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21.
乙酰水扬酸在CTAB胶束溶液中的水解反应 总被引:2,自引:0,他引:2
乙酰水扬酸(阿斯匹林)具有较高的药用价值,对它的性质有较多的研究,如在水中的稳定性和水解等。乙酰水扬酸有一个脂键和一个羰基。脂键易水解,水解后药用价值虽未降低,但有很大的副作用,因而研究抑制乙酰水扬酸水解是很有意义的。本文用RD—Ⅲ型热导式自动量热计研究了在十六烷基三甲基溴化胺(CTAB)胶束溶液中乙酰水扬酸的水解反应热动力学。 相似文献
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研究了半导体隔片光电化学电池(SC-SEP)中光池溶液的pH、暗池溶液的氧化还原电对以及两池中的暗电极对电池的开路电压、光生电压、短路光电流和光伏安特性的影响。对它们的影响机制进行了初步分析。通过合理选择电池体系,SC-SEP的性能可比单隔室的光电化学电池(PEC)优越。 相似文献
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This paper considers the macroscopic and microscopic statistical features of the top 500 firms in China, the United States and the world, denoted as China 500 (CH500), Fortune 500 (US500) and Fortune Global 500 (FG500). From a macroscopic perspective, the firm size distribution of each category, when measured by revenue, is steadily distributed over the observed period, even during periods of financial crises. As is evidenced by the Gini coefficient, divergences between firm scales are most significant for the CH500. From a microscopic perspective, the underlying micro-dynamics are volatile and often turbulent due to the exit and entry of firms as well as shifts in their revenues and ranks. Such fluctuations, or mobility, are visualized in rank/revenue/share clocks. We also propose a revenue/rank/share mobility index that is a quantitative measurement of mobility. Among these, we find that the share mobility acts as an effective indicator of economic status; where there is a share mobility spike, there is an ailing economy. The share mobility indexes indicate that the 2008 Financial Crisis had little impact on the Chinese economy, while it triggered violent changes in the top 500 firms in the United States and the world. 相似文献
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Qinghua Cai Zakaria Mohamad Yuan Yuan 《Communications in Nonlinear Science & Numerical Simulation》2012,17(12):4856-4869
We propose two nutrient-phytoplankton models with instantaneous and time delayed recycling, investigate the dynamics and examine the responses to model complexities. Instead of the familiar specific uptake rate and growth rate functions, we assume only that the nutrient uptake and phytoplankton growth rate functions are positive, increasing and bounded above. We use geometrical and analytical methods to find conditions for the existence of none, one, or at most two positive steady states and analyze the stability properties of each of these equilibria. With the variation of parameters, the system may lose its stability and bifurcation may occur. We study the occurrence of Hopf bifurcation and the possibility of stability switching. Numerical simulations illustrate the analytical results and provide further insight into the dynamics of the models, biological interpretations are given. 相似文献
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Qinghua Xie Xia Li Guanquan Wang Xuan Hou Yujun Wang Hongbo Yu Changfa Qu Shunzhong Luo Yali Cui Chuanqin Xia Ruibing Wang 《Journal of Radioanalytical and Nuclear Chemistry》2017,311(3):1697-1708
Here we reported the radiolabeling and evaluation of a novel 131I-radiolabeled quercetin for the treatment of dedifferentiated thyroid cancers. The human thyroid cancer cell lines (FTC-133, TT and DRO) experienced much higher uptake of 131I-quercetin as compared to the free 131I. And the proliferation inhibition rate of 131I-quercetin on in vitro DRO cell line was 86.87 ± 7.15%. Biodistribution and SPECT analysis demonstrated that the injected radioactivity mainly accumulated in tumors. The tumor volume in the treatment group was dramatically inhibited in comparison with the control group. 相似文献
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Extended field-of-view (EFOV) can acquire a full field of vision, which can help doctors to make more objective and accurate diagnosis. Current EFOV techniques suffer from the low computation speed due to the large amount of ultrasound data to be processed. This paper describes an efficient technique to register 2D multiframe ultrasound images and produce EFOV images with significantly reduced computation time based on a standard PC. For registration of any two adjacent images, we propose to select less image blocks which are regarded as the most valid blocks based on the importance of image content. In registration of a sequence of images, with an assumption that the moving direction and speed of the probe are nearly identical during the data collection, we estimate the moving speed of the probe at the beginning of data collection and ignore redundant image data by processing a smaller number of frames according to a frame interval. The experimental results show that the computation speed of our method is increased by 7–80 times in comparison with two traditional methods, and can accurately produce EFOV images in real-time. 相似文献
29.
Suppression of the Charge Density Wave State in Two-Dimensional 1T-TiSe2 by Atmospheric Oxidation
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Lifei Sun Chuanhui Chen Dr. Qinghua Zhang Christian Sohrt Tianqi Zhao Dr. Guanchen Xu Jinghui Wang Prof. Dong Wang Prof. Kai Rossnagel Prof. Lin Gu Prof. Chenggang Tao Prof. Liying Jiao 《Angewandte Chemie (International ed. in English)》2017,56(31):8981-8985
Two-dimensional (2D) metallic transition-metal dichalcogenides (TMDCs), such as 1T-TiSe2, have recently emerged as unique platforms for exploring their exciting properties of superconductivity and the charge density wave (CDW). 2D 1T-TiSe2 undergoes rapid oxidation under ambient conditions, significantly affecting its CDW phase-transition behavior. We comprehensively investigate the oxidation process of 2D TiSe2 by tracking the evolution of the chemical composition and atomic structure with various microscopic and spectroscopic techniques and reveal its unique selenium-assisting oxidation mechanism. Our findings facilitate a better understanding of the chemistry of ultrathin TMDCs crystals, introduce an effective method to passivate their surfaces with capping layers, and thus open a way to further explore the functionality of these materials toward devices. 相似文献
30.
本文以聚乙二醇(PEG)为相变材料,通过添加不同的无机填料,采用熔融共混浇筑方式制备了导热增强型相变复合材料。 通过扫描电子显微镜(SEM)、热常数分析仪、差示扫描量热仪(DSC)、红外热成像和热重分析仪研究了所制备复合材料的微观结构、导热性能与相变过程。 研究结果表明,相比于碳酸钙和氧化铝,在相同添加含量下,氮化硼(BN)可有效提高PEG的导热系数,当BN质量分数为40%时,导热系数可达到3.40 W/(m·K);当填料添加量相同时,片状BN和不规则纳米碳酸钙(CaCO3)比球形氧化铝(Al2O3)对PEG具有更加优良的定型效果,在相变过程中,能够更加有效阻隔PEG的流动,保持复合材料的形状稳定性。 相似文献