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371.
Neutron Activation Analysis (NAA) is a sensitive multi-element nuclear analytical technique that has been routinely applied by research reactor (RR) facilities to environmental, nutritional, health related, geological and geochemical studies. As RR facilities face calls to increase their research output and impact, with existing or reducing budgets, automation of NAA offers a possible solution. However, automation has many challenges, not the least of which is a lack of system architecture standards to establish acceptable mechanisms for the various hardware/software and software/software interactions among data acquisition systems, specialised hardware such as sample changers, sample loaders, and data processing modules. This lack of standardization often results in automation hardware and software being incompatible with existing system components, in a facility looking to automate its NAA operations. This limits the availability of automation to a few RR facilities with adequate budgets or in-house engineering resources. What is needed is a modern open system architecture for NAA, that provides the required set of functionalities. This paper describes such an “architectural framework” (OpenNAA), and portions of a reference implementation. As an example of the benefits, calculations indicate that applying this architecture to the compilation and QA steps associated with the analysis of 35 elements in 140 samples, with 14 SRM’s, can reduce the time required by over 80 %. The adoption of open standards in the nuclear industry has been very successful over the years in promoting interchangeability and maximising the lifetime and output of nuclear measurement systems. OpenNAA will provide similar benefits within the NAA application space, safeguarding user investments in their current system, while providing a solid path for development into the future. 相似文献
372.
Phase transfer catalysis has been employed for many nucleo-philic substitution reactions.1 Generally these reactions have employed quaternary ammonium salts as catalysts. Among the displacement reactions reported is the formation of thiocyanates.2 Tertiary amines have also been used as catalysts for phase transfer generation of carbenes.3 Recently we reported the preparation of alkyl cyanides to be catalyzed by amines under phase transfer conditions.4 相似文献
373.
Morrison DJ O'Hara JP King RF Preston T 《Rapid communications in mass spectrometry : RCM》2011,25(17):2484-2488
The utilisation of carbohydrate sources under exercise conditions is of considerable importance in performance sports. Incorporation of optimal profiles of macronutrients can improve endurance performance in athletes. However, gaining an understanding of the metabolic partitioning under sustained exercise can be problematical and isotope labelling approaches can help quantify substrate utilisation. The utilisation of oral galactose was investigated using 13C‐galactose and measurement of plasma galactose and glucose enrichment by liquid chromatography/isotope ratio mass spectrometry (LC/IRMS). As little as 100 μL plasma could readily be analysed with only minimal sample processing. Fucose was used as a chemical and isotopic internal standard for the quantitation of plasma galactose and glucose concentrations, and isotopic enrichment. The close elution of galactose and glucose required a correction routine to be implemented to allow the measurement, and correction, of plasma glucose δ13C, even in the presence of very highly enriched galactose. A Bland‐Altman plot of glucose concentration measured by LC/IRMS against glucose measured by an enzymatic method showed good agreement between the methods. Data from seven trained cyclists, undergoing galactose supplementation before exercise, demonstrate that galactose is converted into glucose and is available for subsequent energy metabolism. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
374.
Laser drilling of high aspect ratio holes in copper with femtosecond,picosecond and nanosecond pulses 总被引:1,自引:0,他引:1
A. Weck T.H.R. Crawford D.S. Wilkinson H.K. Haugen J.S. Preston 《Applied Physics A: Materials Science & Processing》2008,90(3):537-543
Deep laser holes were drilled in copper sheets using various pulse lengths and environments. By recording the intensity on
a photodiode placed under the sample while drilling the holes, we obtained the number of pulses to drill through the sheet
as a function of pulse length and energy. The entrance diameter of the holes was successfully predicted using a Gaussian approximation
and a material removal fluence threshold of 0.39 J/cm2 for a pulse length of 150 fs. From cross sections of the holes, the morphology of the inside walls was observed and shows
an increase in the amount of molten material with pulse length. A transition pulse length is defined as the point at which
the laser affected material goes from being mainly vaporized to mainly melted. This transition occurs near ∼10 ps, which corresponds
approximately to the electron–phonon relaxation time for copper.
PACS 62.20.Mk; 62.25.+g; 79.20.Ds 相似文献
375.
Belonoshko AB Burakovsky L Chen SP Johansson B Mikhaylushkin AS Preston DL Simak SI Swift DC 《Physical review letters》2008,100(13):135701
The Gibbs free energies of bcc and fcc Mo are calculated from first principles in the quasiharmonic approximation in the pressure range from 350 to 850 GPa at room temperatures up to 7500 K. It is found that Mo, stable in the bcc phase at low temperatures, has lower free energy in the fcc structure than in the bcc phase at elevated temperatures. Our density-functional-theory-based molecular dynamics simulations demonstrate that fcc melts at higher than bcc temperatures above 1.5 Mbar. Our calculated melting temperatures and bcc-fcc boundary are consistent with the Mo Hugoniot sound speed measurements. We find that melting occurs at temperatures significantly above the bcc-fcc boundary. This suggests an explanation of the recent diamond anvil cell experiments, which find a phase boundary in the vicinity of our extrapolated bcc-fcc boundary. 相似文献
376.
Timothé R. L. Melin Preston Harell Betoul Ali Narasimhan Loganathan Angela K. Wilson 《Journal of computational chemistry》2023,44(4):570-580
The determination of gas phase thermochemical properties of per- and polyfluoroalkyl substances (PFAS) is central to understanding the long-range transport behavior of PFAS in the atmosphere. Prior gas-phase studies have reported the properties of perfluorinated sulfonic acid (PFOS) and perfluorinated octanoic acid (PFOA). Here, this study reports the gas phase enthalpies of formation of short- and long-chain PFAS and their precursor molecules determined using density functional theory (DFT) and ab initio approaches. Two density functionals, two ab initio methods and an empirical method were used to compute enthalpies of formation with the total atomization approach and an isogyric reaction. The performance of the computational methods employed in this work were validated against the experimental enthalpies of linear alkanoic acids and perfluoroalkanes. The gas-phase determinations will be useful for future studies of PFAS in the atmosphere, and the methodological choices will be helpful in the study of other PFAS. 相似文献