首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   366738篇
  免费   8332篇
  国内免费   4116篇
化学   182952篇
晶体学   5354篇
力学   18272篇
综合类   138篇
数学   53507篇
物理学   118963篇
  2021年   2729篇
  2020年   3128篇
  2019年   3360篇
  2018年   12066篇
  2017年   12743篇
  2016年   9304篇
  2015年   4851篇
  2014年   5861篇
  2013年   13540篇
  2012年   14987篇
  2011年   24896篇
  2010年   15333篇
  2009年   15226篇
  2008年   21200篇
  2007年   24493篇
  2006年   10129篇
  2005年   15857篇
  2004年   11348篇
  2003年   10266篇
  2002年   8236篇
  2001年   7906篇
  2000年   6109篇
  1999年   4825篇
  1998年   4097篇
  1997年   4078篇
  1996年   3940篇
  1995年   3650篇
  1994年   3367篇
  1993年   3342篇
  1992年   3629篇
  1991年   3620篇
  1990年   3407篇
  1989年   3317篇
  1988年   3335篇
  1987年   3186篇
  1986年   3100篇
  1985年   4135篇
  1984年   4277篇
  1983年   3519篇
  1982年   3855篇
  1981年   3742篇
  1980年   3601篇
  1979年   3645篇
  1978年   3882篇
  1977年   3627篇
  1976年   3865篇
  1975年   3436篇
  1974年   3555篇
  1973年   3898篇
  1972年   2363篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
11.
Low-flow chromatography has a rich history of innovation but has yet to reach widespread implementation in bioanalytical applications. Improvements in pump technology, microfluidic connections, and nano-electrospray sources for MS have laid the groundwork for broader application, and innovation in this space has accelerated in recent years. This article reviews the instrumentation used for nano-flow LC, the types of columns employed, and strategies for multidimensionality of separations, which are key to the future state of the technique to the high-throughput needs of modern bioanalysis. An update of the current applications where nano-LC is widely used, such as proteomics and metabolomics, is discussed. But the trend toward biopharmaceutical development of increasingly complex, targeted, and potent therapeutics for the safe treatment of disease drives the need for ultimate selectivity and sensitivity of our analytical platforms for targeted quantitation in a regulated space. The selectivity needs are best addressed by mass spectrometric detection, especially at high resolutions, and exquisite sensitivity is provided by nano-electrospray ionization as the technology continues to evolve into an accessible, robust, and easy-to-use platform.  相似文献   
12.
The recognition of boron compounds is well developed as boronic acids but untapped as organotrifluoroborate anions (R−BF3). We are exploring the development of these and other designer anions as anion-recognition motifs by considering them as substituted versions of the parent inorganic ion. To this end, we demonstrate strong and reliable binding of organic trifluoroborates, R−BF3, by cyanostar macrocycles that are size-complementary to the inorganic BF4 progenitors. We find that recognition is modulated by the substituent's sterics and that the affinities are retained using the common K+ salts of R−BF3 anions.  相似文献   
13.
Li  Zhixiang  Zhao  Zhen  Liu  Caishan  Wang  Qingyun 《应用数学和力学(英文版)》2021,42(11):1571-1580
Applied Mathematics and Mechanics - Spiral springs have a wide range of applications in various fields. As a result of the complexity of friction, few theoretical analyses of spring belts under...  相似文献   
14.
Acta Mathematica Hungarica - Minkowski’s classical existence theorem provides necessary and sufficient conditions for a Borel measure on the unit sphere of Euclidean space to be the surface...  相似文献   
15.
Cao  Shunjuan  Zhao  Entao 《Geometriae Dedicata》2021,213(1):315-323
Geometriae Dedicata - Inspired by a recent work of Grove and Petersen (Alexandrov spaces with maximal radius, 2018), where the authors studied positively curved Alexandrov spaces with largest...  相似文献   
16.
We prove a well-posedness result for two pseudo-parabolic problems, which can be seen as two models for the same electrical conduction phenomenon in heterogeneous media, neglecting the magnetic field. One of the problems is the concentration limit of the other one, when the thickness of the dielectric inclusions goes to zero. The concentrated problem involves a transmission condition through interfaces, which is mediated by a suitable Laplace-Beltrami type equation.  相似文献   
17.
Physics of Atomic Nuclei - The muon puzzle is an excess of muon bundles generated by primary cosmic rays (PCR) at energies above 10 $${}^{17}$$ eV compared to estimations that assume even a heavy...  相似文献   
18.
Kumar  Sanjay  Jiwari  Ram  Mittal  R. C.  Awrejcewicz  Jan 《Nonlinear dynamics》2021,104(1):661-682
Nonlinear Dynamics - In this article, the authors simulate and study dark and bright soliton solutions of 1D and 2D regularized long wave (RLW) models. The RLW model occurred in various fields such...  相似文献   
19.
Li  Y.  Shi  W. H.  Dong  L. M.  Xu  S. X.  Huang  H. J.  Yin  J. R. 《Journal of Applied Spectroscopy》2022,89(3):534-541
Journal of Applied Spectroscopy - Sr3B2O6:Dy3+, Eu3+ single-matrix white-light-emitting materials are prepared using the high-temperature solid-state method. The microstructure, emission spectrum,...  相似文献   
20.
Solar-driven interfacial vaporization by localizing solar-thermal energy conversion to the air−water interface has attracted tremendous attention. In the process of converting solar energy into heat energy, photothermal materials play an essential role. Herein, a flexible solar-thermal material di-cyan substituted 5,12-dibutylquinacridone (DCN−4CQA)@Paper was developed by coating photothermal quinacridone derivatives on the cellulose paper. The DCN−4CQA@Paper combines desired chemical and physical properties, broadband light-absorbing, and shape-conforming abilities that render efficient photothermic vaporization. Notably, synergetic coupling of solar-steam and solar-electricity technologies by integrating DCN−4CQA@Paper and the thermoelectric devices is realized without trade-offs, highlighting the practical consideration toward more impactful solar heat exploitation. Such solar distillation and low-grade heat-to-electricity generation functions can provide potential opportunities for fresh water and electricity supply in off-grid or remote areas.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号