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41.
Gold nanoparticles (AuNPs) have been synthesized by greener method using chloroauric acid as precursor and extract of Acorus calamus rhizome as reducing agent. Formation of AuNP was confirmed by the presence of Surface Plasmon Resonance (SPR) peak in UV–Visible spectral analysis. XRD and FT-IR spectral analyses were performed for characterization. SEM images show spherical morphology and HR-TEM images reveal nanosize of AuNPs. The AuNPs were then coated on cotton fabric by pad-dry-cure method and characterized by SEM with EDAX technique. The results reveal the deposition of AuNPs on the surface of cotton fabric. Uncoated cotton, neat extract coated cotton and extract containing AuNPs coated cotton fabrics were then tested for antibacterial activity against Gram positive (Staphylococcus aureus) and Gram negative (Escherichia coli) bacterial strains by AATCC 100 test method. It showed that the extract containing AuNPs coated cotton fabric had higher antibacterial activity than other test samples against E. coli. UV-DRS analysis performed on extract containing AuNPs coated cotton fabric showed improved UV-blocking property than uncoated cotton fabric and neat extract coated cotton fabric. 相似文献
42.
A. Bansil R. Prasad S. Bessendorf L. Schwartz W.J. Venema R. Feenstra F. Blom R. Griessen 《Solid State Communications》1979,32(11):1115-1118
Calculations based on a muffin tin model for the electronic structure of the random interstitial alloy PdHx are presented together with the first high resolution de Haas-van Alphen data for this system in the α-phase. In the dilute limit good agreement is obtained for the concentration dependence of the areas of several extremal orbits. The behavior of the PdHx Fermi surface is unique in that the Γ-centered electron orbits are found to grow at approximately the rate predicted by the rigid band model while the X-centered hole pockets shrink at only half the rigid band rate. 相似文献
43.
RM. Sekkappan 《Annals of the Institute of Statistical Mathematics》1982,34(1):605-609
Summary Smith (1976,J. R. Statist. Soc., A,139, 183–204) has argued that survey statisticians should attempt to model finite population structures in the same way that
statisticians in other disciplines have to provide models of finite or infinite populations. Following this argument, we suggest
in this paper that an obvious model for a stratified population when auxiliary information regarding variate values is available,
is the one way analysis of covariance model with unequal variances and we consider the problem of estimating the finite population
mean. Finally a possible extension of this result is discussed. 相似文献
44.
S.J. Feenstra J. van Klinken J.P. Pijn R. Janssens C. Michel J. Steyaert J. Vervier K. Cornelis M. Huyse G. Lhersonneau 《Physics letters. [Part B]》1979,80(3):183-186
The multipolarity of continuum transitions deexciting high-spin states has been deduced from measured conversion coefficients. The investigated 146Nd(20Ne, 4n or 5n) 162,161Yb reactions were selected by gating on discrete lines. The average multipolarity gradually changes from E2 at 0.5 MeV to E1 above 1.5 MeV. 相似文献
45.
S.J.H.?Petra K.A.H.?van Leeuwen L.?Feenstra W.?Hogervorst W.?VassenEmail author 《Applied physics. B, Lasers and optics》2004,79(3):279-283
With a two-dimensional (2D) optical mask at =1083 nm, nanoscale patterns are created for the first time in an atom lithography process using metastable helium atoms. The internal energy of the atoms is used to locally damage a hydrophobic resist layer, which is removed in a wet etching process. Experiments have been performed with several polarizations for the optical mask, resulting in different intensity patterns, and corresponding nanoscale structures. The results for a linear polarized light field show an array of holes with a diameter of 260 nm, in agreement with a computed pattern. With a circularly polarized light field a line pattern is observed with a spacing of /20.5=766 nm. Simulations taking into account many possible experimental imperfections can not explain this pattern. PACS 32.80.Lg; 39.25.+k; 81.16.Nd 相似文献
46.
K. Anton Feenstra Berk Hess Herman J. C. Berendsen 《Journal of computational chemistry》1999,20(8):786-798
A systematic analysis is performed on the effectiveness of removing degrees of freedom from hydrogen atoms and/or increasing hydrogen masses to increase the efficiency of molecular dynamics simulations of hydrogen-rich systems such as proteins in water. In proteins, high-frequency bond-angle vibrations involving hydrogen atoms limit the time step to 3 fs, which is already a factor of 1.5 beyond the commonly used time step of 2 fs. Removing these degrees of freedom from the system by constructing hydrogen atoms as dummy atoms, allows the time step to be increased to 7 fs, a factor of 3.5 compared with 2 fs. Additionally, a gain in simulation stability can be achieved by increasing the masses of hydrogen atoms with remaining degrees of freedom from 1 to 4 u. Increasing hydrogen mass without removing the high-frequency degrees of freedom allows the time step to be increased only to 4 fs, a factor of two, compared with 2 fs. The net gain in efficiency of sampling configurational space may be up to 15% lower than expected from the increase in time step due to the increase in viscosity and decrease in diffusion constant. In principle, introducing dummy atoms and increasing hydrogen mass do not influence thermodynamical properties of the system and dynamical properties are shown to be influenced only to a moderate degree. Comparing the maximum time step attainable with these methods (7 fs) to the time step of 2 fs that is routinely used in simulation, and taking into account the increase in viscosity and decrease in diffusion constant, we can say that a net gain in simulation efficiency of a factor of 3 to 3.5 can be achieved. ©1999 John Wiley & Sons, Inc. J Comput Chem 20: 786–798, 1999 相似文献
47.
RM. Murugappan M. Karthikeyan A. Aravinth MR. Alamelu 《Applied biochemistry and biotechnology》2012,168(8):2170-2183
In the present study, siderophore produced by the marine yeast Aureobasidium pullulans was characterized as hydroxamate by chemical and bioassays. The hydroxamate assignment was supported by the appearance of peaks at 1,647.21?C1,625.99?cm?1 and at 1,435.04?cm?1 in the infrared spectrum. The purified siderophore exhibited specific growth-promoting activity under iron-limited conditions for siderophore auxotrophic probiotic bacteria. Cross-utilization of siderophore indicates a symbiotic relationship between the yeast A. pullulans and the selected probiotic bacterial strains. Statistical optimization of medium components for improved siderophore production in A. pullulans was depicted by response surface methodology. The shift in UV?CVis spectroscopy indicates the photoreactive property and subsequent oxidative cleavage of purified siderophore on exposure to sunlight. 相似文献
48.
K. S. Pramod V. Vijayasundaram N. Krishnakumar PL. RM. Palaniappan 《Journal of Thermal Analysis and Calorimetry》2012,108(1):133-139
This article presents the changes in the thermal properties of the control and titanium dioxide (TiO2), both nano and bulk exposed Zebrafish bones by using thermo analytical techniques. The result shows that the mass loss due
to the thermal decomposition occurs in three distinct steps due to loss of water, organic and inorganic materials. The titanium
dioxide exposed bones present a different thermal behaviour compared to the control bones. The residue masses are found to
be increased due to titanium dioxide exposure. In particular, nano titanium dioxide exposure increases the residue mass level
significantly (three fold) when compared to titanium dioxide bulk exposure. These thermal characteristics can be used as a
qualitative method to check the metal oxide intoxication in biological samples. 相似文献
49.
A. V. Pronin B. P. Gorshunov A. A. Volkov H. S. Somal D. van der Marel B. J. Feenstra Y. Jaccard J. -P. Locquet 《JETP Letters》1998,68(5):432-436
Direct measurements of the complex conductivity spectra of thin-film La2−2x
SrxCuO4 are made at frequencies of 5–40 cm−1. Narrow, intense Drude-type excitation is observed in the superconducting phase.
Pis’ma Zh. éksp. Teor. Fiz. 68, No. 5, 406–409 (10 September 1998) 相似文献
50.
Rubens R Santos Jr Alexandrina Sartori Deison S Lima Patrícia RM Souza Arlete AM Coelho-Castelo Vania LD Bonato Célio L Silva 《Journal of immune based therapies and vaccines》2009,7(1):4-12