全文获取类型
收费全文 | 286篇 |
免费 | 9篇 |
国内免费 | 1篇 |
专业分类
化学 | 212篇 |
晶体学 | 2篇 |
力学 | 2篇 |
数学 | 18篇 |
物理学 | 62篇 |
出版年
2023年 | 1篇 |
2022年 | 8篇 |
2021年 | 7篇 |
2020年 | 3篇 |
2019年 | 5篇 |
2018年 | 3篇 |
2017年 | 8篇 |
2016年 | 13篇 |
2015年 | 7篇 |
2014年 | 13篇 |
2013年 | 26篇 |
2012年 | 14篇 |
2011年 | 26篇 |
2010年 | 12篇 |
2009年 | 17篇 |
2008年 | 13篇 |
2007年 | 8篇 |
2006年 | 9篇 |
2005年 | 10篇 |
2004年 | 8篇 |
2003年 | 13篇 |
2002年 | 13篇 |
2001年 | 7篇 |
2000年 | 4篇 |
1999年 | 10篇 |
1998年 | 2篇 |
1997年 | 2篇 |
1996年 | 4篇 |
1995年 | 6篇 |
1994年 | 8篇 |
1993年 | 4篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1988年 | 1篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1982年 | 1篇 |
1980年 | 2篇 |
排序方式: 共有296条查询结果,搜索用时 15 毫秒
71.
P. A. Jr. de Souza R. S. de Queiroz T. Morimoto A. F. Guimarães V. K. Garg 《Journal of Radioanalytical and Nuclear Chemistry》2000,246(1):85-90
The application of Mössbauer spectroscopy, X-ray diffractometry, thermogravimetric analysis and PIXE in the characterization of the particulate matter in atmospheric aerosols in Metropolitan Region of Vitória (MRV), Brazil have been investigated. The main sources of particulate matter, natural, industrial and antropogenic from human activities, have been studied to identify its contribution in the atmospheric particles. During the years 1995 to 1999 samples of total suspended particles (TSP, Ø 100 m) were collected from four points within MRV. The inhalable particles (PM10 Ø 10 m) and sedimented particles (SP) were also collected from the same region. A receptor modeling was used for the identification of the source of particulate matter in the collected urban aerosol. 相似文献
72.
M. H. De. Oliveira M. E. C. Queiroz D. Carvalho S. M. Silva F. M. Lancas 《Chromatographia》2005,62(3-4):215-219
A simple, sensitive, and reproducible solid-phase microextraction and capillary gas chromatography-mass spectrometry (SPME-GC-MS) method for determination of diazepam in human plasma is described. The optimum conditions for the SPME procedure were as following: direct extraction mode with a polydimethylsiloxane (PDMS) fiber (100 μm film thickness), 250 μL of sample plasma matrix modified with a solution containing sodium chloride (10% weight by volume) and 4.25 mL of a phosphate buffer solution (0.1mol L−1, pH 6.9), extraction temperature 55°C under a magnetic stirring rate of 2500 rpm for 30 min, followed by the drug thermal desorption (250°C) in a GC injection port for 10 min. The limit of quantification of diazepam in plasma was 10.0 ng mL−1, with a coefficient of variation lower than 14.0% and linearity from 10.0 to 1000.0 ng mL−1, which allows diazepam analyses from sub to therapeutic levels. 相似文献
73.
74.
75.
76.
NMR has been used to study slow spontaneous oscillations previously observed for the activity of enzymes extracted from plant leaves and maintained under constant conditions. The randomly modulated period of these oscillations has a mean value of several hours. This phenomenon is interpreted in terms of synchronous transition among several conformational states of biomolecules. 相似文献
77.
78.
79.
80.
The enzyme catechol-O-methyltransferase (COMT) plays an important role in the metabolism of catechol estrogens and degradation of the catecholamine neurotransmitters, such as epinephrine. Several analytical methods, mainly high-performance liquid chromatography with electrochemical amperometric detection, have been reported for the analysis of catecholamines and their metabolites in biological fluids. In this paper we report the relevance of controlling temperature in calibration procedures of metanephrine, an O-methylated product of catechol-O-methyltransferase, using epinephrine as substrate. The results at higher temperatures show shorter retention times of metanephrine, no undue band-broadening and increased electro signals. This study also showed that, despite different temperatures leading to similarly specific activities of recombinant human COMT as expected, there are additional advantages in flow analytical methods where good sensitivity, efficiency and selectivity is required, mainly in tissues with low levels of COMT activity. 相似文献