丙烯酰胺与丙烯酸十四酯共聚物的合成及性能研究

利用过氧化苯甲酰为引发剂探讨了丙烯酰胺（ＡＭ）和丙烯酸十四酯（ＴＡ）的自由基共聚合。重点讨论了合成条件如引发剂用量，单体配比、溶剂、温度等对共聚反应及共聚物对苯丙乳胶增稠性能的影响。并用ＩＲ和凯达定氮法表征了共聚物的组成，实验结果表明，ＡＭｔ ＴＡ进行沉淀聚合所得到的共物分子量足够大，可以作为疏水缔合型稠剂使用。     

Stereoselective Synthesis of 2-(4-Hydroxyphenyl)-3-hydroxymethyl-1,4-benzodioxane-6-aldehyde—The Key Intermediate of Sinaiticin

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Heat-transfer characteristics of climbing film evaporation in a vertical tube

Heat-transfer characteristics of climbing film evaporation were experimentally investigated on a vertical climbing film evaporator heated by tube-outside hot water. The experimental setup was designed for determining the effect of the height of feed water inside a vertical tube and the range of temperature difference on local heat transfer coefficient inside a vertical tube (h_i). In this setup, the height of feed water was successfully controlled and the polypropylene shell effectively impedes the heat loss to the ground. The results indicated that a reduction in the height of feed water contributed to a significant increase in h_i if no dry patches around the wall of the heated tube appeared inside the tube. The height ratio of feed water R_h = 0.3 was proposed as the optimal one as dry patches destroyed the continuous climbing film when R_h is under 0.3. It was found that the minimum temperature difference driving climbing film evaporation is suggested as 5 °C due to a sharp reduction in h_i for temperature difference below 5 °C. The experiment also showed that h_i increased with an increase in temperature difference, which proved the superiority of climbing film evaporation in utilizing low-grade surplus heating source due to its wide range of driving temperature difference. The experimental results were compared with the previous literature and demonstrated a satisfactory agreement.     

A New Capillary Electrophoresis Apparatus with Piezoelectric Ceramics High Voltage Source and Amperometric Detector

IntroductionHighperformancecapiliar}'electrophoresis(HPCE)isanewanalyticaltechnology'rapidly'developedinrecentyears.Withtheadvantagesofsmallsample.highsensitivity,highresolution.rapidanalysisandverycheaprunning,ithasbeenappliedinchemistry'.lifescienc...     

Studies on Chem icalCom position ofIron-m olybdenum Cofactor fromNitrogenase by Fluorescence Analysis

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One-step synthesis and characterization of dendrimer-protected gold nanoparticles

We proposed an economic, convenient, and mild synthesis of dendrimer-protected gold nanoparticles by exposing a third-generation poly(propyleneimine) dendrimer-HAuCl₄ aqueous solution to sunlight without the additional step of introducing other reducing agents and protective agents. Most importantly, it is found that the size of the gold nanoparticles thus formed can be controlled by the molar ratio of the dendrimer to gold. The text was submitted by the author in English.