Synthesis and reactivity of sulfur and silyl substituted α-alkylidene-β-lactams

Synthetically valuable α-alkylidene-β-lactams are produced from the addition of chlorosulfonyl isocyanate to allenyl sulfides.     

Oligomerisation of phenyl acetylene over titanium oxide supported on silica - alumina catalyst

Titanium oxide on silica-alumina support is found to be effective for oligomerisation of phenyl acetylene. Cyclic trimerisation of the acetylene leading to trisubstituted benzene was also found to occur during the oligomerisation, in addition to the formation of small quantities of a ketone by the reaction of phenyl acetylene with moisture over the catalyst surface.     

Study of cosmic ray diurnal variation on a day-to-day basis

From a careful examination of the diurnal variation of cosmic ray intensity at high energies and the interplanetary field characteristics, the average characteristics of diurnal variation were recently explained by us in terms of a balance between outward convection and field aligned diffusion, the latter arising out of a positive radial density gradient. In this paper, we extend this new concept to explain the large variability observed in the diurnal variation on a day-to-day basis and further demonstrate that the measurement of diurnal anisotropy characteristic of cosmic ray particles on a day-to-day basis can be used directly to infer the nature and scale sizes of interplanetary field parameters. Comparing with the magnetic field vector, we show that this simple concept holds good on more than 80% of days. On the rest 20% of days which have a predominant morning maxima, the diurnal anisotropy characteristics seem to indicate the presence of a significant component of transverse diffusion current in addition to the normal convection and diffusion flow. Such days are found to be present in the form of trains of consecutive days and are found to be associated with abrupt changes in the interplanetary field direction having scale sizes >4 hr. The value ofK _⊥/K _‖ which is normally about ⩽0.05 is found to be ≈1.0 on non-field aligned days.     

Algorithms for discounted stochastic games

In this paper, a two-person zero-sum discounted stochastic game with a finite state space is considered. The movement of the game from state to state is jointly controlled by the two players with a finite number of alternatives available to each player in each of the states. We present two convergent algorithms for arriving at minimax strategies for the players and the value of the game. The two algorithms are compared with respect to computational efficiency. Finally, a possible extension to nonzero sum stochastic game is suggested.This research was supported in part by funds allocated to the Department of Operations Research, School of Management, Case Western Reserve University under Contract No. DAHC 19-68-C-0007 (Project Themis) with the U.S. Army Research Office, Durham, North Carolina. The authors thank the referees for their valuable suggestions.     

Magnetic moments of the 10− isomeric states in 202Bi and 204Bi

The g-factors of the 10^? isomeric states in ²⁰²Bi and ²⁰⁴Bi have been measured by the method of in-beam TDPAD. The experimental values $\text{g = 0.243(14)}\text{for}{}^{202}\text{Bi}\text{and}\text{g = 0.236(23)}\text{for}{}^{204}\text{Bi}$ confirm the previously suggested shell-model configuration.     

Oxidimetric determination of sulphides

Hypoiodite oxidises sulphides much more rapidly than does iodate under comparable experimental conditions. A procedure is reported for the determination of soluble and insoluble sulphides by oxidation to sulphate with hypoiodite. This is an improvement over Bethge's iodate method.