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111.
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K. G. Schulz G. Kunisch H. Siegfried R. Otto A. Götz S. Rosier B. Lampe R. Deplanaque F. Eckhardt D. A. Coleman S. R. Snider J. De Clerk F. Tombeur Olli Ant-Wuorinen und F. M. Wieninger 《Fresenius' Journal of Analytical Chemistry》1937,109(1-2):60-63
Ohne Zusammenfassung 相似文献
113.
Anthony W. Coleman C. Mitchell Means Simon G. Bott Jerry L. Atwood 《Journal of chemical crystallography》1990,20(2):199-201
[NBu4][Br3] interacts with C6H6 to form an air-stable liquid clathrate. The tribromide anion reacts with phenol to give para-bromophenol in>95% yield. The HBr which is generated in the reaction combines with the Br– anion to form [Br-H-Br]–. The latter forms the basis for a new liquid clathrate, [NBu4][Br-H-Br]·n C6H6. The parent salt, [NBu4][Br3], crystallizes in the monoclinic space group C2/c witha=12.983(5),b=10.380(7),c=16.222(6) Å,=93.93(3)°, andD
c
=1.47 g cm–3 forZ=4. The final R value is 0.068 based on 787 observed reflections. 相似文献
114.
Coleman WM 《Journal of chromatographic science》2006,44(3):167-173
For the first time, relative distributions of optical and geometrical isomers in selected propylene glycol acetals are determined. Resolution of the four acetal isomers possible through the reaction of racemic propylene glycol (PG) with selected aldehydes is demonstrated. The four isomers are ascribed to the presence of syn and anti geometrical isomers for each optically active PG acetal enantiomer. Thus, the (+) and well as (-) enantiomer are found to have a pair of syn and anti geometrical isomers. The ratio of the (+) and (-) isomers in the product remains at an approximate 50:50 ratio, as expected. However, somewhat unexpectedly, the syn/anti geometrical isomer ratio systematically varies with the nature of the substituent comprising the side chain of the aldehyde. Mechanisms involving electronic and minimal steric effects are advanced as possible reasons for the change in the syn/anti PG acetal ratios. 相似文献
115.
[reaction: see text] A unified strategy for the divergent and stereocontrolled introduction of the (E)- and (Z)-enamide side-chains of oximidines I, II, and III, salicylihalamides A and B, lobatamides A and D, and CJ-12,950 is detailed. The synthesis relied on the copper-promoted C-N coupling of (E)- and (Z)-vinyl iodides with a protected maleimide hemiaminal followed by deprotection and reaction of the resulting (E)- or (Z)-enelactam hemiaminals with O-methylhydroxylamine or propylidenetriphenylphosphorane. 相似文献
116.
Hendricks K.J. Haworth M.D. Englert T. Shiffler D. Baca G. Coleman P.D. Bowers L. Lemke R.W. Spencer T.A. Arman M.J. 《IEEE transactions on plasma science. IEEE Nuclear and Plasma Sciences Society》1998,26(3):320-325
The Air Force Research Laboratory RKO source has recently demonstrated the ability to convert electron beam power to RF power until the termination of the electron beam pulse, achieving a power of 1.5 GW at an energy of 170 J. These results represent an increase in power of 25-30% in power and energy extracted from this source. This paper discusses the principal research areas encountered in lengthening the RF pulse (FWHM) from 50 ns to the present 120 ns and the associated increase in the RF energy 相似文献
117.
Patrick Shahgaldian Anthony W. Coleman Beth Rather Michael J. Zaworotko 《Journal of inclusion phenomena and macrocyclic chemistry》2005,52(3):241-245
The crystal structure of para-octanoylcalix-[4]-arene·2 tetrahydrofuran complex reveals double inclusion of the guest molecules, one deep in the aromatic cavity and the other held in a four-fingered molecular hand formed by the aliphatic chains, the inclusion changes the molecular packing from a bilayer system in the absence of guest, to a head-to-tail antiparallel chain packing. 相似文献
118.
D. C. Coleman 《Analytical and bioanalytical chemistry》1997,357(2):209-213
In this article a brief overview of the World Wide Web (WWW) is given, with some examples of the kind of information and
services pertaining to analytical chemistry that can be found there. An existing WWW site that has been set up for analytical
chemists is used as a case in point. The article concludes with a brief look at some of the issues raised by publishing on
the Internet.
Received:15 January 1996 / Accepted: 28 January 1996 相似文献
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