The use of sulfide cluster-derived catalysts to understand the promotional effect in hydrotreatment catalysis

Sulfide cluster-derived ensembles are promising models of the active sites in commercial hydrotreatment catalysts. A series of sulfide clusters were adsorbed intact onto high-surface-area γ-alumina, magnesium oxide and activated carbon supports, then pretreated to produce highly dispersed catalytic ensembles with sizes similar to those of their precursor clusters. The activities of the bimetallic cluster-derived catalysts were significantly higher than those of the monometallic catalysts. We took this as evidence that direct interactions between molybdenum and the promoter element cause the promotional effect observed in commercial hydrotreatment catalysts. The hydrodesulfurization and hydrodenitrogenation activities correlated with the extent of molybdenum reduction. Our results suggested that the active sites in promoted hydrotreatment catalysts are centered on molecular-scale ensembles containing molybdenum, sulfur and the promoter element.     

NMR Study of the propagation center in the cationic polymerization of N-benzoyl-8-octanelactam. II. Investigation of the propagation center

The nature of the propagation center in the cationic polymerization of N-benzoyl-8-octanelactam initiated by octanoylium hexachlcroantimonate, SbCl₅, and Ph₃CAsF₆ in perdeuterated tetrachloroethane or its mixture with o-dichlorobenzene was studied using ¹H, ¹³C, ¹⁹F, ³¹P, ⁷⁵As, and ¹²¹Sb nuclear magnetic resonance (NMR) of model oligomers and the products of their end-capping with triphenylphosphine. In all cases, the nature of the propagation center has been found to be of an acylium ion pair with an SbCl₆^? or AsF₆^? counterion coordinated with the nearest benzoylamide group and cosolvated by the solvent. © 1994 John Wiley & Sons, Inc.     

Spectrophotometric study of holmium complexation in KOH solutions at 25°C

The complexation of Ho³⁺ in HoCl₃ and KOH solutions at 25°C and saturated vapor pressure was studied by an indicator spectrophotometric technique, and the pH values of the investigated solutions were determined. The stability constants of the hydroxo complexes of Ho³⁺ were measured over a range of pH 9.25–10.10 and at μ≤ 4 × 10^?4 and extrapolated to zero ionic strength.     

On accurate boundary conditions for a shape sensitivity equation method

This paper studies the application of the continuous sensitivity equation method (CSEM) for the Navier–Stokes equations in the particular case of shape parameters. Boundary conditions for shape parameters involve flow derivatives at the boundary. Thus, accurate flow gradients are critical to the success of the CSEM. A new approach is presented to extract accurate flow derivatives at the boundary. High order Taylor series expansions are used on layered patches in conjunction with a constrained least‐squares procedure to evaluate accurate first and second derivatives of the flow variables at the boundary, required for Dirichlet and Neumann sensitivity boundary conditions. The flow and sensitivity fields are solved using an adaptive finite‐element method. The proposed methodology is first verified on a problem with a closed form solution obtained by the Method of Manufactured Solutions. The ability of the proposed method to provide accurate sensitivity fields for realistic problems is then demonstrated. The flow and sensitivity fields for a NACA 0012 airfoil are used for fast evaluation of the nearby flow over an airfoil of different thickness (NACA 0015). Copyright © 2005 John Wiley & Sons, Ltd.     

Arc Discharge in a Channel with Transparent Walls at Intense Flow Rates of a Plasma Forming Gas

The arc discharge was studied in a transparent channel at an intense flow rate of nitrogen, hydrogen, air, carbon dioxide in the current range 100–1500 A. The internal diameter of the porous channel varied from 10 to 34 mm, the length - from 50 to 150 mm, the air and nitrogen flow rates - from 0.05 to 1.5 kg/s, hydrogen - from 0.005 to 0.05 kg/s. The electric field strength in the arc channel reached a value of 300 V/cm for N₂ and 500 V/cm for H₂. The effect of plasma thermochemical non-equilibrium was discovered.     

Band structures in73Se

Excited states of⁷³Se have been investigated up to spin, 21/2 using techniques of in-beamγ-ray spectroscopy in connection with the⁷⁰Ge(α, n) reaction. Mean lifetimes of 12 levels have been determined applying Doppler-shift andγ-RF-methods. Five different bands have been identified that reflect a variety of different excitation modes. The decoupled 9/2⁺ band is likely to correspond to an oblate deformation while the 5/2⁺ band is interpreted as a strongly coupled prolate band built on the Nilsson configuration [422] 5/2⁺. The 3/2^? band is a strongly coupled band built on the [301] 3/2^} configuration.Nuclear reactions:⁷⁰Ge(α,n),E=14, 16, 18, 19, 20MeV; measuredE _γ,I _γ,σ(E _γ,θ),γγ-coin, linear polarization, DSA,γ(t).⁷⁵Se deduced levels,I, π, τ, δ(E2/M1), B(σλ). Enriched targets, Ge detectors.     

Serial magnetic resonance imaging in patients following acute myocardial infarction.

The detection of serial changes in magnetic resonance (MR) signal intensity of the heart following acute myocardial infarction may provide a useful method of characterizing tissue healing. Fourteen patients with acute Q-wave infarction underwent T2-weighted, spin-echo cardiac imaging during hospitalization, followed by one or more additional MR studies (total 31) over a 6- to 27-wk period (mean: 3 mo). Visual assessment of the images demonstrated a gradual reduction in signal intensity and localization of the bright signal to the subendocardium of the infarction region over the three-mo study period. A quantitative measurement of signal intensity (infarction/normal myocardium) fell from 1.81 +/- 0.42 on the initial study to 1.34 +/- 0.37 (p less than 0.05) at a mean of 14 wk. Two patients had an increase in signal intensity on the follow-up study and both patients had been readmitted with acute coronary syndromes. In summary, characterization of changes in signal intensity may provide a useful method of assessing myocardial healing following acute myocardial infarction. Further studies are indicated to determine the prognostic significance of these parameters.