Dalpanio,AC-glycosylisoflavanone fromDalbergia paniculata

Dalpanin, isolated from the flowers ofDalbergia paniculata (Roxb.) has been characterised as aC-glycosylisoflavanone by chemical and spectral evidence. A provisional structure (IV) is assigned to this new compound.     

Study of isotope shifts,isotone shifts and nuclear compressibility from the analysis of muonic x-ray transitions

Muonic x-ray transitions in various spherical nuclei in the region 13?Z?83 have been analysed and the isotope and isotone shifts in charge radiusR are investigated. AssumingR=r ₀ A ^1/3, the isotopic and isotonic behaviour of the parameterr ₀ (=RA ^?1/3) is also studied. The variation ofr ₀ with mass numberA reveals the variation of average nucleon density, which in turn sheds light on the compressibility of nuclear matter. The isotope and isotone shifts inR exhibit the shell effects in the vicinity of magic neutron and proton numbers: 20, 28, 50, 82 and 126. The results indicate that neutron-proton interaction is maximum at the beginning of a major neutron shell and decreases gradually as the shell gets filled up. The behaviour of parameterr ₀ clearly suggests that low-Z nuclei are highly compressible while high-Z nuclei are more or less incompressible. The parameterr ₀ too is observed to exhibit profound shell effects.     

Symmetrizations of Markov processes

Two methods for symmetrizing Markov processes are discussed. Letu ^a(x, y) be the potential density of a Lévy process on a compact Abelian groupG. A general condition is given that guarantees thatv(x, y)=u^a(x, y)+u^a(y, x) is the potential density of a symmetric Lévy process onG. The second method arises by considering the linear space of one-potentialsU ¹ f, withf inL ², endowed with the inner product (U ¹ f,U ¹ g)=fU ¹ g+gU ¹ f. If the semigroup ofX(t) is normal, then the completionH of this space is the Dirichlet space of a symmetric processY(t). A set that is semipolar forX(t) is polar forY(t).     

An auger electron spectroscopic investigation of the electron states of copper alloys

L₃VV Auger transitions of copper alloys show a feature due to a band-like states, the shape and intensity of which depend on the composition. The energy separation between this feature and the L₃M_4·5M_4·5 peak increases progressively with Cu concentration.     

Distortion of the coordination polyhedron in mononuclear copper(II) complexes. Optical absorption and electron spin resonance studies on some five-coordinate copper(II) complexes

The preparation and spectral properties are reported for a series of ten mixed-ligand copper(II) complexes of the form [Cu(A)(B)_n](X), where A is acetylacetonate anion, B represents a mono- or bidentate ligand such as morpholine, piperidine, isonicotinic acid hydrazide, 2,2′-bipyridine, 1,10-phenanthroline and X is variously NO^?₃ or ClO^?₄ anion and n = 1 or 2. The coordination of the anions and ligands has been demonstrated by infrared and electronic spectral methods. Electron spin resonance spectral data show the square-pyramidal five-coordinated arrangement around copper(II) in these complexes. Parameters such as g₆, g_⊥, A₆, A_⊥, 〈g〉 and 〈A〉 calculated from electron spin resonance data in solid and solution state at room temperature as well as frozen solution indicate the presence of the unpaired electron in the d_x2_?y2 or d_z2 orbital. These results are in good agreement with electronic and photoacoustic spectral studies.     

Flag transitive planes of dimension four over GF(3)

Two non desarguesian flag transitive planes of order 3⁴ whose Kernel is GF(3) are constructed. These planes are distinct from the planes of the same order contained in the class constructed by Narayana Rao M. L. (Proceedings of American Mathematical Society 39 (1973) 51–56) and Ebert, G.L. and Baker, R. (Enumeration of two dimensional Flag-Transitive planes, Algebras, Groups and Geometries 3 (1985) 248–257). The Flag Transitive group modulo the scalar collineations of these planes is generated by two elements and is of order 328.     

Low-frequency vibrational modes and temperature dependence of NQR frequencies in 1,2,4,5-tetrabromobenzene

A temperature variation study of the nuclear quadrupole resonance (NQR) frequencies for the two resonance lines in 1,2,4,5-tetrabromobenzene was carried out in the range 77–300 K. The far-infrared spectrum of 1,2,4,5-tetrabromobenzene was recorded and the low-frequency vibrational modes noted. From the nine observed frequencies, the torsional modes contributing to the change in NQR frequencies with temperature are identified by correlating the calculated values of the NQR frequencies at different temperatures with the observed values.