Electron microscope studies of sodium and lithium intercalation in TiS2

Lithium and sodium intercalation in TiS₂ have been studied by transmission electron microscopy using lattice imaging and diffraction contrast techniques. Na_xTiS₂ samples (0 ≤ x ≤ 0.6) from $\text{Na}\text{NaI}$ in propylene carbonate/TiS₂ batteries were found to contain a complex variety of phases inhomogeneous on a fine scale. Observations showed variable staging and a 2H phase not previously reported for this system at ambient temperatures. Observations on both Na_xTiS₂ and chemically prepared Li_xTiS₂ showed highly dislocated structures. A model is proposed whereby dislocations are introduced to accommodate misfit strains caused by nonuniform intercalation and, in the case of Na_xTiS₂, to initiate phase transformations, leading to potentially irreversible structural changes in cycled material.     

Influence of extrasphere cations on the thermal stability of hydrates of iron (III) ethylenediaminetetraacetates

Russian Chemical Bulletin -     

UV-visible spectroscopic study of the salicyladehyde benzoylhydrazone and its cobalt complexes

Salicyladehyde benzoylhydrazone (SBH) has three groups suitable for forming coordination bond with transition metal. The UV-vis absorption spectra of SBH and its Co(II) complexes in various media were studied by using the deconvolution method. It is found that the structure of complex in solution is different from those in solid crystals. The nature of complexes in solution depends on acidity of the phenolic proton of SBH and on the medium. In neutral or slightly acid medium, the SBH is a non-charged bidentate ligand. And the "free" hydroxyl group on the SBH molecule makes it possible to form hydrogen bonds in solution. In basic medium, the SBH is a mono, negatively charged tridentates ligand.     

Laboratory singing sand avalanches

Some desert sand dunes have the peculiar ability to emit a loud sound up to 110 dB, with a well-defined frequency: this phenomenon, known since early travelers (Darwin, Marco Polo, etc.), has been called the song of dunes. But only in late 19th century scientific observations were made, showing three important characteristics of singing dunes: first, not all dunes sing, but all the singing dunes are composed of dry and well-sorted sand; second, this sound occurs spontaneously during avalanches on a slip face; third this is not the only way to produce sound with this sand.More recent field observations have shown that during avalanches, the sound frequency does not depend on the dune size or shape, but on the grain diameter only, and scales as the square root of g/d - with g the gravity and d the diameter of the grains - explaining why all the singing dunes in the same vicinity sing at the same frequency.We have been able to reproduce these singing avalanches in laboratory on a hard plate, which made possible to study them more accurately than on the field. Signals of accelerometers at the flowing surface of the avalanche are compared to signals of microphones placed above, and it evidences a very strong vibration of the flowing layer at the same frequency as on the field, responsible for the emission of sound.Moreover, other characteristics of the booming dunes are reproduced and analyzed, such as a threshold under which no sound is produced, or beats in the sound that appears when the flow is too large. Finally, the size of the coherence zones emitting sound has been measured and discussed.     

A remark on ψ–Hilfer fractional differential equations with non-instantaneous impulses

We present a reasonable concept for solutions of non-instantaneous impulsive Cauchy problems with a ψ–Hilfer fractional derivative. Also, we provide a new sufficient condition for the existence, uniqueness, and stability of solutions for the given problem.     

The Bhattacharya Function of Complete Monomial Ideals in Two Variables

We give explicit formulas for the Bhattacharya function of 𝔪-primary complete monomial ideals in two variables in terms of the vertices of the Newton polyhedra or in terms of the decompositions of the ideals as products of simple ideals.