Alkaloids ofPetilium raddeana II. Structures of petisine and petisinine

The alkaloids imperialine, imperialone, peumisine, petiline, petilidine, and the new bases petisine (I) and petisinine (III) have been isolated from bulbs ofPetilium raddeana (Regl.) Vved. On the basis of spectral characteristics and passages to a known compound, the structure of 3β-hydroxy-Δ²²(N)-22,26-iminocholestane-6,23-dione has been established for (I) and petisine 3β-glucopyranoside for (III).     

The dipole moment of HNO in its ÃA″ excited state determined using optical—optical double resonance stark spectroscopy

The Stark splittings and rotational asymmetry splittings of a number of levels of the ùA″ excited state of HNO have been measured using the sub-Doppler technique of optical—optical double resonance, μ_a is found to be 1.08 ± 0.01 D for the 100 vibronic state, and 1.05 ± 0.01 D for the 020 vibronic state. These values are to be compared with a recently determined ground state value of μ_a = 0.996 D. The asymmetry splittings of some of the levels studied are considerably larger than predicted from the known rotational constants, indicating minor rotational perturbations.     

Transient analysis of a vibrating reed: Error analysis

The error analysis for the transient vibrating reed test is developed based on a linearized approximation. Tables are given for the efficient utilization of the equations in evaluating the accuracy range of test data.     

An automatic absorptiometric method for the determination of nitrate

A method has been developed for the determination of nitrate with the Technicon Autoanalyser in the range 2–10 p.p.m. The method depends on the reduction of nitrate to nitrite by hydrazine in alkaline solution, with copper as a catalyst. The nitrite produced diazotises sulphanilamide and the product is coupled with N-(1-naphthyl) ethylenediamine, to give a red dye, the absorbance of which is measured at 550 mμ. A relative standard deviation of 3–4% is obtained.     

The extraction of elements with cyclic solvents and its application to geochemical analysis

The extraction of the elements Zn, Cd, Hg, Ga, In, Tl, Sn, Pb, As, Sb and Bi into the solvents cyclohexanone, cyclohexanol, and cyclohexane from hydrochloric acid solutions, has been studied. Cyclohexanone is a more efficient but less selective extracting agent than cyclohexanol while cyclohexane has little extracting power. Solvent extraction of hydrochloric acid solutions of materials of geochemical interest into cyclohexanone has been used to enrich trace elements prior to spectrochemical analysis.     

Metallfällungen mit Nitropnenylarsinsäuren

Zusammenfassung Die qualitative Fällung von Metallionen mit den drei isomeren o-, m- und p-Nitrophenylarsinsäuren wird beschrieben und auf Unterschiede der p_h-Werte des Fällungsbeginnes hingewiesen. Die Beeinflussung des Fällungsbeginnes durch die Stellung der Nitrogruppe wird hervorgehoben.

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Summary The precipitation of metal ions by means ofo-, m-, andp-nitrophenyl arsonic acids is described. The differences of the p_H values of the start of the precipitation are pointed out. The effect of the position of the nitro group on the beginning of the precipitation is stressed.

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Résumé On décrit la précipitation qualitative d'ions métalliques par les trois isomèreso., m. etp. de l'acide nitrophénylarsonique et l'on donne des indications concernant les différences de valeur du p_h lors du commencement de précipitation. On met en évidence l'influence de la position du groupe nitro sur le commencement de précipitation.

     

Application of multiparameter equations to calculation of the mutual solubility in water-organic solvent binary systems

The solubility of organic liquids in water and of water in organic liquids is primarily determined by the capability of organic liquids for hydrogen bonding. Adequate generalization of the solubility data is possible only with multiparameter equations taking also into account other properties of organic components, including the cohesion and molar volume.     

Total synthesis of the marine alkaloid halitulin

The structure of the strongly cytotoxic marine alkaloid halitulin (1) has been confirmed by total synthesis and its absolute configuration determined as (15S). The synthesis follows a strategy previously reported by one of us and uses an efficient preparation of the quinoline-7,8-diol unit by modified Baeyer-Villiger and Skraup reactions. The O-benzyl protecting groups were removed in the last step of the synthesis by transfer hydrogenolysis without concomitant reduction of the quinoline ring. The method can be applied for the synthesis of halitulin analogues.     

Spreading of liquid drops over saturated porous layers

Spreading of small liquid drops over thin porous layers saturated with the same liquid is investigated from both theoretical and experimental points of view. A theory is presented that shows that spreading is governed by the same power law as in the case of spreading over a dry solid substrate. The Brinkman's equations are used to model the liquid flow inside the porous substrate. An equation of the drop spreading is deduced, which shows that both an effective lubrication and the liquid exchange between the drop and the porous substrates are equally important. The presence of these two phenomena removes the well-known singularity at the moving three-phase contact line. Matching of the drop profile in the vicinity of the three-phase contact line with the main spherical part of the drop gives the possibility to calculate the pre-exponential factor in the spreading law via permeability and effective viscosity of the liquid in the porous layer. Unfortunately, the latter dependency turns out to be very weak. Spreading of silicone oils over different microfiltration membranes is carried out. Radii of spreading on time experimental dependencies confirm the theory predictions. Experimentally found coefficients agree with theoretical estimations.     

Reaction of 2,3,3-trimethyl-3H-indole hydrochloride with methacrylic and crotonic amides

Reaction of 2,3,3-trimethyl-and 2,3,3,5-tetramethyl-3H-indole hydrochlorides with methacrylic and crotonic amides gives 3- and 4-methyl-1,2,3,4,10,10a-hexahydropyrimido[1,2-a]indol-2-ones. With perchloric acid these are converted to 1-carbamoylpropyl-3H-indolium perchlorates. The syntheses of 10a-(4-dimethylaminostyryl)- and 10a-[(4-dimethylaminophenyl)butadienyl]-3,10,10-trimethylpyrimido[1,2-a]indol-2-ones have been studied.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 625–627, May, 1990.