Lattice Distortion in Hollow Multi-Shelled Structures for Efficient Visible-Light CO2 Reduction with a SnS2/SnO2 Junction

Precise control of the micro-/nanostructures of nanomaterials, such as hollow multi-shelled structures (HoMSs), has shown its great advantages in various applications. Now, the crystal structure of building blocks of HoMSs are controlled by introducing the lattice distortion in HoMSs, for the first time. The lattice distortion located at the nanoscale interface of SnS₂/SnO₂ can provide additional active sites, which not only provide the catalytic activity under visible light but also improve the separation of photoexcited electron–hole pairs. Combined with the efficient light utilization, the natural advantage of HoMSs, a record catalytic activity was achieved in solid–gas system for CO₂ reduction, with an excellent stability and 100 % CO selectivity without using any sensitizers or noble metals.     

Engineering the Atomic Interface with Single Platinum Atoms for Enhanced Photocatalytic Hydrogen Production

It is highly desirable but challenging to optimize the structure of photocatalysts at the atomic scale to facilitate the separation of electron–hole pairs for enhanced performance. Now, a highly efficient photocatalyst is formed by assembling single Pt atoms on a defective TiO₂ support (Pt₁/def‐TiO₂). Apart from being proton reduction sites, single Pt atoms promote the neighboring TiO₂ units to generate surface oxygen vacancies and form a Pt‐O‐Ti³⁺ atomic interface. Experimental results and density functional theory calculations demonstrate that the Pt‐O‐Ti³⁺ atomic interface effectively facilitates photogenerated electrons to transfer from Ti³⁺ defective sites to single Pt atoms, thereby enhancing the separation of electron–hole pairs. This unique structure makes Pt₁/def‐TiO₂ exhibit a record‐level photocatalytic hydrogen production performance with an unexpectedly high turnover frequency of 51423 h^?1, exceeding the Pt nanoparticle supported TiO₂ catalyst by a factor of 591.     

空气 - 乙炔火焰原子吸收法连续测定铜粉中微量Fe、Pb、Sb、Zn和Ni

用HNO3-HCl溶解试样,在几个相同量的试液中,分别加入质量浓度依次递增的5种元素的标准溶液,用火焰原子吸收法连续测定了Fe、Pb、Sb、Zn和Ni的含量,建立了优化的仪器测定条件,并对可能存在的元素进行了干扰试验。结果表明,Fe、Pb、Sb等5种元素的回收率为98.0%～102.3%,相对标准偏差为1.4%～2.5%。     

Output feedback regulation of time-delay nonlinear systems with unknown continuous output function and unknown growth rate

Nonlinear Dynamics - This paper is concerned with the global regulation via output feedback for the time-delay nonlinear systems with unknown continuous output function and unknown growth rate....     

Ballistic Resistance of Novel Amorphous-Alloy-Reinforced Perforated Armor

A new concept of lightweight structure,namely amorphous-alloy-reinforced perforated armor(ARPA)consisting of the amorphous alloy coating and perforated metal substrate plate,is proposed.The ballistic performance of the ARPA is investigated numerically.The failure modes of ARPA and projectiles are identified,and the defeating mechanism of the ARPA is explored.It is shown that the amorphous alloy coating is helpful for enhancing the target’s ballistic performance by seriously eroding and fracturing the penetrators.The effects of coating thickness,initial impact velocity and impact angle are also discussed for the target’s ballistic performance.The optimal design of coating thickness may be necessary for enhancing the ballistic resistance of ARPAs.     

亚甲胺叶立德与环丙基亚甲基乙酸乙酯参与的催化不对称exo-1,3-偶极环加成反应构建5-氮杂-螺[2,4]庚烷片段

首次研究了Cu（CH₃CN）₄BF₄/DTBM-BIPHEP催化的亚甲胺叶立德与环丙基亚甲基乙酸乙酯参与的不对称1,3-偶极环加成反应,获得了优异的exo-选择性,研究结果证实大空间位阻的手性双膦配体对反应的非对映选择性控制起到至关重要的影响;同时一步高效构建三个叔碳手性中心和一个螺环季碳中心. 该不对称1,3-偶极环加成反应收率良好,得到优秀的非对映（>98：2,dr）与对映选择性（ee值高达99%）. 该催化体系为合成exo构型的5-氮杂-螺[2,4]庚烷衍生物提供了一种简洁高效的方法,具有原子经济性好、反应条件温和、底物适用范围广等优点.     

跳马项目的三维实时动态测量系统

为跳马项目研究的电测系统中引入数字信号处理的传递函数及频谱分析的方法,采集和处理了因人体冲击三维力对信号的耦合干扰造成的十分复杂的响应信号,具有较高的动态测试精度.可以获得跳马动作的全部运动生物力学参数.现已用于中国国家体操队进行计算机辅助训炼.     

浅海温跃层声散射实验研究

本文给出１９８８、１９８９和１９９２年夏季南黄海海域三站位（水深３４米、４４米和３９米）处的温跃层声脉冲反向散射实验结果。实验用窄带脉冲声源的中心频率分别为１２０ｋＨｚ、１６０ｋＨｚ和２００ｋＨｚ。实验过程中同时用ＣＴＤ仪昼夜分段记录温、盐、深参数和分层拖网采集浮游生物样本。作者根据Ｒ．Ｋｉｎｄ关于平面波在任意分布不均匀层系上反射系数谱的计算方法，求出以实测温、盐垂直分布构成的不均匀层系上反射系数谱，得到跃层散射在时域上的数值模拟散射信号，与海上实测记录在时域和幅度进行对比。三年同期重复实验结果表明：实测跃层散射波到达接收点的时间与按温度剖面所做数值模拟计算结果相符。浮游生物样品分析数据与声信号记录看不出确定的对应关系，说明声散射主要是海水介质的物理不均匀性引起。     

冈村枝管藻孢子体的形态和超微结构

从日本冲绳采回枝管藻，用毛细管将成熟多室孢子囊挑出，在试验室条件下培养，可长成孢子体．用光学显微镜和透射电子显微镜观察发现：孢子释放后形成盘状体附着在基质上，念珠状同化丝从盘状体中间分生．同化丝可从中间部位产生分支，多室孢子囊位于部分同化丝的近端部；同化丝大量产生后基部细胞平行排列，中空，形成假薄壁组织，而后孢子体进入伸长生长阶段；在每个盘状体细胞和同化丝细胞中都有多个色素体和线粒体，蛋白核突出于色素体其他部分，类脂体存在于类囊体中；在同化丝的细胞壁上存在缺口；对同化纤毛而言，色素体和线粒体数量少，紧贴细胞膜，质壁分离严重，在细胞壁上存在“通道”．