原子荧光法测定甘草中汞

利用还原气化的非色散型装置，以湿法消解的方式，对中药甘草中的痕量汞进行了原子荧光测定。研究了影响测定结果的条件，比较了两种玻璃仪器的洗涤方式，并以工作曲线法和加入作图法对照，试验回收率在86．9％－110．8％，误差＜13．1％，得出了满意的分析结果。     

B -值白噪声广义泛函的解析刻画

Banach空间值白噪声广义泛函是一类重要的向量值白噪声广义泛函. 该文建立了Banach空间值白噪声广义泛函的一个解析刻画定理, 并给出了此结果的若干应用.     

变质CH13钢中Ce_2O_3异质核心作用的研究

采用变质处理大大减弱了CH13钢枝晶组织的元素偏析 ,使未变质CH13钢中的晶界碳化物得以消除 ,CH13钢的冲击韧性大大提高。通过热力学计算及二维点阵错配度计算 ,并采用电子探针定量分析等手段 ,证实Ce2 O3型稀土夹杂物可作为CH13钢中初生奥氏体的异质核心 ,细化枝晶组织 ,减弱合金元素偏析     

氨基酸及其衍生物的手性识别研究进展

本文综述了近年来开拓的多种人工受体模型对氨基酸及其衍生物的对映选择性识别性能，并做了相互比较，从中总结出手性识别的几个基本原则，预期了其应用前景。     

Lanthanide complexes with polyaminopolycarboxylates as prospective NMR/MRI diagnostic probes: peculiarities of molecular structure,dynamics and paramagnetic properties

Journal of Inclusion Phenomena and Macrocyclic Chemistry - The paramagnetic lanthanide complexes with polyaminopolycarboxylate (PAPC) ligands attract considerable attention from the standpoint of...     

High-Performance Heterogeneous Thermocatalysis Caused by Catalyst Wettability Regulation

Catalyst wettability regulation has emerged as an attractive approach for high catalytic performance for the past few years. By introducing appropriate wettability, the molecule diffusion of reactants and products can be enhanced, leading to high activity. Besides this, undesired molecules are isolated for high selectivity of target products and long-term stability of catalyst. Herein, we summarize wettability-induced high-performance heterogeneous thermocatalysis in recent years, including hydrophilicity, hydrophobicity, hybrid hydrophilicity-hydrophobicity, amphiphilicity, and superaerophilicity. Relevant reactions are further classified and described according to the reason for the performance improvement. It should be pointed out that studies of utilizing superaerophilicity to improve heterogeneous thermocatalytic performance have been included for the first time, so this is a comparatively comprehensive review in this field as yet.     

Triindolo-Truxene Derivatives: Design,Synthesis, and Fine-Tuning of Electronic Properties and Molecular Assembly through Molecular Engineering

Triindolo-truxene, a C₃-symmetric molecule with a large π-conjugated plane, has six methylene carbon atoms and three aromatic carbon atoms that can be facilely functionalized. Herein, butyl, carbonyl, cyano, and/or malononitrile groups were introduced at six methylene carbon atoms (6-, 14-, 22- or 8-, 16-, 24-positions) and/or three aromatic carbon atoms (2-, 10-, and 18-positions) of triindolo-truxene to produce eight derivatives. Their photophysical properties, electrochemical properties, and molecular assembly can be effectively modulated by substituents and substitution patterns. Incorporation of electron-deficient groups led to redshifts in both the absorption and emission of these derivatives and also lowered their HOMO and LUMO levels. Different substitution patterns resulted in the different intramolecular donor–acceptor interactions. Electron-deficient substituents at the methylene carbon atoms in the 6-, 14-, and 22-positions led to intramolecular charge transfer from the fluorene arms to the truxene core, whereas the corresponding substitutions at the methylene carbon atoms in the 8-, 16-, and 24-positions resulted in intramolecular charge transfer from the truxene core to the fluorene arms. The molecular packing in single crystals and molecular aggregation in solution are also influenced by the substituents and substitution patterns. This work provides a straightforward strategy to alter the properties of triindolo-truxene.