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941.
M. Froese C. Champagne J. R. Crespo López-Urrutia S. Epp G. Gwinner A. Lapierre J. Pfister G. Sikler J. Ullrich J. Dilling 《Hyperfine Interactions》2006,173(1-3):85-92
The precision of atomic mass measurements in a Penning trap is directly proportional to the charge state q of the ion and,
hence, can be increased by using highly charged ions (HCI). For this reason, charge breeding with an electron beam ion trap
(EBIT) is employed at TRIUMF’s Ion Trap for Atomic and Nuclear science (TITAN) on-line facility in Vancouver, Canada. By bombarding
the injected and trapped singly charged ions with an intense beam of electrons, the charge state of the ions is rapidly increased
inside the EBIT. To be compatible with the on-line requirements of short-lived isotopes, very high electron beam current densities
are needed. The TITAN EBIT includes a 6 Tesla superconducting magnet and is designed to have electron beam currents and energies
of up to 5 A and 60 keV, respectively. Once operational at full capacity, most species can be bred into a He-like configuration
within tens of ms. Subsequently, the HCI are extracted, pass a Wien filter to reduce isobaric contamination, are cooled, and
injected into a precision Penning trap for mass measurement. We will present the first results and current status of the TITAN
EBIT, which has recently been moved to TRIUMF after assembly and commissioning at the Max-Planck-Institute (MPI) for Nuclear
Physics in Heidelberg, Germany. 相似文献
942.
Three new magnetic oxides have been synthesised, viz., Li2Fe3VO8, YFe3TiO8 and CaFe3VO8. XRD studies show that the first compound has a cubic symmetry of spinel type while the latter two show orthorhombic symmetry. All the three compounds are magnetic at room temperature, however, the first compound shows a large magnetic moment as compared to the other two. Their Mössbauer spectra at room temperature show distinct hyperfine split spectral lines. The present preliminary investigation indicates that the long range order is ferrimagnetic in Li2Fe3VO8 and CaFe3VO8 while in YFe3TiO8 it is more likely to be canted antiferromagnetic. 相似文献
943.
C.X. Gao F.C. Yu S.Y. Jeong A.R. Choi P. Parchinskiy D.J. Kim H.J. Kim Y.E. Ihm C.G. Kim C.S. Kim 《Journal of magnetism and magnetic materials》2006
GaMnN and Be-codoped GaMnN were grown via molecular beam epitaxy using a single GaN precursor and their structural and magnetic properties were examined. X-ray diffraction and superconducting quantum interference device (SQUID) measurements revealed that the grown layers are homogeneous without precipitates. The saturation magnetization of GaMnN has increased from ∼4 to ∼16 emu/cm3 via codoping of Be. The d–d exchange interaction between Mn atoms was discussed for the ferromagnetism of GaMnN. 相似文献
944.
R. Pinna F.J.M. Rutten E.F. Smith M.R. Willis M.R.S. McCoustra 《Applied Surface Science》2006,252(19):6672-6675
Time-of-flight secondary ion mass spectrometry (ToF-SIMS) and polarisation-modulation reflection-absorption infrared spectroscopy (PM-RAIRS) have been used to monitor the surface synthesis of self-assembled aromatic π-conjugated molecular wires on gold substrates as a step towards a novel structure for organic electroluminescent devices (OLEDs). The wires have been synthesised using a series of Schiff's base coupling reactions in solution on a self-assembled monolayer of an aromatic thiolate anchor. ToF-SIMS and PM-RAIRS measurements have demonstrated that: (i) the anchor molecules self-assemble at the gold surface, (ii) the anchor molecules selectively react through imino coupling reactions with additional wire units with high efficiency and (iii) the wire-like structure is predominantly orientated normal to the surface. 相似文献
945.
When some parameters cannot be easily measured experimentally, mathematical models can often be used to deconvolute or interpret data collected on complex systems, such as those characteristic of many environmental problems. These models can help quantify the contributions of various physical or chemical phenomena that contribute to the overall behavior, thereby enabling the scientist to control and manipulate these phenomena, and thus to optimize the performance of the material or device. In the first case study presented here, a model is used to test the hypothesis that oxygen interactions with hydrogen on the catalyst particles of solid oxide fuel cell anodes can sometimes occur a finite distance away from the triple phase boundary (TPB), so that such reactions are not restricted to the TPB as normally assumed. The model may help explain a discrepancy between the observed structure of SOFCs and their performance. The second case study develops a simple physical model that allows engineers to design and control the sizes and shapes of mesopores in silica thin films. Such pore design can be useful for enhancing the selectivity and reactivity of environmental sensors and catalysts. This paper demonstrates the mutually beneficial interactions between experiment and modeling in the solution of a wide range of problems. 相似文献
946.
R. Guerrero F.G. Aliev R. Villar J. Hauch M. Fraune G. Güntherodt K. Rott H. Brückl G. Reiss 《Journal of magnetism and magnetic materials》2006
We report on tunnelling magnetoresistance (TMR), current–voltage (IV) characteristics and low-frequency noise in epitaxially grown Fe(1 1 0)/MgO(1 1 1)/Fe(1 1 0) magnetic tunnel junctions (MTJs) with dimensions from 2×2 to 20×20 μm2. The evaluated MgO energy barrier (0.50±0.08 eV), the barrier width (13.1±0.5 Å) as well as the resistance times area product (7±1 MΩ μm2) show relatively small variation, confirming a high quality epitaxy and uniformity of all MTJs studied. At low temperatures (T<10 K) inelastic electron tunneling spectroscopy (IETS) shows anomalies related to phonons (symmetric structures below 100 meV) and asymmetric features above 200 meV. We explain the asymmetric features in IETS as due to generation of electron standing waves in one of the Fe electrodes. The noise power, though exhibiting a large variation, was observed to be roughly anti-correlated with the TMR. Surprisingly, for the largest junctions we observed a strong enhancement of the normalized low-frequency noise in the antiparallel magnetic configuration. This behavior could be related to the influence of magnetostriction on the characteristics of the insulating barrier through changes in local barrier defects structure. 相似文献
947.
Let X be a Tychonoff space, C(X) be the space of all continuous real-valued functions defined on X and CL(X×R) be the hyperspace of all nonempty closed subsets of X×R. We prove the following result. Let X be a countably paracompact normal space. The following are equivalent: (a) dimX=0; (b) the closure of C(X) in CL(X×R) with the Vietoris topology consists of all F∈CL(X×R) such that F(x)≠∅ for every x∈X and F maps isolated points into singletons; (c) each usco map which maps isolated points into singletons can be approximated by continuous functions in CL(X×R) with the locally finite topology. From the mentioned result we can also obtain the answer to Problem 5.5 in [L'. Holá, R.A. McCoy, Relations approximated by continuous functions, Proc. Amer. Math. Soc. 133 (2005) 2173-2182] and to Question 5.5 in [R.A. McCoy, Comparison of hyperspace and function space topologies, Quad. Mat. 3 (1998) 243-258] in the realm of normal, countably paracompact, strongly zero-dimensional spaces. Generalizations of some results from [L'. Holá, R.A. McCoy, Relations approximated by continuous functions, Proc. Amer. Math. Soc. 133 (2005) 2173-2182] are also given. 相似文献
948.
C. Uranga C. Connell G.M. Borstad L.R. Zink M. Jackson 《Applied physics. B, Lasers and optics》2007,88(4):503-505
A three-laser heterodyne system was used to measure the frequencies of twelve previously observed far-infrared laser emissions
from the partially deuterated methanol isotopologues 13CD3OH and CHD2OH. Two laser emissions, a 53.773 μm line from 13CD3OH and a 74.939 μm line from CHD2OH, have also been discovered and frequency measured. The CO2 pump laser offset frequency was measured with respect to its center frequency for twenty-four FIR laser emissions from CH3OH, 13CD3OH and CHD2OH.
PACS 07.57.Hm; 42.55.Lt; 42.62.Eh 相似文献
949.
Justina Grabowska Karuna Kar Nanda R.T. Rajendra Kumar J.P. Mosnier M.O. Henry Simon B. Newcomb Patrick McNally Lisa OReilly Xu Lu Enda McGlynn 《Superlattices and Microstructures》2007,42(1-6):327
Self-organized ZnAl2O4 nanostructures with the appearance (in SEM) of high aspect ratio horizontal nanowires are grown on uncatalysed c-sapphire by vapour phase transport. The nanostructures grow as three equivalent crystallographic variants on c-sapphire. Raman and cathodoluminescence spectroscopy confirm that the nanostructures are not ZnO and TEM shows that they are the cubic spinel, zinc aluminate, ZnAl2O4, formed by the reaction of Zn and O with the sapphire substrate. 相似文献
950.
Dielectric relaxation study of the binary mixtures of poly(vinyl pyrrolidone) (PVP) (Mw=24000, 40000 and 360000 g mol−1) with ethyl alcohol (EA) and poly(ethylene glycol)s (PEGs) (Mw=200 and 400 g mol−1) in dilute solutions of dioxane were carried out at 10.1 GHz and 35°C. The relaxation time of PVP-EA mixtures was interpreted
by the consideration of a wait-and-switch model in the local structure of self-associated ethyl alcohol molecules and also
the PVP chain length as a geometric constraint for the reorientational motion of ethyl alcohol molecules. The formation of
complexes and effect of PVP chain length on the molecular dynamics, chain flexibility and stretching of PEG molecules in PVP-PEG
mixtures were explored from the comparative values of dielectric relaxation time. Further, relaxation time values in dioxane
and benzene solvent confirm the viscosity independent molecular dynamics in PVP-EA mixtures but the values vary significantly
with the non-polar solvent environment. 相似文献