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81.
82.
R.M. Freeman F. Haas M.-P. Nicoli A. Morsad Z. Basrak 《The European Physical Journal A - Hadrons and Nuclei》1999,4(3):239-244
It has been noticed that a distinct resemblance exists at large angles among angular distributions measured for reaction
channels at the energies of some resonance-like structures in the 12C+12C and 14C+16O systems. It is pointed out that such forms are typical of a diffraction pattern of a broad band of coherent partial waves.
Received: 5 October 1998 / Revised version: 8 December 1998 相似文献
83.
New algorithms for parallel one-dimensional globally adaptive quadrature are developed. The algorithms are implemented on
a Kendall Square Research KSR-1 parallel computer and numerical results are presented. The most successful algorithm gives
significant speedups on a range of hard problems, including ones with singular integrands.
Both authors acknowledge the support of the EEC Esprit Basic Research Action Programme, Project 6634 (APPARC).
The second author acknowledges the support of the NATO Collaborative Research Grant 920037. 相似文献
84.
N. Aissaoui F. Haas R. M. Freeman C. Beck A. Morsad B. Djerroud R. Čaplar G. A. Monnehan A. Hachem M. Youlal 《Zeitschrift für Physik A Hadrons and Nuclei》1994,348(3):237-238
The 16 O+ 15 N reaction products have been studied by the γ-ray detection method in the CM energy range 15.5 to 36.1 MeV and by the kinematical coincidence method at energies ranging from E CM =20.6 to 33.5MeV. The γ-ray yield excitation function of the 16O 3? inelastic channel shows the existence of resonant structures. Two structures with ~ 1.6 MeV width are observed in the large angle elastic scattering excitation function, they are correlated with the resonances seen in the inelastic channel. Angular momentum assignments were made from the elastic backward angular distributions. 相似文献
85.
Helmut Sengstschmid Heinz Sterk Ray Freeman 《Journal of magnetic resonance (San Diego, Calif. : 1997)》1998,131(2):315-326
An automated scheme is described which locates the centers of cross peaks in two-dimensional correlation spectra, even under conditions of severe overlap. Double-quantum-filtered correlation (DQ-COSY) spectra have been investigated, but the method is also applicable to TOCSY and NOESY spectra. The search criterion is the intrinsic symmetry (or antisymmetry) of cross-peak multiplets. An initial global search provides the preliminary information to build up a two-dimensional “chemical shift grid.” All genuine cross peaks must be centered at intersections of this grid, a fact that reduces the extent of the subsequent search program enormously. The program recognizes cross peaks by examining the symmetry of signals in a test zone centered at a grid intersection. This “symmetry filter” employs a “lowest value algorithm” to discriminate against overlapping responses from adjacent multiplets. A progressive multiplet subtraction scheme provides further suppression of overlap effects. The processed two-dimensional correlation spectrum represents cross peaks as points at the chemical shift coordinates, with some indication of their relative intensities. Alternatively, the information is presented in the form of a correlation table. The authenticity of a given cross peak is judged by a set of “confidence criteria” expressed as numerical parameters. Experimental results are presented for the 400-MHz double-quantum-filtered COSY spectrum of 4-androsten-3,17-dione, a case where there is severe overlap. 相似文献
86.
We prove that the variance of the error function in the shifted circle problem, as a function of the shift, is a continuous function which has a sharp local maximum with infinite derivatives at every rational point on a plane. 相似文献
87.
Kazukiyo Nagai Lora G. Toy Benny D. Freeman Masahiro Teraguchi Giseop Kwak Toshio Masuda Ingo Pinnau 《Journal of Polymer Science.Polymer Physics》2002,40(19):2228-2236
The gas permeability and n‐butane solubility in glassy poly(1‐trimethylgermyl‐1‐propyne) (PTMGP) are reported. As synthesized, the PTMGP product contains two fractions: (1) one that is insoluble in toluene and soluble only in carbon disulfide (the toluene‐insoluble polymer) and (2) one that is soluble in both toluene and carbon disulfide (the toluene‐soluble polymer). In as‐cast films, the gas permeability and n‐butane solubility are higher in films prepared from the toluene‐soluble polymer (particularly in those films cast from toluene) than in films prepared from the toluene‐insoluble polymer and increase to a maximum in both fractions after methanol conditioning. For example, in as‐cast films prepared from carbon disulfide, the oxygen permeability at 35 °C is 330 × 10?10 cm3 (STP) cm/(cm2 s cmHg) for the toluene‐soluble polymer and 73 × 10?10 cm3 (STP) cm/(cm2 s cmHg) for the toluene‐insoluble polymer. After these films are conditioned in methanol, the oxygen permeability increases to 5200 × 10?10 cm3 (STP) cm/(cm2 s cmHg) for the toluene‐soluble polymer and 6200 × 10?10 cm3 (STP) cm/(cm2 s cmHg) for the toluene‐insoluble polymer. The rankings of the fractional free volume and nonequilibrium excess free volume in the various PTMGP films are consistent with the measured gas permeability and n‐butane solubility values. Methanol conditioning increases gas permeability and n‐butane solubility of as‐cast PTMGP films, regardless of the polymer fraction type and casting solvent used, and minimizes the permeability and solubility differences between the various films (i.e., the permeability and solubility values of all conditioned PTMGP films are similar). © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 2228–2236, 2002 相似文献
88.
We use inelastic neutron scattering to probe magnetic excitations of an optimally electron-doped superconductor Nd1.85Ce0.15CuO4-delta above and below its superconducting transition temperature Tc=25 K. In addition to gradually opening a spin pseudogap at the antiferromagnetic ordering wave vector Q=(1/2,1/2,0), the effect of superconductivity is to form a resonance centered also at Q=(1/2,1/2,0) but at energies above the spin pseudogap. The intensity of the resonance develops like a superconducting order parameter, similar to those for hole-doped superconductors and electron-doped Pr0.88LaCe0.12CuO4. The resonance is therefore a general phenomenon of cuprate superconductors, and must be fundamental to the mechanism of high-Tc superconductivity. 相似文献
89.
Nicholas P. Calta Dr. Jino Im Alexandra P. Rodriguez Dr. Lei Fang Dr. Daniel E. Bugaris Dr. Thomas C. Chasapis Prof. Arthur J. Freeman Prof. Mercouri G. Kanatzidis 《Angewandte Chemie (International ed. in English)》2015,54(32):9186-9191
EuIr4In2Ge4 is a new intermetallic semiconductor that adopts a non‐centrosymmetric structure in the tetragonal ${I\bar 42m}$ space group with unit cell parameters a=6.9016(5) Å and c=8.7153(9) Å. The compound features an indirect optical band gap Eg=0.26(2) eV, and electronic‐structure calculations show that the energy gap originates primarily from hybridization of the Ir 5d orbitals, with small contributions from the Ge 4p and In 5p orbitals. The strong spin–orbit coupling arising from the Ir atoms, and the lack of inversion symmetry leads to significant spin splitting, which is described by the Dresselhaus term, at both the conduction‐ and valence‐band edges. The magnetic Eu2+ ions present in the structure, which do not play a role in gap formation, order antiferromagnetically at 2.5 K. 相似文献
90.
Nano titanium dioxide (nTiO2), generally considered to be toxicologically inert, is manufactured in large quantities and extensively applied in consumer products. The small size and large surface area endow them with an active group or intrinsic toxicity. Advances in instrumentation are making Raman spectroscopy the tool of choice for an increasing number of (bio) chemical applications. One of the great advantages of this technique is its ability to provide information on the concentration, structure and interaction of biochemical molecules in their microenvironments within intact cells and tissues, non-destructively. Zebrafish (Danio rerio), one of the most important vertebrate model organisms used in developmental biology, are increasingly used in biomedical research, particularly as a model of human disease. In the present work, an attempt is made to study the effect of titanium dioxide, both nano and bulk, on the microenvironment of the liver tissues of Zebrafish using FT-Raman spectroscopy. The results of the present study suggest that TiO2 exposure demonstrate a marked influence on the microenvironments of the liver tissues of Zebrafish. A shift to a higher wavenumber and an increase in the intensity of the band at ∼1087 cm−1 in the TiO2 exposed tissues suggest that some of the conformational changes resulting from the alkali recovery process takes place due to TiO2 exposure. The decreased intensity ratio (I3220/I3400) observed in the titanium-exposed tissues suggests a decreased water domain size, which could be interpreted in terms of weaker hydrogen-bonded molecular species of water in the TiO2 exposed tissues. The observed shift of COO− bands to higher frequencies shows the disruption of salt bridges as a result of a change in the oppositely charged partners and due to the enhanced random coil conformation. The variation in the intensity ratio of the tyrosyl doublet (I858/I825) indicates variation in the hydrogen bonding of the phenolic hydroxyl group due to TiO2 exposure. The results further suggest that the microenvironments are greatly altered due to titanium nano exposure when compared to titanium bulk. In conclusion, the results indicate that FT-Raman spectroscopy might be a useful tool for rapid assessment of nano particle biological interactions. 相似文献