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111.
112.
In CZE, the adsorption of the proteins on the capillary wall is a common problem. This paper describes the simple method of utilizing zwitterionic buffer additives to improve the separation of proteins in untreated fused silica capillaries at neutral pH. Three kinds of zwitterion are evaluated in the separation of acidic, neutral, and basic proteins, including their effect on protein efficiency, mobility, separation, and resolution; the difference between the effects of the different additives are also highlighted. The method has proved to be a possible means of reducing protein adsorption, especially for basic proteins. 相似文献
113.
Xiao Huang Bishwa Ranjan Nayak Tao Lu Lowe 《Journal of polymer science. Part A, Polymer chemistry》2004,42(20):5054-5066
A series of novel multifunctional hydrogels that combined the merits of both thermoresponsive and biodegradable polymeric materials were designed, synthesized, and characterized. The hydrogels were copolymeric networks composed of N‐isopropylacrylamide (NIPAAM) as a thermoresponsive component, poly(L‐lactic acid) (PLLA) as a hydrolytically degradable and hydrophobic component, and dextran as an enzymatically degradable and hydrophilic component. The chemical structures of the hydrogels were characterized by an attenuated total reflection–Fourier transform infrared spectroscopy (ATR–FTIR) technique. The hydrogels were thermoresponsive, showing a lower critical solution temperature (LCST) at approximately 32 °C, and their swelling properties strongly depended on temperature changes, the balance of the hydrophilic/hydrophobic components, and the degradation of the PLLA component. The degradation of the hydrogels caused by hydrolytic cleavage of ester bonds in the PLLA component was faster at 25 °C below the LCST than at 37 °C above the LCST, determined by the ATR–FTIR technique. Due to their multifunctional properties, the designed hydrogels show great potential for biomedical applications, including drug delivery and tissue engineering. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5054–5066, 2004 相似文献
114.
Tao Bo 《数学学报(英文版)》1992,8(1):46-59
In this paper the thought on the uniform convergence of an empirical Bayes estimator or linear empirical Bayes (l.e.B.) estimator
is advanced. Under two different models the l.e.B. estimators of the parameter are constructed respectively. It is proved
that the convergence rates and uniform convergence rates of these l.e.B. estimators are all one with respect to the corresponding
prior families. It is shown that the uniform convergence rate one is the best, under mild assumptions imposed on the conditional
density of the sample. 相似文献
115.
Based on the Kachanov method and the alternating iteration technique, a new method is proposed to deal with the problem of the strongly interacted multiple cracks in an infinite plate. Unlike the Kachanov method which neglects the interaction of the tractions of the non-uniform components, the tractions of the non-uniform components on the surfaces of cracks are considered through the alternating technique. The accuracy and efficiency of present method are validated by comparing the results of two collinear and two parallel overlapped open the cracks obtained by the present method with those of the exact solutions, the results of the Kachanov method and the alternating iteration technique. Applications of present method in solving sliding close crack problems and evaluating the plastic zones demonstrate the versatility of present method. 相似文献
116.
Super-Wavelets and Decomposable Wavelet Frames 总被引:4,自引:0,他引:4
A wavelet frame is called decomposable whenever it is equivalent to a superwavelet frame of length greater than one. Decomposable
wavelet frames are closely related to some problems on super-wavelets. In this article we first obtain some necessary or sufficient
conditions for decomposable Parseval wavelet frames. As an application of these conditions, we prove that for each n > 1 there
exists a Parseval wavelet frame which is m-decomposable for any 1 < m ≤ n, but not k-decomposable for any k > n. Moreover,
there exists a super-wavelet whose components are non-decomposable. Similarly we also prove that for each n > 1, there exists
a Parseval wavelet frame that can be extended to a super-wavelet of length m for any 1 < m ≤ n, but can not be extended to
any super-wavelet of length k with k > n. The connection between decomposable Parseval wavelet frames and super-wavelets is
investigated, and some necessary or sufficient conditions for extendable Parseval wavelet frames are given. 相似文献
117.
We describe one convenient synthesis route to boron nitride (BN) nanotube by the reaction of boron powder, iron oxide, and ammonium chloride at 600 °C for 12 h. Characterized by XRD, FTIR, XPS, TEM and SAED, the composition and morphology of the products are confirmed. The possible reaction mechanism is also discussed. 相似文献
118.
119.
光子晶体的原理与应用 总被引:1,自引:0,他引:1
光子晶体是一种在微米、亚微米等光波长量级上折射率呈现周期性变化的介质材料,它使某些频率范围内的光子态密度大大降低.甚至完全形成光子禁带.本文介绍了光子晶体的原理、制备及应用. 相似文献
120.
Yonggang Shangguan Li Zhao Liyang Tao Qiang Zheng 《Journal of Polymer Science.Polymer Physics》2007,45(13):1704-1712
The effects of preparation method, composition, and thermal condition on formation of β‐iPP in isotactic polypropylene/ethylene–propylene rubber (iPP/EPR) blends were studied using modulated differential scanning calorimeter (MDSC), wide angle X‐ray diffraction (WAXD), and phase contrast microscopy (PCM). It was found that the α‐iPP and β‐iPP can simultaneity form in the melt‐blended samples, whereas only α‐iPP exists in the solution‐blended samples. The results show that the formation of β‐iPP in the melt‐blended samples is related to the crystallization temperature and the β‐iPP generally diminishes and finally vanishes when the crystallization temperature moves far from 125 °C. The phenomena that the lower critical temperature of β‐iPP in iPP/EPR obviously increases to 114 °C and the upper critical temperature decreases to 134 °C indicate the narrowing of temperature interval, facilitating the formation of β‐iPP in iPP/EPR. Furthermore, it was found that the amount of β‐iPP in melt‐blended iPP/EPR samples is dependent on the composition and the maximum amount of β‐iPP formed when the composition of iPP/EPR blends is 85:15 in weight. The results through examining the effect of annealing for iPP/EPR samples at melt state indicate that this annealing may eliminate the susceptibility to β‐crystallization of iPP. However, only α‐iPP can be observed in solution‐blended samples subjected to annealing for different time. The PCM images demonstrate that an obvious phase‐separation happens in both melt‐blended and solution‐blended iPP/EPR samples, implying that compared with the disperse degree of EPR in iPP, the preparation method plays a dominant role in formation of β‐iPP. It is suggested that the origin of formation of β‐iPP results from the thermomechanical history of the EPR component in iPP/EPR. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1704–1712, 2007 相似文献