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81.
Stereoselective functionalization of pyrrolidinone moiety towards the synthesis of salinosporamide A
Julien Barbion Geoffroy Sorin Mohamed Selkti Esther Kellenberger Rachid Baati Stefano Santoro Fahmi Himo Ange Pancrazi Marie-Isabelle Lannou Janick Ardisson 《Tetrahedron》2012,68(32):6504-6512
An important feature of the synthesis of salinosporamide A, a potent proteasome inhibitor, is the establishment of the quaternary stereocenter at C3. A new route has been developed based on the methylation of a functionalized pyrrolidinone. Direct methylation reaction led to the unwanted diastereomer; however, by means of a Corey–Chaykovsky reaction followed by LiAlH4 epoxide opening, the desired alcohol was obtained. The pyrrolidinone was elaborated through a key allylation reaction between a tertiary allyltitanium reagent and an aldehyde bearing a spiroketal moiety in α-position. 相似文献
82.
Khalil Al Mamari Hamid Ennajih Hafid Zouihri Rachid Bouhfid Seik Weng Ng El Mokhtar Essassi 《Tetrahedron letters》2012,53(18):2328-2331
The 1,3-dipolar cycloaddition of 1-allyl-5-haloisatin derivatives as dipolarophiles with the azomethine ylides generated in situ from N-allylisatin and l-proline to furnish novel dispiro-oxindoles has been investigated. The structures and relative stereochemistry of both types of cycloadducts were confirmed by single crystal X-ray diffraction, 1H and 13C NMR spectroscopy and mass spectrometry. 相似文献
83.
Houcine Ammar Fatma Abdelkafi Souhir Abid Bouchra Benjelloum-Mlayah Rachid El Gharbi Michel Delmas 《Chemistry of Natural Compounds》2012,48(1):99-102
Alfa grass pulping was successfully performed in hydro-organic acid medium under mild conditions (107°C, atmospheric pressure, cooking
time: 3 h). Use of an acetic acid/formic acid/water mixture as pulping liquor was perfectly suitable for selective isolation
of pulp, lignin, and hemicelluloses. The unbleached pulp obtained in good yield was first delignified by peroxyacids in organic
acid medium and then bleached with hydrogen peroxide in a basic medium to give pulp offering good physico-chemical and mechanical
characteristics. 相似文献
84.
Invariant Manifold Approach for the Stabilization of Nonholonomic Chained Systems: Application to a Mobile Robot 总被引:1,自引:0,他引:1
In this paper it is shown that a class ofn-dimensional nonholonomic chained systems can bestabilized using the invariant manifold approach. First, we derive aninvariant manifold for this class of systems and we show that, once onit, all the closed-loop trajectories tend to the origin under a linearsmooth time-invariant state feedback. Thereafter, it is shown that thismanifold can be made attractive by means of a discontinuoustime-invariant state feedback. Finally, a mobile robot is taken as anexample demonstrating the effectiveness of our study. 相似文献
85.
Yassine Kaddouri Redouane Benabbes Sabir Ouahhoud Magda Abdellattif Belkheir Hammouti Rachid Touzani 《Molecules (Basel, Switzerland)》2022,27(9)
Bayoud disease affects date palms in North Africa and the Middle East, and many researchers have used various methods to fight it. One of those methods is the chemical use of synthetic compounds, which raises questions centred around the compounds and common features used to prepare targeted molecules. In this review, 100 compounds of tested small molecules, collected from 2002 to 2022 in Web of Sciences, were divided into ten different classes against the main cause of Bayoud disease pathogen Fusarium oxysporum f. sp. albedinis (F.o.a.) with structure–activity relationship (SAR) interpretations for pharmacophore site predictions as (δ−···δ−), where 12 compounds are the most efficient (one compound from each group). The compounds, i.e., (Z)-1-(1.5-Dimethyl-1H-pyrazole-3-yl)-3-hydroxy but-2-en-1-one 7, (Z)-3-(phenyl)-1-(1,5-dimethyl-1H-pyrazole-3-yl)-3-hydroxyprop-2-en-1-one 23, (Z)-1-(1,5-Dimethyl-1H-pyrazole-3-yl)-3-hydroxy-3-(pyridine-2-yl)prop-2-en-1-one 29, and 2,3-bis-[(2-hydroxy-2-phenyl)ethenyl]-6-nitro-quinoxaline 61, have antifungal pharmacophore sites (δ−···δ−) in common in N1---O4, whereas other compounds have only one δ− pharmacophore site pushed by the donor effect of the substituents on the phenyl rings. This specificity interferes in the biological activity against F.o.a. Further understanding of mechanistic drug–target interactions on this subject is currently underway. 相似文献
86.
The stability and singularity problem of agile small satellite (ASS) with actuator failure is discussed in this paper. Firstly, the three-axis stabilized controller of an ASS is designed, where micro control moment gyros (MCMG's) in pyramid configuration (PC) is used as the actuator. By using the same controller and steering law, the control results before and after one gyro fails are compared by simulation. The variation of singular momentum envelope before and after one gyro fails is also compared. The simulation results show that the failure intensively decreases the capacity of output torque, which leads to the emergence of more singular points and the rapid saturation of MCMG's. Finally, the parameters of system controller are changed to compare the control effect. 相似文献
87.
88.
89.
The Relationship between the Relative Solvating Power of Electrolytes and Shuttling Effect of Lithium Polysulfides in Lithium–Sulfur Batteries
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Dr. Chi‐Cheung Su Meinan He Rachid Amine Zonghai Chen Dr. Khalil Amine 《Angewandte Chemie (International ed. in English)》2018,57(37):12033-12036
Relative solvating power, that is, the ratio of the coordination ratios between a solvent and the reference solvent, was used to probe the quantitative structure–activity relationship of electrolyte solvents and the lithium polysulfide (LiPS) dissolution in lithium–sulfur batteries. Internally referenced diffusion‐ordered nuclear magnetic resonance spectroscopy (IR‐DOSY) was used to determine the diffusion coefficient and coordination ratio, from which the relative solvating power can be easily measured. The higher the relative solvating power of an ethereal solvent, the more severe will be the LiPS dissolution and the lower the coulombic efficiency of the lithium–sulfur battery. A linear relationship was established between the logarithm of relative solvating power of a solvent and the degree of LiPS dissolution, rendering relative solvating power an important parameter in choosing the electrolyte solvent for lithium–sulfur batteries. 相似文献
90.
El Antri A Messouri I Bouktaib M El Alami R Bolte M El Bali B Lachkar M 《Molecules (Basel, Switzerland)》2004,9(8):650-657
Two tetrahydroisoquinoline alkaloids were extracted from the alkaloid fraction of a methanol extract of the seeds of Calycotome Villosa Subsp. intermedia. Their structures were established as (R)-1-hydroxymethyl-7-8-dimethoxy-1,2,3,4-tetrahydro- isoquinoline (1) and (S)-7-hydroxymethyl-2-3-dimethoxy-7,8,9,10-tetrahydroisoquinoline chloride (2) by spectroscopic techniques and X-ray diffraction analysis. 相似文献