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931.
A theory that predicts the effect of the counterion size on the swelling and collapse of a weakly charged polyelectrolyte gel was developed. In addition to excluded-volume interactions between monomer units of the gel, the theory involves the counterion-monomer unit and counterion-counterion interactions in terms of the virial approximation. The character of interactions between different units in the system varies from repulsion to attraction depending on the type of solvent, counterion, and dielectric permittivity of the solvent. For solvents with a low permittivity, the effect of condensation of counterions resulting in the formation of ion pairs is taken into account. 相似文献
932.
B. D. Kabulov K. A. Akhundzhanov F. U. Yunusov O. A. Shpigun S. S. Negmatov 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2007,81(3):354-356
The hydrolytic polycondensation of tetraethoxysilane in the presence of various polymers (polyacrylonitrile, polycaproamide, and chitosan) as templates was performed with the use of the sol-gel technology to obtain nanohybrid composite polymer-silica sorbents-nanofractals. 相似文献
933.
E. Baggio Saitovitch F. J. Litterst I. Souza Azevedo R. B. Scorzelli 《Hyperfine Interactions》1989,50(1-4):529-535
The Mössbauer spectra of YBa2(Cu1?x Fe x )3O7 at room temperature show several doublets attributed to Fe in Cu(1) sites with different oxygen configurations. Here we present a systematic study performed at 4.2 K forx=0.005, 0.01, 0.03, 0.05, 0.10, 0.15. To obtain information about the magnetic ordered state two samples, withx=0.005 andx=0.15, have been studied at 4.2 K underB ext=5 T. The Mössbauer spectra indicate that the iron moments are polarized forx=0.005, while in the ordered state (x=0.15) they have an antiferromagnetic or spin-glass-like arrangement with high anisotropy. 相似文献
934.
R. L. Moreira P. Saint-Grgoire M. Lopez M. Latour 《Journal of Polymer Science.Polymer Physics》1989,27(3):709-722
The thermal and dielectric behaviors of poly(vinylidene fluoride-trifluoroethylene) copolymers near the ferroelectric-to-paraelectric phase transition are investigated for samples with 20, 25, 30, and 40 mol% trifluoroethylene (TrFE). The data suggest that the transition becomes continuous for a particular composition near 50 mol% TrFE. Experimental data are sensitive to thermal history (kinetics of crystallization, and kinetics and cycling over the structural transition). It is found that several anomalies are present at the structural change, and in particular the 30 mol% TrFE sample shows the most marked anomalies. These phenomena can be attributed to defects, but another possibility would be the existence of an intemediate supplementary phase. Both hypotheses are discussed. 相似文献
935.
936.
4-Amino-3-arylisothiazole-5-carboxylate esters are converted to the corresponding desamino, chloro, bromo, and iodo esters by processes involving nonaqueous diazotization. These related procedures open up the possibility for the conversion of readily available heterocyclic ortho-amino esters and nitriles to related heterocyclic derivatives, which are not easily obtained by alternate routes. 相似文献
937.
938.
In the framework of three-dimensional stability equations, we study the local instability of a horizontal excavation with elliptic cross-section under the assumption that the rock mass behaves like an elastoviscoplastic media. An estimate of the influence of the rock mass parameters on the value of the critical pressure is given. 相似文献
939.
Consider the problem of three point vortices (also called Helmholtz’ vortices) on a plane, with arbitrarily given vorticities.
The interaction between vortices is proportional to 1/r, where r is the distance between two vortices. The problem has 2 equilateral and at most 3 collinear normalized relative equilibria.
This 3 is the optimal upper bound. Our main result is that the above standard statements remain unchanged if we consider an
interaction proportional to r
b, for any b < 0. For 0 < b < 1, the optimal upper bound becomes 5. For positive vorticities and any b < 1, there are exactly 3 collinear normalized relative equilibria. The case b = −2 of this last statement is the well-known theorem due to Euler: in the Newtonian 3-body problem, for any choice of the
3 masses, there are 3 Euler configurations (also known as the 3 Euler points). These small upper bounds strengthen the belief
of Kushnirenko and Khovanskii [18]: real varieties defined by simple systems should have a simple topology. We indicate some
hard conjectures about the configurations of relative equilibrium and suggest they could be attacked within the quasi-polynomial
framework. 相似文献
940.
High even order generalizations of the traditional upwind method are introduced to solve second order ODE-BVPs without recasting
the problem as a first order system. Both theoretical analysis and numerical comparison with central difference schemes of
the same order show that these new methods may avoid typical oscillations and achieve high accuracy. Singular perturbation
problems are taken into account to emphasize the main features of the proposed methods.
AMS subject classification (2000) 65L10, 65L12, 65L50 相似文献