全文获取类型
收费全文 | 16646篇 |
免费 | 2544篇 |
国内免费 | 2405篇 |
专业分类
化学 | 13005篇 |
晶体学 | 203篇 |
力学 | 883篇 |
综合类 | 239篇 |
数学 | 2009篇 |
物理学 | 5256篇 |
出版年
2024年 | 51篇 |
2023年 | 281篇 |
2022年 | 472篇 |
2021年 | 507篇 |
2020年 | 640篇 |
2019年 | 610篇 |
2018年 | 546篇 |
2017年 | 506篇 |
2016年 | 804篇 |
2015年 | 792篇 |
2014年 | 1049篇 |
2013年 | 1256篇 |
2012年 | 1464篇 |
2011年 | 1493篇 |
2010年 | 1148篇 |
2009年 | 1041篇 |
2008年 | 1143篇 |
2007年 | 972篇 |
2006年 | 873篇 |
2005年 | 766篇 |
2004年 | 745篇 |
2003年 | 628篇 |
2002年 | 716篇 |
2001年 | 565篇 |
2000年 | 417篇 |
1999年 | 386篇 |
1998年 | 245篇 |
1997年 | 173篇 |
1996年 | 203篇 |
1995年 | 163篇 |
1994年 | 136篇 |
1993年 | 129篇 |
1992年 | 108篇 |
1991年 | 106篇 |
1990年 | 72篇 |
1989年 | 64篇 |
1988年 | 47篇 |
1987年 | 43篇 |
1986年 | 40篇 |
1985年 | 35篇 |
1984年 | 13篇 |
1983年 | 7篇 |
1982年 | 10篇 |
1981年 | 10篇 |
1980年 | 8篇 |
1963年 | 7篇 |
1959年 | 12篇 |
1958年 | 11篇 |
1957年 | 16篇 |
1956年 | 10篇 |
排序方式: 共有10000条查询结果,搜索用时 78 毫秒
31.
Hydrogels containing benzo-18-crown-6 were used to modify microcantilevers for measurements of the concentration of Pb2+ in aqueous solutions. These microcantilevers undergo bending deflection upon exposure to solutions containing various Pb2+ concentrations as the result of a swelling of the hydrogels. It was found that a concentration of 10(-6) M Pb2+ can be detected using this technology. Other cations, such as Na+, have no effect on the deflection of this cantilever. The cation K+, which also complexes with benzo-18-crown-6, could interfere with Pb2+ detection, but only at high concentrations (> 10(-4) M). 相似文献
32.
Won Keun Son Ji Ho Youk Taek Seung Lee Won Ho Park 《Journal of Polymer Science.Polymer Physics》2004,42(1):5-11
Electrospinning of cellulose acetate (CA) in a new solvent system and the deacetylation of the resulting ultrafine CA fibers were investigated. Ultrafine CA fibers (∼2.3 μm) were successfully prepared via electrospinning of CA in a mixed solvent of acetone/water at water contents of 10–15 wt %, and more ultrafine CA fibers (0.46 μm) were produced under basic pH conditions. Ultrafine cellulose fibers were regenerated from the homogeneous deacetylation of ultrafine CA fibers in KOH/ethanol. It was very rapid and completed within 20 min. The crystal structure, thermal properties, and morphology of ultrafine CA fibers were changed according to the degree of deacetylation, finally to those of pure cellulose, but the nonwoven fibrous mat structure was maintained. The activation energy for the deacetylation of ultrafine CA fibers was 10.3 kcal/mol. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 5–11, 2004 相似文献
33.
Chunxia Zhao Guowang Xu Xianzhe Shi Jianmei Ma Yan Zhang Shen Lv Qianfeng Weng Qing Yang 《Analytical sciences》2004,20(7):1001-1005
Fluorescent-based single-strand conformation polymorphism (F-SSCP) analysis with capillary electrophoresis (CE) is the most common method for the detection of mutation because of its high sensitivity and resolution. In this study, we prepared an inexpensive linear polyacrylamide (LPA), and successfully applied it to CE-SSCP analysis and tandem CE-SSCP/heteroduplex analysis (HA) of the P53 gene on an ABI capillary genetic analyzer. A comparison of the sieving capabilities of a homemade LPA and commercial polydimethylacrylamide (PDMA) demonstrates that the homemade LPA has a higher resolution, a shorter analysis time, and is more suitable for tandem SSCP/HA than commercial PDMA. To show the usefulness, mutations of P53 gene exon 7 - 8 in 37 tumor samples were investigated by using homemade LPA. The results indicate that 10 mutations were found in 9 of 37 cases; the majority of P53 mutations were missense mutations, and 70% were located in exon 7, which plays an important role in neoplastic progression in human tumorigenesis. 相似文献
34.
35.
报道了Pr(0.5):ZBLAN玻璃在双频双光束光源激发下的激发态上转换现象.发现上转换发射谱的荧光与常规荧光发射谱的荧光一致,还发现双频激发下的上转换激发谱有3个明显的谱峰,它们依此对应于788.5nm 1G4→3P2,850.5nm 1G4→1I6和805.0nm 3H6→1D2的激发态吸收跃迁,而大的850.5nm上转换激发谱峰是由大的1G4(Pr3+ )→1I6(Pr3+)跃迁的振子强度f=23.04×10-6所致.这说明起源于1G4能级的激发态吸收上转换尤其1G4(Pr3+)→1I6(Pr3+) 相似文献
36.
37.
Qing An WU Zhen Yuan XU Mei ZHENG Dan Qian XU Jun XU Yin Chu SHENCollege of Chemical Engineering Materials Zhejiang University of Technology Hangzhou 《中国化学快报》2004,(7)
Six new 13-O-acylavermectin Bl aglycones(3-8) were synthesized from avermectin B1 aglycone and their bioactivities were evaluated against Spodoptera exigua, Spodoptera eridania, Tetranychus urticae and Aphis fabae. 相似文献
38.
XiangBaoMENG HuiLI QingLI ZhongJunLI 《中国化学快报》2004,15(7):777-778
An unusual reductive ring-opening reaction of phthalimide with sodium hydride in anhydrous DMF was observed for the first time. The presumed mechanism was described in detail. 相似文献
39.
40.
Impact of the internucleotide linkage modification by inserting a methylene group to the P-O bond (—O—PO
2
—
—O— chain changed for —O—PO
2
—
—CH2—O—), on the modified oligonucleotide binding ability to the natural DNA strand was studied by molecular dynamics simulation. Complex of (dT)11 with a deoxyadenosine undecamer containing alternating modified and natural internucleotide linkage was studied as a model system. The Amber force field was completed by a set of new parameters needed to model the modified part of the nucleotide. The simulations confirmed existence of a double-helical complex the melting point of which is considerably higher than 300 K. While the thymidine (unmodified) strand possesses a B-type secondary structure, the conformation of the adenosine (modified) strand is not stable at 300 K. The -ggt conformation of the modified linkages is highly preferred, temporary jumps to the -g-gt and ggt conformations were, however, observed. 相似文献