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51.
Villie Flari Qasim Chaudhry Rabin Neslo Roger Cooke 《Journal of nanoparticle research》2011,13(5):1813-1831
Currently, risk assessment of nanotechnology-enabled food products is considered difficult due to the large number of uncertainties involved. We developed an approach which could address some of the main uncertainties through the use of expert judgment. Our approach employs a multi-criteria decision model, based on probabilistic inversion that enables capturing experts’ preferences in regard to safety of nanotechnology-enabled food products, and identifying their opinions in regard to the significance of key criteria that are important in determining the safety of such products. An advantage of these sample-based techniques is that they provide out-of-sample validation and therefore a robust scientific basis. This validation in turn adds predictive power to the model developed. We achieved out-of-sample validation in two ways: (1) a portion of the expert preference data was excluded from the model’s fitting and was then predicted by the model fitted on the remaining rankings and (2) a (partially) different set of experts generated new scenarios, using the same criteria employed in the model, and ranked them; their ranks were compared with ranks predicted by the model. The degree of validation in each method was less than perfect but reasonably substantial. The validated model we applied captured and modelled experts’ preferences regarding safety of hypothetical nanotechnology-enabled food products. It appears therefore that such an approach can provide a promising route to explore further for assessing the risk of nanotechnology-enabled food products. 相似文献
52.
The ac small signal capacitance of Schottky structures obtained on undoped (106 Ωcm) and chlorine compensated (108Ωcm) p-type CdTe as well as on low resistivity (300 to 1000 Ωcm) n-type material is analyzed. For the lower resistivity p- and n-type samples, deviations from the expected behaviour are observed, which are explained in terms of a model taking into account the existence of a predominating deep level. Its energy level, capture cross-section and trap density are experimentally determined and compared to values given by other methods. For the chlorine compensated CdTe a long time polarization is demonstrated. 相似文献
53.
Teichmüller theory for super Riemann surfaces is rigorously developed using the supermanifold theory of Rogers. In the case of trivial topology in the soul directions, relevant for superstring applications, the following results are proven. The super Teichmüller space is a complex super-orbifold whose body is the ordinary Teichmüller space of the associated Riemann surfaces with spin structure. For genusg>1 it has 3g-3 complex even and 2g-2 complex odd dimensions. The super modular group which reduces super Teichmüller space to super moduli space is the ordinary modular group; there are no new discrete modular transformations in the odd directions. The boundary of super Teichmüller space contains not only super Riemann surfaces with pinched bodies, but Rogers supermanifolds having nontrivial topology in the odd dimensions as well. We also prove the uniformization theorem for super Riemann surfaces and discuss their representation by discrete supergroups of Fuchsian and Schottky type and by Beltrami differentials. Finally we present partial results for the more difficult problem of classifying super Riemann surfaces of arbitrary topology.Enrico Fermi Fellow. Research supported by the NSF (PHY 83-01221) and DOE (DE-AC02-82-ER-40073). 相似文献
54.
Steve Rabin John Stillian Victor Barreto Keith Friedman Mahmood Toofan 《Journal of chromatography. A》1993,640(1-2):97-109
This paper discusses the newest advancement in chemical suppression preceding conductivity detection. The new suppressor uses electrolysis of deionized water to generate the required acid or base for the suppression neutralization reaction and utilizes the electrical field to enhance, through electrodialysis, the suppressor's capacity for neutralization. The suppressor is able to accommodate eluents as high as 150 mM NaOH, without the need for a separate regenerant solution, by recycling the conductivity detector cell waste to the regenerant and electrolysing the water in the waste stream to the required acid or base. The device is able to use deionized water as regenerant and neutralize the eluent stream to deionized water without the expected increase in resistance by employing ion exchange material in intimate contact with the electrodes and the membranes. The current is carried with low resistance through the ion-exchange material via ion transport from one ion-exchange site to another. 相似文献
55.
We calculate the Komar energy E for a noncommutative inspired Schwarzschild black hole. A deformation from the conventional identity E = 2ST H is found in the next to leading order computation in the noncommutative parameter θ (i.e. \({\mathcal{O}(\sqrt{\theta}e^{-M^2/\theta})}\)) which is also consistent with the fact that the area law now breaks down. This deformation yields a nonvanishing Komar energy at the extremal point T H = 0 of these black holes. We then work out the Smarr formula, clearly elaborating the differences from the standard result M = 2ST H , where the mass (M) of the black hole is identified with the asymptotic limit of the Komar energy. Similar conclusions are also shown to hold for a deSitter–Schwarzschild geometry. 相似文献
56.
Bissessur R Liu PK White W Scully SF 《Langmuir : the ACS journal of surfaces and colloids》2006,22(4):1729-1734
Herein we report on the intercalation of polyaniline, poly(2-ethylaniline), and poly(2-propylaniline) into graphite oxide. This was achieved by taking advantage of the exfoliation/reconstruction properties of the layered host. The resulting intercalates were characterized by powder X-ray diffraction and thermogravimetric analysis. 相似文献
57.
Based on an estimate of the knot entropy of a wormlike chain we predict that the interplay of bending energy and confinement entropy will result in a compact metastable configuration of the knot that will diffuse, without spreading, along the contour of the semiflexible polymer until it reaches one of the chain ends. Our estimate of the size of the knot as a function of its topological invariant (ideal aspect ratio) agrees with recent experimental results of knotted dsDNA. Further experimental tests of our ideas are proposed. 相似文献
58.
Alaa S. Abd‐El‐Aziz Amani A. Abdelghani Brian D. Wagner Rabin Bissessur 《Macromolecular rapid communications》2019,40(1)
The design of dendrimers with various chromophores has attracted significant attention in light of the dual effect of the luminescence of the chromophores and the morphology of the synthesized dendrimers. Recent developments in this field stem from their wide potential applications, including organic light‐emitting diodes, photonic switches and upconversion lasers, as well as sensors and electronic devices. The focus of this comprehensive review is on the design and properties of various classes of light‐harvesting dendrimeric materials. 相似文献
59.
Justine Pallu Dr. Charlie Rabin Geordie Creste Dr. Mathieu Branca Dr. François Mavré Dr. Benoît Limoges 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(31):7534-7546
Herein, a new molecular autocatalytic reaction scheme based on a H2O2-mediated deprotection of a boronate ester probe into a redox cycling compound is described, generating an exponential signal gain in the presence of O2 and a reducing agent or enzyme. For such a purpose, new chemosensing probes built around a naphthoquinone/naphthohydroquinone redox-active core, masked by a self-immolative boronic ester protecting group, were designed. With these probes, typical autocatalytic kinetic traces with characteristic lags and exponential phases were obtained by using either UV/Visible or fluorescence optical detection, or by using electrochemical monitoring. Detection of concentrations as low as 0.5 μm H2O2 and 0.5 nm of a naphthoquinone derivative were achieved in a relatively short time (<1 h). From kinetic analysis of the two cross-activated catalytic loops associated with the autocatalysis, the key parameters governing the autocatalytic reaction network were determined, indirectly showing that the analytical performances are currently limited by the slow nonspecific self-deprotection of boronate probes. Collectively, the present results demonstrate the potential of this new exponential molecular amplification strategy, which, owing to its generic nature and modularity, is quite promising for coupling to a wide range of bioassays involving H2O2 or redox cycling compounds, or for use as a new building block in the development of more complex chemical reaction networks. 相似文献
60.
Alaa S. Abd-El-Aziz Maysun R. Benaaisha Mohammed S. M. Abdelbaky David Martinez-Blanco Santiago García-Granda Amani A. Abdelghani Laila H. Abdel-Rahman Rabin Bissessur 《Molecules (Basel, Switzerland)》2021,26(21)
The development of synthesis methods to access advanced materials, such as magnetic materials that combine multimetallic phosphide phases, remains a worthy research challenge. The most widely used strategies for the synthesis of magnetic transition metal phosphides (TMPs) are organometallic approaches. In this study, Fe-containing homometallic dendrimers and Fe/Co-containing heterometallic dendrimers were used to synthesize magnetic materials containing multimetallic phosphide phases. The crystalline nature of the nearly aggregated particles was indicated for both designed magnetic samples. In contrast to heterometallic samples, homometallic samples showed dendritic effects on their magnetic properties. Specifically, saturation magnetization (Ms) and coercivity (Hc) decrease as dendritic generation increases. Incorporating cobalt into the homometallic dendrimers to prepare the heterometallic dendrimers markedly increases the magnetic properties of the magnetic materials from 60 to 75 emu/g. Ferromagnetism in homometallic and heterometallic particles shows different responses to temperature changes. For example, heterometallic samples were less sensitive to temperature changes due to the presence of Co2P in contrast to the homometallic ones, which show an abrupt change in their slopes at a temperature close to 209 K, which appears to be related to the Fe2P ratios. This study presents dendrimers as a new type of precursor for the assembly of magnetic materials containing a mixture of iron- and cobalt-phosphides phases with tunable magnetism, and provides an opportunity to understand magnetism in such materials. 相似文献