全文获取类型
收费全文 | 409082篇 |
免费 | 4083篇 |
国内免费 | 1303篇 |
专业分类
化学 | 223051篇 |
晶体学 | 6567篇 |
力学 | 16665篇 |
综合类 | 13篇 |
数学 | 44121篇 |
物理学 | 124051篇 |
出版年
2020年 | 3213篇 |
2019年 | 3638篇 |
2018年 | 4362篇 |
2017年 | 4339篇 |
2016年 | 6731篇 |
2015年 | 4449篇 |
2014年 | 6790篇 |
2013年 | 18667篇 |
2012年 | 13373篇 |
2011年 | 16536篇 |
2010年 | 11231篇 |
2009年 | 11157篇 |
2008年 | 14799篇 |
2007年 | 14823篇 |
2006年 | 13795篇 |
2005年 | 12699篇 |
2004年 | 11456篇 |
2003年 | 10414篇 |
2002年 | 10064篇 |
2001年 | 12012篇 |
2000年 | 9046篇 |
1999年 | 7085篇 |
1998年 | 5795篇 |
1997年 | 5757篇 |
1996年 | 5364篇 |
1995年 | 5126篇 |
1994年 | 4819篇 |
1993年 | 4757篇 |
1992年 | 5588篇 |
1991年 | 5540篇 |
1990年 | 5314篇 |
1989年 | 5287篇 |
1988年 | 5331篇 |
1987年 | 5321篇 |
1986年 | 5062篇 |
1985年 | 6711篇 |
1984年 | 6842篇 |
1983年 | 5499篇 |
1982年 | 5962篇 |
1981年 | 5881篇 |
1980年 | 5559篇 |
1979年 | 5915篇 |
1978年 | 6073篇 |
1977年 | 6120篇 |
1976年 | 6106篇 |
1975年 | 5475篇 |
1974年 | 5556篇 |
1973年 | 5829篇 |
1972年 | 3774篇 |
1968年 | 3080篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
151.
Using the DFT/B3LYP method with a 6-31G(d) basis set, the structure, normal vibration frequencies, and the absolute band intensities in the IR spectra of the chlorin molecule and its four symmetric isotopomers have been calculated. Scaling of the force field by the Pulay method in independent and natural coordinates has been carried out. A method for obtaining effective force fields without using experimental data on the fundamental vibration frequencies is proposed. By comparing the vibration modes and constructing special matrices, complete assignment of the fundamental frequencies of porphin and chlorin has been carried out. It has been shown that the majority of porphin macroring vibrations upon pyrrolenine ring hydrogenation are frequency-characteristic and only 12 vibrations change considerably. A frequency correlation with regard for the mode transition between chlorin and all its isotopomers under consideration has been established. Comparative analysis of the force fields of porphin and chlorin in dependent natural coordinates has revealed the unique nonlocal character of the change in force constants of the macroring upon hydrogenation of one pyrrolenine ring. Modeling of the IR spectra of chlorin and its isotopomers has been performed. Assignment and interpretation of the normal vibrations of the molecules under consideration have been carried out. 相似文献
152.
In different regimes of exposure of metals to pulsed laser radiation, we show the role played by the liquid-drop phase formed from the target material in a laser-induced erosion plume due to bulk vaporization, in the dynamics of this plume. For some metals, the ranges of power densities of the acting laser radiation, at which the condensed-phase particles influence the passage of laser radiation to the target surface, have been determined experimentally. The mechanism of realization of a low-threshold breakdown has been revealed. 相似文献
153.
R. K. Bairamov 《Russian Journal of Applied Chemistry》2003,76(10):1699-1701
Influence exerted by additives introduced into the working solution, by iron or copper formedin electric-spark dispersion of these metals and zinc, on the quality of the products obtained in electric erosionwas studied. 相似文献
154.
The fine-structure parameters of a series of configurations of the first ion of indium and the gyromagnetic ratios in intermediate coupling are calculated by a semiempirical method in the single-configuration approximation. 相似文献
155.
The synthesis and characterization of a new homologous series of compounds, the 2-cyano-1,3-phenylene bis[4-(4-n-alkoxyphenyliminomethyl)benzoates] derived from 2-cyanoresorcinol is reported. All the compounds are enantiotropic mesogens and exhibit the fascinating B7 mesophase. The characterization of the mesophase was performed using polarizing optical microscopy, differential scanning calorimetry, X-ray diffraction and electro-optical studies. 相似文献
156.
The first stage in a multi-attribute value analysis is the development of a hierarchical structure of the attributes of the problem. This paper reports the process of developing such a structure for the problem of choosing a suitable mode of transport for radioactive waste. The initial hierarchy of attributes went through several stages of development as new insights emerged about the nature of the problem. Some of the reasons behind this restructuring are discussed, and several important questions about the structuring process are formulated. 相似文献
157.
We develop a theory of the magnetic-zenith effect (MZE) observed upon the ionosphere modification by powerful radio waves.
The dependences of MZE on main parameters, such as the magnetic-field inclination angle, pump-wave frequency and power, and
angular width of HF beam are obtained. The optimal elevation angle of pump-wave beam is predicted.
__________
Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 48, No. 9, pp. 772–787, September 2005. 相似文献
158.
159.
Robert R. Gamache Jean-Michel Hartmann 《Journal of Quantitative Spectroscopy & Radiative Transfer》2004,83(2):119-147
A complex semiclassical model for the calculation of line widths and shifts of H2O broadened by N2, derived from the Robert and Bonamy approach, is tested by comparisons with measurements for selected transitions in various vibrational bands. The lines retained, which involve rotational states with Kc=J or J−1 have been chosen for two reasons. The first is that they show large variations of the widths with J and thus enable a severe test of the model. The second is that, as explained in this paper, they are well-suited for the study of the effects of vibration on the collisional parameters. The measured values have been extracted from an updated version of a database built years ago (JQSRT 52 (1994) 481) that contains all available measurements. Comparisons between experimental and calculated widths and shifts at room temperature illustrate the quality of the model and clearly demonstrate, for the first time, that there is a vibrational dependence of the broadening. Values of collisional parameters are first studied in fundamental bands. This shows that the theoretical approach accounts for most of the dependence of broadening and shifting on rotational quantum numbers: the variations of γ, which reach a factor of nearly 20 from low to high J values, are correctly accounted for by the model as are some specific features of the shifts δ. Analysis confirms that the bending and stretching vibrations have significantly different effects on δ, due to the vibrational dependence of the intermolecular potential. On the other hand, differences on the widths are rather small with slightly smaller broadening for lines of the bending band. Calculations show that there is a spectroscopic effect, due to the larger rotational constant A in the v2=1 state. Calculations made for overtone bands involving numerous quanta of the stretching vibration are then presented. They predict that a significant dependence of the width should be observed for high J lines due to the effect of vibration on the interaction potential. This is confirmed by comparisons with measurements for lines involving a change of three and four quanta of stretching vibration. 相似文献
160.
We examine several interesting relationships and expressions involving Fourier-Feynman transform, convolution product and
first variation for functionals in the Fresnel class F(B) of an abstract Wiener space B. We also prove a translation theorem and Parseval's identity for the analytic Feynman integral.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献