, where 11 distances, ranging from 2.5 to 6 A, were measured.