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21.
We study generic solutions in a non-minimally coupled to gravity scalar field cosmology. It is shown that dynamics for both canonical and phantoms scalar fields with the potential can be reduced to the dynamical system from which the exact forms for an equation of the state parameter can be derived. We have found the stationary solutions of the system and discussed their stability. Within the large class of admissible solutions we have found a non-degenerate critical points and we pointed out multiple attractor type of trajectory travelling in neighborhood of three critical points at which we have the radiation dominating universe, the barotropic matter dominating state and finally the de Sitter attractor. We have demonstrated the stability of this trajectory which we call the twister solution. Discovered evolutional path is only realized if there exist the non-minimal coupling constant. We have found simple duality relations between twister solutions in phantom and canonical scalar fields in the radiation domination phase. For the twister trajectory we have found an oscillating regime of approaching the de Sitter attractor. 相似文献
22.
Marek Wichtowski Andrzej Ziółkowski Ewa Weinert-Rączka 《Central European Journal of Physics》2008,6(3):546-554
In our work we propose a novel method of analysis of photorefractive transport equations. The method based on a perturbative
approach can be used in the case of two wave mixing and four wave mixing geometry, i.e. for the samples illuminated by interference
patterns. Presented approach can be employed for a broad range of material and experimental parameters, particularly for arbitrary
depth of light modulation pattern. The approximate analytical solution is compared with results of numerical calculations
and a good agreement practically in every case was found.
Presented at 9-th International Workshop on Nonlinear Optics Applications, NOA 2007, May 17–20, 2007, Šwinoujście, Poland 相似文献
23.
An exactly solvable vibronic coupling model is used to improve existing definitions of strong and weak vibronic coupling limits in molecules and to derive a unique correlation between the corresponding energy levels. 相似文献
24.
25.
Mohamed K. Albolkany Dr. Yang Wang Dr. Weijin Li Syeda Arooj Chun-Hui Chen Niannian Wu Yan Wang Prof. Dr. Radek Zbořil Prof. Dr. Roland A. Fischer Prof. Dr. Bo Liu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(48):21683-21688
Graphitic carbon nitride quantum dots (g-CNQDs) are highly promising photoresponsive materials. However, synthesis of monodispersed g-CNQDs remains challenging. Here we report the dual function of MOF [Cu3BTC2] (HKUST-1) as a catalyst and template simultaneously to prepare g-CNQDs under mild conditions. Cyanamide (CA), a graphitic carbon nitride precursor, catalytically dimerized inside the larger MOF cavities at 90 °C and condensed into g-CNQDs at 120 °C in a controlled fashion. The HKUST-1 template was stable under the reaction conditions, leading to uniform g-CNQDs with a particle size of 2.22±0.68 nm. The as prepared g-CNQDs showed photoluminescence emission with a quantum yield of 3.1 %. This concept (MOF dual functionality) for catalyzing CA polycondensation (open metal sites (OMSs) effect) and controlling the produced particle size (pore-templating effect), together with the tunable MOF porosity, is expected to produce unique g-CNQDs with controllable size, morphology, and surface functionality. 相似文献
26.
27.
Yan-Cong Chen Yan Meng Yan-Jie Dong Xiao-Wei Song Guo-Zhang Huang Chuan-Lei Zhang Zhao-Ping Ni Jakub Navaík Ondej Malina Radek Zboil Ming-Liang Tong 《Chemical science》2020,11(12):3281
Among responsive multistable materials, spin crossover (SCO) systems are of particular interest for stabilizing multiple spin states with various stimulus inputs and physical outputs. Here, in a 2D Hofmann-type coordination polymer, [Fe(isoq)2{Au(CN)2}2] (isoq = isoquinoline), a medium-temperature annealing process is introduced after light/temperature stimulation, which accesses the hidden multistability of the spin state. With the combined effort of magnetic, crystallographic and Mössbauer spectral investigation, these distinct spin states are identified and the light- and temperature-assisted transition pathways are clarified. Such excitation-relaxation and trapping-relaxation joint mechanisms, as ingenious interplays between the kinetic and thermodynamic effects, uncover hidden possibilities for the discovery of multistable materials and the development of multistate intelligent devices.Two new two-stage manipulation protocols, namely light- and temperature-assisted spin state annealing (LASSA/TASSA), are applied to a spin crossover coordination polymer, [Fe(isoq)2{Au(CN)2}2], revealing the hidden multistability of spin states. 相似文献
28.
Klara Markova Klaudia Chmelova Srgio M. Marques Philippe Carpentier David Bednar Jiri Damborsky Martin Marek 《Chemical science》2020,11(41):11162
Computational design of protein catalysts with enhanced stabilities for use in research and enzyme technologies is a challenging task. Using force-field calculations and phylogenetic analysis, we previously designed the haloalkane dehalogenase DhaA115 which contains 11 mutations that confer upon it outstanding thermostability (Tm = 73.5 °C; ΔTm > 23 °C). An understanding of the structural basis of this hyperstabilization is required in order to develop computer algorithms and predictive tools. Here, we report X-ray structures of DhaA115 at 1.55 Å and 1.6 Å resolutions and their molecular dynamics trajectories, which unravel the intricate network of interactions that reinforce the αβα-sandwich architecture. Unexpectedly, mutations toward bulky aromatic amino acids at the protein surface triggered long-distance (∼27 Å) backbone changes due to cooperative effects. These cooperative interactions produced an unprecedented double-lock system that: (i) induced backbone changes, (ii) closed the molecular gates to the active site, (iii) reduced the volumes of the main and slot access tunnels, and (iv) occluded the active site. Despite these spatial restrictions, experimental tracing of the access tunnels using krypton derivative crystals demonstrates that transport of ligands is still effective. Our findings highlight key thermostabilization effects and provide a structural basis for designing new thermostable protein catalysts.Illustration of cooperative thermostabilization effects of the double-lock system that: (i) induced backbone changes, (ii) closed the molecular gates, (iii) reduced the volumes of the main and slot access tunnels, and (iv) occluded the active site. 相似文献
29.
A. Vértes Z. Klenesár Gy. Vankó T. Marek K. Süvegh Z. Homonnay E. Kuzmann 《Journal of Radioanalytical and Nuclear Chemistry》2000,243(1):241-253
The paper offers three applications of nuclear methods in the research of chemical structure. First, progress in positron annihilation spectroscopy is illustrated by a positron beamline study, which obtained results that are not available through conventional experiments. The positron beam was used for the study of Langmuir-Blodgett (LB) films containing 4-58 layers of arachidic acid and its salts. These measurements have shown that this emerging technique is capable of characterizing even such elusive systems. Second, the potential of Mössbauer spectroscopy to answer current challenges of solid state chemistry are shown in a study on perovskites of recent interest. 151Eu Mössbauer spectroscopy was used to study the effect of Pr substitution in EuBa2Cu3O7-. It was shown that the introduction of Pr into the rare earth site as well as into the Ba site results in the appearance of extra electrons both in the copper oxide planes and at the 4f shell of Eu cations. The observed effects were explained by the hole filling effect of Pr. Finally, a survey is presented on the recently developed techniques for nuclear resonant scattering of synchrotron radiation, an exciting and very rapidly developing extension to conventional Mössbauer spectroscopy. An interesting new result is that nuclear inelastic scattering experiments performed on solutions of 57Fe complexes show contribution from vibrations rather than from diffusion to the inelastic spectra. 相似文献
30.