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41.
42.
Fernandez YD Gramatges AP Amendola V Foti F Mangano C Pallavicini P Patroni S 《Chemical communications (Cambridge, England)》2004,(14):1650-1651
A new approach based on self-assembly inside micelles has been individuated to prepare a system behaving as a water-operating selective fluorescent sensor for Cu2+ and Ni2+. 相似文献
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44.
Hoefman M Aphecetche L Bacelar JC Delagrange H Descouvemont P Diaz J d'Enterria D van Goethem M Holzmann R Huisman H Kalantar-Nayestanaki N Kugler A Lohner H Marques FM Martinez G Messchendorp JG Ostendorf RW Schadmand S Siemssen RH Simon RS Schutz Y Timmermans R Turrisi R Volkerts M Wagner V Weller H 《Physical review letters》2000,85(7):1404-1407
45.
Alejandro R. Diaz Noboru Klkuchl Panos Papalambros John E. Taylor 《基于设计的结构力学与机械力学》2013,41(2):215-230
ABSTRACT Finite element solutions of improved quality are obtained by optimizing the location of nodes of the finite element grid, while keeping the number of degrees of freedom fixed. The formulation of the grid optimization problem is based on the reduction of error associated with interpolation of the exact solution, using functions from the finite element space. Element sizes are selected as design variables: length in R1 and area in R2. Analytically derived optimality conditions are presented and an approximation to these conditions is introduced to obtain a set of operationally useful equations that can be used as guidelines for construction of improved grids. Example problems are given for illustration. 相似文献
46.
Natalia A. Nikonorova Nikolai N. Smirnov Ricardo Diaz‐Calleja Alexander V. Yakimansky 《Journal of Polymer Science.Polymer Physics》2008,46(14):1488-1496
Local forms of molecular mobility of comb‐like random copolymethacrylates, containing side‐chain nonlinear optical chromophores and amyl‐ or octafluoroamyl‐groups, are studied. In the glassy state, two relaxation processes are found, which are due to reorientation of terminal polar groups (γ2‐process) and rotation of chromophore groups about their long axes (β‐process). For octafluoroamyl‐containing copolymers, the γ2‐process is superposition of the two molecular motions due to reorientation of terminal chromophore groups and ? CF2H groups. The intensity and relaxation times in the range of the γ2‐process depend on the chemical structure and concentration of chromophores in a copolymer. For the β‐process, the molecular mobility weakly depends on the chromophore structure, being mainly determined by the relative lengths of the rigid chromophore and flexible side chains. On the global spectrum of depolarization current it was observed the γ1‐process due to reorientation of (CH2)n spacers between chromophore groups and copolymer backbone. © 2008 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 1488–1496, 2008 相似文献
47.
Véronique Cariou Stéphane Verdun Emmanuelle Diaz El Mostafa Qannari Evelyne Vigneau 《Advances in Data Analysis and Classification》2009,3(3):227-241
Within the scope of cluster analysis of variables, the selection of the appropriate number of clusters is of paramount interest. The strategy of determination of the appropriate number of clusters adopted herein is based on a hypothesis testing approach. It consists in testing whether the variation of a partition quality criterion between two consecutive partitions is far removed from the expected variation under the null-hypothesis stipulating a lack of structure. Three hypothesis testing strategies are detailed and compared in the scope of clustering of variables: Gap, Weighted Gap and a statistic associated with CLV methodology. Finally, an illustration is presented based on data from a preference study. 相似文献
48.
Melvina Leolukman Peerasak Paoprasert Ian Mandel Solimar J. Diaz David J. Mcgee Padma Gopalan 《Journal of polymer science. Part A, Polymer chemistry》2009,47(19):5017-5026
Linear‐dendritic block copolymer hosts were synthesized by end‐functionalizing poly(methylmethacrylate) with dendrons that acted as hydrogen‐bonding acceptors for nonlinear optical chromophores. Second harmonic generation experiments indicate that the d33 coefficients and maximum chromophore loading are increased in linear‐dendritic block copolymer hosts over comparable homopolymer hosts. Transmission electron microscopy shows 5–10 nm chromophore domains, confirming the effective spatial dispersion of the chromophores. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 5017–5026, 2009 相似文献
49.
Constantina Papatriantafyllopoulou Marta Estrader Constantinos G. Efthymiou Despina Dermitzaki Konstantinos Gkotsis Aris Terzis Carmen Diaz Spyros P. Perlepes 《Polyhedron》2009,28(9-10):1652-1655
Employing the mononuclear complex [Ni{(py)C(Me)NO}2{(py)C(Me)NOH}] (1) as ‘ligand’ [(py)C(Me)NOH = methyl 2-pyridyl ketone oxime], the use of the ‘metal complexes as ligands’ approach has led to the synthesis of the mixed NiII/LnIII complexes [NiTb{(py)C(Me)NO}2(NO3)3{(py)C(Me)NOH}] (2), [Ni2Ln2{(py)C(Me)NO}6(NO3)4] (Ln = Dy, 3; Ln = Tb, 4) and [Ni2Tb{(py)C(Me)NO}6](NO3) (5). The structures of 2, 3, and 5, and the magnetic properties of 2 and 5 are briefly discussed. 相似文献
50.
Here is reported a novel analytical approach for the extractive separation and determination of enantiomeric ratios of aristocularine in bovine serum albumin. The results demonstrate suitable analytical performances. The separation was performed by chiral high-performance liquid chromatography with a 5-µm column using a mobile phase of 1:1 n-hexane:ethanol at a flow rate of 0.7?mL?min?1 with ultraviolet–visible absorption, circular dichroism, and polarimetric detection. The enantiomers were eluted at 13.2 and 15.6?min for (+) and (?)-aristocularine, with a resolution of 1.58 and a separation factor of 1.27. The analytical parameters for the dispersive liquid–liquid microextraction were optimized; under these conditions, the extraction recoveries were from 88.6% to 93.9% for a two-step extraction. The precision, reported as the percent relative standard deviation, had values from 2.9% to 3.2% for 0.5?µg?mL?1 of analyte for five replicate measurements using ultraviolet–visible absorption and circular dichroism detection. The limits of detection were between 0.05 and 0.08?µg?mL?1 with enrichment ratios up to a value of 12. 相似文献