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11.
Kriti Pathak Sourav Gayen Suvam Saha Chandan Nandi Shivankan Mishra Prof. Dr. Sundargopal Ghosh 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(18):e202104393
Treatment of [Cp*RuCl2]2, 1 , [(COD)IrCl]2, 2 or [(p-cymene)RuCl2]2, 3 (Cp*=η5-C5Me5, COD= 1,5-cyclooctadiene and p-cymene=η6-iPrC6H4Me) with heterocyclic borate ligands [Na[(H3B)L], L1 and L2 ( L1 : L=amt, L2 : L=mp; amt=2-amino-5-mercapto-1,3,4-thiadiazole, mp=2-mercaptopyridine) led to the formation of borate complexes having uncommon coordination. For example, complexes 1 and 2 on reaction with L1 and L2 afforded dihydridoborate species [LAM(μ-H)2BHL] 4 – 6 ( 4 : LA=Cp*, M=Ru, L=amt; 5 : LA=Cp*, M=Ru, L=mp; 6 : LA=COD, M=Ir, L=mp). On the other hand, treatment of 3 with L2 yielded cis- and trans-bis(dihydridoborate) species, [Ru{(μ-H)2BH(mp)}2], cis- 7 and trans- 7 . The isolation and structural characterization of fac- and mer-[Ru{(μ-H)2BH(mp)}{(μ-H)BH(mp)2}], 8 from the same reaction offered an insight into the behaviour of these dihydridoborate species in solution. Fascinatingly, despite having reduced natural charges on Ru centres both at cis-and trans- 7 , they underwent hydroboration reaction with alkynes that yielded both Markovnikov and anti-Markovnikov addition products, 10 a – d . 相似文献
12.
Rumpa Chakraborty Arpita Mondal R. Gayen 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2016,67(5):115
In this paper, we present an alternative method to investigate scattering of water waves by a submerged thin vertical elastic plate in the context of linear theory. The plate is submerged either in deep water or in the water of uniform finite depth. Using the condition on the plate, together with the end conditions, the derivative of the velocity potential in the direction of normal to the plate is expressed in terms of a Green’s function. This expression is compared with that obtained by employing Green’s integral theorem to the scattered velocity potential and the Green’s function for the fluid region. This produces a hypersingular integral equation of the first kind in the difference in potential across the plate. The reflection coefficients are computed using the solution of the hypersingular integral equation. We find good agreement when the results for these quantities are compared with those for a vertical elastic plate and submerged and partially immersed rigid plates. New results for the hydrodynamic force on the plate, the shear stress and the shear strain of the vertical elastic plate are also evaluated and represented graphically. 相似文献
13.
Dr. Srestha Basu Archismita Hajra Chirantan Gayen Prof. Anumita Paul 《Chemphyschem》2020,21(8):809-813
Herein, we report discrimination of dicarboxylic acids – fumaric acid (FA) and maleic acid (MA) – exhibiting geometrical isomerism, using nanoclusters based luminescent probe having excitation under broad day light. The luminescent probe was designed via complexation reaction between zinc ions and ligands (mercaptopropioinc acid; MPA) stabilizing the gold nanoclusters. This resulted in formation of nanoaggregates exhibiting bright green luminescence upon excitation at 450 nm capable of discriminating between FA and MA upto nanomolar level. The basis of discrimination has been attributed to deprotonation of FA and MA following interaction with MPA moieties present on the surface of the nanoaggregates and being governed by the stability of the respective conjugate base of the geometrical isomers of the dicarboxylic acids. As a consequence of different extent of deprotonation of FA and MA upon interaction with the cluster aggregates, different effect on the luminescence of the aggregates was observed, thus enabling discernible fluorimetric discrimination between FA and MA under visible light excitation. 相似文献
14.
High-average-power kilohertz-repetition-rate sub-100-fs Ti:sapphire amplifier system 总被引:1,自引:0,他引:1
We report on a femtosecond Ti:sapphire laser amplifier system that generates pulse energies >5 mJ at a 1-kHz repetition rate. The system consists of regenerative and multipass amplifiers and uses the technique of chirped-pulse amplification. When the system was seeded with 70-fs pulses at 800 nm from a self-mode-locked Ti:sapphire oscillator, amplified pulses of 94-fs duration at a repetition rate of 1 kHz and an average output power of 5.4 W were produced. The amplified pulse-repetition rate is variable from 250 Hz to 3 kHz. Pulse energies of >7.5 mJ were obtained at 500 and 250 Hz. 相似文献
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16.
TORBJØRN LORENTZEN 《Natural Resource Modeling》2008,21(3):416-435
Abstract Global warming is expected to affect the ecosystem in the Northeast Atlantic, and substantial changes will also affect the aquaculture industry. Farming of salmon and trout is the biggest aquaculture industry in Norway, with an export value of about 3 billion US dollars in 2007. The objective of the paper is to analyze the potential economic effect a general increase in sea temperature can have on the Norwegian salmon aquaculture industry. The assessment of the economic impact of global warming is made possible by estimating a growth function, which explicitly includes sea water temperature. The analysis compares the economic effect of a climate change on fish farming plants in the south and the north of Norway. The scenarios are based on a model with monthly seasonal variation in temperature. 相似文献
17.
18.
Gayen Rupanwita; Mandal B. N.; Chakrabarti A. 《IMA Journal of Applied Mathematics》2006,71(6):811-831
** Corresponding author. Email: biren{at}isical.ac.in
The problem of water wave scattering by two sharp discontinuitiesin the surface boundary conditions involving infinitely deepwater is examined here by reducing it to two coupled Carleman-typesingular integral equations. The discontinuities arise due tothe presence of two types of non-interacting materials floatingon the surface, one type being in the form of an infinite stripof finite width sandwiched between another type. The non-interactingmaterials form an inertial surface which is a mass-loading modelof floating ice and is regarded as a material of uniform surfacedensity having no elastic property. The two integral equationsare solved approximately by assuming the two discontinuitiesto be widely separated, and approximate analytical expressionsfor the reflection and transmission coefficients are also obtained.This problem has applications in wave propagation through stripsof frazil or pancake ice modelled as floating inertial surfaces.Numerical results for the reflection coefficient are depictedgraphically against the wave number for different values ofthe surface densities of the two types of floating materials.The main feature of the graphs is the oscillatory nature ofthe reflection coefficient and occurrence of zero reflectionfor an increasing sequence of discrete values of the wave number.A direct analytical treatment to solve the integral equationsnumerically, when the separation length between the two discontinuitiesis arbitrary, is also indicated. For the case of more than twodiscontinuities the solution methodology of the correspondingscattering problem is described briefly. 相似文献
19.
Ab initio Hartree–Fock calculations are reported for the chemisorption of K on Ag using three different types of clusters to model the system. Geometry optimization is done in 4 degrees of freedom. It is found that since there is an absence of complete charge transfer between the adsorbate and substrate, the interaction can be interpreted as being predominately covalent in nature. 相似文献
20.
C. Krishnakumar P. Revathi K. K. Nandy K. Suresh Kumar T. Kumar J. K. Gayen B. Shreekumar P. K. Dey 《Journal of Radioanalytical and Nuclear Chemistry》2013,295(2):1019-1022
Nuclear fuels should meet some specified characteristics to achieve their better performance in the reactor. Hence controlling and monitoring of trace level elements in the fuel materials are essential. Atomic emission spectroscopic methods are most popular for the trace level analysis. An ICP-AES procedure is described here for the trace level impurity analysis of PuO2 produced through PUREX process. To avoid the Pu interference in the impurity analysis, initially the Pu was separated by extraction chromatography using TOPO impregnated XAD-4 resin. Magnitude of Pu interference in the impurities spectra lines was investigated. Moreover the recovery of impurity elements using the resin was established. 相似文献