Interaction of the lithium derivatives of carboranes with lanthanides chlorides

Carboranyl derivatives of lanthanides have been prepared by interaction of the lithium derivatives of carboranes with the salts LnCl₃ · nTHF (Ln = La, Tm, Yb). The influence of the ratio of the reagents, the type of metal and the nature of solvents on these reactions has been studied.     

Chemical control of quartz suspensions aggregative stability

This article studies the influence of zeta potential on the fluidization of quartz suspensions and the possibility of its chemical control by changing the aggregative stability of the system using a reagent whose main component is the reaction product of amines and phosphoric esters. It is shown that aggregation of quartz, when treated by the specified chemical system, takes place due to an electrokinetic potential decrease resulting from reduction in the thickness of the diffuse portion of the electrical double layer around the quartz particles. It was found that chemical treatment of the quartz suspension contributes to a significant increase in fluidization onset velocity and fluid filtration coefficient. The article also proposed a correction to the Richardson–Zaki equation to take into account the aggregation of quartz particles. In order to explain the filtration properties of treated sand, a model was developed that takes into account the influence of aggregation on the porosity of the porous medium. The results presented here can be of use when developing oil fields composed of poorly consolidated sandstones.     

Interaction between explosive and analyte layers in explosive matrix-assisted plasma desorption mass spectrometry

An HMX/insulin two-layer system was chosen as a model for further investigation of the matrix properties of explosive materials for protein analytes in plasma desorption mass spectrometry. The dependencies of the molecular ion yield and average charge state as a function of the analyte thickness were studied. An increase in the charge state of multiply protonated molecular species was confirmed as the major matrix effect, with the average charge state z at the smallest thickness studied being higher than in matrix-assisted laser desorption/ionization and closer to the value obtained in electrospray ionization under standard acidic conditions. Observed charge state distributions are significantly narrower than the corresponding Poisson distributions, which suggests that the protonation of insulin is limited in plasma desorption by the number of basic sites in the molecule, similar to electrospray ionization. Both the curve displaying total molecular ion yield and the one showing the total charge (proton) yield as a function of the insulin thickness have maxima at a thickness different from an insulin monolayer. These observations diminish the significance of a matrix/analyte interface mechanism for the explosive matrix assistance. Instead, a mechanism related to the chemical energy release during conversion of the explosive after the ion impact is proposed. As additional mechanisms, enhanced protonation of the analyte through collisions with products of the explosive decay is considered, as well as electron scavenging by other products, which leads to a higher survival probability of positively charged protein molecular ions. Copyright 1999 John Wiley & Sons, Ltd.     

Wave scattering effects in elastic percolation models

The study of the propagation of waves in randomly diluted models is presented. Porosity (crack-like) models are simulated by constructing typical elastic percolation networks with random microscopic heterogeneities in order to resemble rock media. Central and bond-bending forces (Born Hamiltonian) models are considered. For each experimental case, the elastic energy of the system is relaxed in equilibrium and then the model is excited by a pulse source in order to produce wave propagation. First, a review is presented of the well established velocity-porosity relationship from rock physics, which shows a linear trend from small porosities up to the critical porosity (percolation threshold) where the rocks fall apart. From the wave propagation analysis a general trend is observed for the attenuation of waves, from the small to the large porosity models, suggesting multiple scattering effects similar to those reported from effective-medium approximations of wave scattering due to random heterogeneities. Finally, the results are compared with those obtained from laboratory experiments on dry rocks with different porosities and different applied stress regimes.     

Muon spin echo

A muon spin echo method is proposed for determining the contributions of the static and dynamic local fields in muon experiments. It is shown that if for each muon which has stopped in the sample a rf pulse of fixed duration is applied to the sample at a time τ after the muon entered the sample, then after a sufficient number of muon-positron decays have been accumulated a muon spin echo can appear at time 2τ. Pis’ma Zh. éksp. Teor. Fiz. 64, No. 7, 500–503 (10 October 1996)     

Application of wavelet transforms to the solution of boundary value problems for linear parabolic equations

A method based on wavelet transforms is proposed for finding weak solutions to initial-boundary value problems for linear parabolic equations with discontinuous coefficients and inexact data. In the framework of multiresolution analysis, the general scheme for finite-dimensional approximation in the regularization method is combined with the discrepancy principle. An error estimate is obtained for the stable approximate solution obtained by solving a set of linear algebraic equations for the wavelet coefficients of the desired solution.     

Experimental, Theoretical and Biological Activity Study on the Acyl-Substituted Benzo-18-crown-6, Dibenzo-18-crown-6 and Dibenzo-24-crown-8

Hexadecanoyl, dihexadecanoyl, dioctadecaneoyl, di-10-undecenoyl, and dicis-9-octadecenoyl derivatives of benzo[18]crown-6, dibenzo[18]crown-6 and dibenzo[24]-8 were synthesized by the condensation of carboxylic acids (palmitic, stearic, oleic and undecenoic acid) with benzo and dibenzo crown ethers in the presence of zinc chloride. The extraction equilibrium constants of such macrocyclic ethers with long side chains were estimated using chloroform/water and dichloromethane/water membranes transfer of Na-PAR (4-(2-pyridylazo)-resorcinol mono sodium monohydrate) with UV–Vis spectroscopy. It was found that they were in the range of 10.88–11.71 in dichloromethane and 8.04–11.77 in chloroform. These results actually show that the Na+ binding effect of macrocyclic ethers depends on the type and the length of side chains. The geometrical properties of the molecules were studied employing semi-empirical calculations by simulated annealing technique. The frontier molecular orbital energies and dipole moments were also examined. The biological activity results showed that the synthesized crown ethers have no activity against the studied microorganisms.