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301.
DAndrea A. Tomassini N. Ferrari L. Righini M. Selci S. Bruni M. R. Simeoni G. 《Il Nuovo Cimento D》1995,17(11):1423-1427
Il Nuovo Cimento D - Normalized reflection spectra in GaInAs/GaAs quantum wells are shown for two sets of samples with different alloy concentration (x=9% and 18.5%) and well thickness ranging from... 相似文献
302.
In this paper we describe a method for separating a combination of a chaotic time series and a discrete-valued signal. The method uses a feedback technique stabilised using knowledge of the chaotic system and the discrete nature of the signal. It is not based on a linearization of the dynamics, and therefore, unlike previously proposed separation methods, does not require that the signal be small. Nor does it make any assumptions about the relative timescales of the signal and the chaotic time series. 相似文献
303.
Robert W. Baker Geoffrey R. Pocock Melvyn V. Sargent Edi Twiss 《Tetrahedron: Asymmetry》1993,4(12):2423-2426
Introduction of a 2-isopropoxycarbonyl or 2-NN-dimethylcarbamoyl group into homochiral 1-p-tolyl- or 1-t-butyl-sulfinylnaphthalenes, via directed metalation reaction, followed by ligand coupling reaction with 1-naphthylmagnesium bromide, furnished atropisomeric 1,1′-binaphthyls in 82–95% enantiomeric excess (e.e.). 相似文献
304.
305.
306.
Chemical kinetics of benzonitrile nitration with mixed acid is investigated in the temperature range 283–299 K. Pseudo-first-order rate constants are evaluated by means of rate experiments on homogeneous reacting mixtures having large stoichiometric excesses of nitric acid. The second-order kinetic constants for nitronium ion attack to the aromatic substrate are derived on the basis of the assessed nitration mechanism. An activation energy of 604 ± 37 kJ mol?1 is calculated for this reaction step. © 1993 John Wiley & Sons, Inc. 相似文献
307.
R Ehrhardt 《The Journal of the Operational Research Society》1997,48(10):1013-1021
We consider a firm that manages its internal manufacturing operations according to a just-in-time (JIT) system but maintains an inventory of finished goods as a buffer against random demands from external customers. We formulate a model in which finished goods are replenished by a small fixed quantity each time period. In the interest of schedule stability, the size of the replenishment quantity must remain fixed for a predetermined interval of time periods. We analyse the single-interval problem in depth, showing how to compute a cost-minimising value of the replenishment quantity for a given interval length, and characterising the optimal cost, inventory levels and service as functions of the interval length and initial inventory. The model displays significant cost and service penalties for schedule stability. A dynamic version of the problem is also formulated, and shown to be convex in nature with relatively easily computed optima. 相似文献
308.
309.
This research extends previous work with dynamic models to manage groundwater quality by using the consumptive nitrate use rate instead of the nitrate application rate. The analysis indicates that misspecification results in overestimation of economic benefits, and supra-optimum nitrogen fertilizer application rates and groundwater nitrate stocks at a steady state. 相似文献
310.
Fe(II)--Fe(III) hydroxy-chloride, -sulphate and -carbonate were prepared by oxidation of a ferrous hydroxide precipitate in anion-containing aqueous solutions. The compounds are characterized by monitoring the redox potential Eh and the pH of stochiometric suspension vs time with the appropriate concentration ratios. X-ray diffraction allows us to characterize the crystal structure by distinguishing “green rust one” (GR1) from “green rust two” (GR2). Since green rusts (GRs) are of a pyroaurite-sjögrenite-like structure, i.e., consisting of intercalated foreign anions and water molecules in the interlayers between the brucite-like layers of Fe(OH)2, their chemical formulae can be determined from the Mössbauer spectra. Three quadrupole doublets are observed: D1 and D2 correspond to a ferrous state with isomershift IS of about 1.27 mm s-1 and quadrupole splittings QS of about 2.85 and 2.60 mm s-1, respectively, whereas D3 corresponds to a ferric state with IS and QS of about 0.4 mm s-1. The hyperfine parameters of these doublets are similar from one green rust to another but their intensity ratios vary considerably. Finally, Eh and pH equilibrium diagrams of the Fe species in the presence of chloride, sulphate and carbonate anions contained within the water solution are drawn and the thermodynamic conditions of existence and degrees of oxidation of green rusts are discussed. 相似文献