η3-Allyl[1,2-bis(diphenylphosphino)ethan]tricarbonylvanadium(0)-komplexe

The preparation, properties and spectroscopic investigation (IR, ¹H NMR, ³¹P NMR, MS) of η³-allyl[1,2-bis(diphenylphosphino)ethan]tricarbonylvanadium(0) compounds are reported.     

Organoarsen-Verbindungen : XXIV. Zur synthese der perhydro-1,3-azarsenine

The reaction of NaAsHR with ClCH₂CH₂CH₂NH₂ yields the corresponding secondary 3-aminopropylarsines, RAs(H)CH₂CH₂CH₂NH₂, which with aldehydes and ketones form the perhydro-1,3-azarsenines. The properties and reactivity of these heterocyclic compounds are described.     

An axiomatic scheme more general than quantum theory

An axiomatic scheme generalizing the operational approach to quantum theory is described. Only quite general axioms ensuring the existence of well-behaved probabilities are postulated. The space-time location of macroscopic apparatus interacting with the object is explicitly taken into consideration. The states and observables are defined and their time development is considered. The classification of physical processes with respect to their reversibility or irreversibility in time is given. The conditions of Lorentz and translational invariance are formulated. Linear transformations corresponding to operations on the object are introduced. In the case of reversible processes these transformations form an algebra and linear representations of the Poincaré group arise naturally. These results are, in general, invalid for irreversible processes. The position of quantum theory in the scheme described is clarified.     

A Statistical Model for Describing Spectral Diffusion Effects in Electron Spin Echo (ESE) and Electron Nuclear Double Resonance (ENDOR) Experiments

A statistical model for an EPR line broadened by dipolar electron-nuclear interaction is proposed. This makes it possible for the effect of spectral diffusion on the width and intensity of ENDOR signals to be determined from electron spin echo experiments. In this paper, various ENDOR mechanisms are discussed in addition to a calculation of the variation in both Boltzmann factor and spin temperature due to the spectral diffusion effect.     

Observation of the decay τ → πv

The decay of the heavy lepton τ into πv has been established using the magnetic detector PLUTO. The branching ratio is determined to be BR(τ→πv)=(9.0 ± 2.9)% with an additional systematic uncertainty of 2.5%. This value is in good agreement with the theoretical prediction.     

Spurenanalyse von Cu in ZnS-Phosphoren mittels Neutronenaktivierung

The half life of the 206 kev state of Re¹⁸⁷ was determined with delayed coincidence technic to be:T _1/2=(5·70±0·05)·10^?7 s. The rotation of the spin of the 206 kev state in a magnetic field has been observed in a differential angular correlation measurement with the 480 kev?72 kevγ?γ cascade. From the observed Larmor frequency a magnetic moment ofμ=(5·02±0·06)μ _K for the 206 kev level has been derived. The 480 kev?72 kevγ?γ angular correlation was found to be undisturbed in an aqueous solution of ammoniumtungstate.     

Calculation of the mass spectrum of QED-2 in light-front coordinates

With the aim of a further investigation of the nonperturbative Hamiltonian approach in gauge field theories, the mass spectrum of QED-2 is calculated numerically by using the corrected Hamiltonian that was constructed previously for this theory on the light front. The calculations are performed for a wide range of the ratio of the fermion mass to the fermion charge at all values of the parameter \(\hat \theta \) related to the vacuum angle θ. The results obtained in this way are compared with the results of known numerical calculations on a lattice in Lorentz coordinates. A method is proposed for extrapolating the values obtained within the infrared-regularized theory to the limit where the regularization is removed. The resulting spectrum agrees well with the known results in the case of θ = 0; in the case of θ = π, there is agreement at small values of the fermionmass (below the phase-transition point).     

Gauge-Invariant Regularization of Quantum Field Theory on the Light Front

We briefly describe problems of the Hamiltonian approach for quantizing gauge fields on the light front for space–time bounded by the inequality |x ^–|L with periodic boundary conditions in the variable x ^– imposed on all fields (the DLCQ method). With these restrictions, we consider the gauge-invariant ultraviolet regularization by passing to a lattice in transverse coordinates. We remove the remaining ultraviolet divergences in the longitudinal momentum p _– by imposing a gauge-invariant finite-mode regularization. It turns out that the canonical formalism on the light front with such a regularization imposed does not contain the usual most complicated second-class constraints between zero and nonzero modes of fields. The described scheme can be used both to regularize the standard gauge theory and to provide a gauge-invariant formulation of effective low-energy models on the light front. Because the manifest Lorentz invariance is broken in our formalism, the vacuum state is poorly defined. We discuss this problem, in particular, in relation to the problem of passing to the continuous space limit.