三效吸收式制冷循环系统性能分析

对12个通用的三效循环系统以及这12个通用循环系统组成的76种可能的密闭循环系统进行了评测。根据通用三效循环系统的压力和溶解度要求,对通用三效循环系统进行了分析,并充分考虑各部件设计中的问题和COPs数值,以及处于高腐蚀环境中部件的数目。通过分析,确定了四个性价比较优的系统:Alkitrate Topping循环系统,Pressure Staged Envelope循环系统,High Overlap循环系统和Dual Loop循环系统。     

H基于模糊观测器参数摄动的耦合时空混沌H跟踪控制

由于子系统的时空耦合作用及参数的摄动性，实现参数摄动的耦合时空混沌的跟踪控制非常困难。然而模型未知的耦合时空混沌的每个子系统可由一系列模糊逻辑模型逼近，每个模糊逻辑模型代表子系统在特定运行点的局部线性化模型，同时考虑子系统状态的不可测性，采用模糊观测器来估计子系统的状态。基于模糊模型及状态观测器，计及混沌参数的摄动性，提出一种模糊跟踪控制方案，实现了参数摄动的耦合时空混沌的鲁棒跟踪控制，并将模糊跟踪控制表征为线性矩阵不等式问题，用线性矩阵不等式的凸优化方法求解控制器参数，确保系统的全局渐近稳定性。仿真验证了方案的有效性。     

Stress evolution and lattice distortion induced by thickness variation and lattice misfit in La0.67Sr0.33MnO3−δ films

La_0.67Sr_0.33MnO_3?δ thin films with different thicknesses are prepared in order to investigate the structural variation induced by film thickness and lattice misfit. The X-ray diffraction results show the in-built stress evolution from a full strained thin layer (～10 nm) to a completely relaxed thick layer (～150 nm), which can be well explained by the Poisson effect. Raman spectroscopy measurements reveal the complicated correlation between the Jahn–Teller (JT) distortion and film thickness. Important octahedron modes reflecting JT distortion are completely caused by the relaxed layer. It is observed that broad JT bands are formed in the films with large thickness of the relaxed layer and the residual stress in the layer leads to an obvious blue shift. In contrast, for films with the thin relaxed layer, JT modes are present as a sharper structure and move to low frequency, indicating towards a much better oxygen stoichiometry.     

在有限空间内生成的晶格高度取向的ZnO纳米颗粒

应用固态反应的方法,在260和300 oC空气中分别热分解层状锌油酸固体得到氧化锌纳米颗粒/团簇．高分辨透射电子显微镜和选区电子衍射表明,这种团簇是带有各种缺陷的单晶．光致发光激发光谱表明这两个样品在272和366 nm有两个频段．前者可能是由于不到200个氧化锌分子组成的团簇从价带到导带的电子转移引起的．     

Rayleigh散射Doppler激光雷达风场反演方法改进

在Rayleigh散射Doppler激光雷达的风场反演过程中,除了温度、压强等因素之外,风速反演结果的 准确性还受到Mie散射信号的影响．当Mie散射信号较强时,尤其是遇到高层云或火山灰等情况,如果仍不考虑 气溶胶信号,由于温度不确定度和气溶胶信号的综合影响,风速反演结果将与真值偏差很大．本文提出了利用 激光雷达在垂直方向的测量信号同时反演后向散射比和大气温度的非线性迭代算法,并优化给出了最佳的 初始发射激光工作点．仿真试验结果表明:该方法可以准确有效地反演后向散射比;将该方法结合非线性迭代 风速反演方法,可以有效消除气溶胶后向散射信号的影响,进一步提高大气风速和温度的反演精度．     

On the index of Fredholm pairs of idempotents

Using the technique of block-operators, in this note, we prove that if P and Q are idempotents and （P - Q）^2n＋1 is in the trace class, then （P - Q）^2m＋1 is also in the trace class and tr（P - Q）^2m＋1 = dim（k（P） ∩ k（Q）^⊥） -dim（k（P）^⊥ N k（Q））, for all m ≥ n. Moreover, we prove that dim（k（P）∩ k（Q）^⊥） = dim（k（P）^⊥ ∩k（Q）） if and only if there exists a unitary U such that UP = QU and PU = UQ, where k（T） denotes the range of T. Keywords Fredholm, orthogonal projection, positive operator     

Congruences for (3,11)-regular bipartitions modulo 11

In this note we investigate the function \(B_{k,\ell }(n)\), which counts the number of \((k,\ell )\)-regular bipartitions of n. We shall prove an infinite family of congruences modulo 11: for \(\alpha \ge 2\) and \(n\ge 0\),

$$\begin{aligned} B_{3,11}\left( 3^{\alpha }n+\frac{5\cdot 3^{\alpha -1}-1}{2}\right) \equiv 0\ (\mathrm{mod\ }11). \end{aligned}$$

     

1H NMR Studies on the Methylation,Protonation, and Hydration Sites in Some Benzo[b]Naphthyridines (Azaacridines)

Abstract

The 300.13 MHz ¹H NMR spectra of the methylated and protonated 6(9)-methylbenzo[b][1,x] naphthyridines (x=5, 6, 7, 8) (5-methylazaacridines) were collected at 298 K in deuterated dimethyl sulfoxide and chloroform, respectively. The methylation and protonation sites were assigned by comparisons of these data with those of the free bases. The results were compared with similar data for related heterocycles and showed that both methylation and protonation occur at the nitrogen in the outer pyrido ring in all four series.

The hydration site in some 2-and 3-azaacridines was determined by specific line broadening in their ¹H NMR spectra to be the same nitrogen as that involved in methylation and protonation. Variable temperature ¹H NMR demonstrated that the specific line broadening results from some changes of ¹⁴N quadrupolar relaxation produced by the slow chemical exchange between unhydrated and hydrated species. Deuterium exchange experiments indicated that the direct spin-spin interaction of a water proton and the protons alpha to the hydrated nitrogen may also have some contribution.     

外场形式对超冷原子-多聚物分子转化效率的影响

通过改变激光场Rabi频率和原子-多聚物分子耦合强度, 探索了外场形式对超冷原子-多聚物分子转化效率的影响. 首先通过定义时间指数, 对文献所给出的外场做出改进, 讨论了时间指数对转化效率的影响; 然后选取一种更优化的外场形式, 其具有很好的参数鲁棒性, 该外场作用下的绝热过程几乎不存在振荡, 其绝热保真度接近于1, 系统误差较小, 可以稳定、高效地实现超冷原子-多聚物分子的转化. 关键词： 超冷多聚物分子 转化效率 外场形式 绝热保真度     

一类四阶变分不等式解的极限正则性

An example of a fourth order variational inequality is structed in this note. The example shows; u∈H^3+σ(Ω) with every σ<0.5(but u(?) H^3.5(Ω)) is limiting regularity of solution u of a fourth order variational inequality with displacement obstacle.