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961.
Chen Dong Zhenkang Lin Yuxin Yin Yaoxuan Qiao Wei Wang Qibing Wu Chengxiang Yang David Rooney Cheng Fan Kening Sun 《Journal of Energy Chemistry》2021,(4):1-9
A uniform diffusion layer is essential for non-dendritic deposition of lithium in high-density lithium batteries.However,natural pristine solid electrolyte interface(SEI)is always porous and inhomogeneous because of repeated breakdown and repair cycles,whereas ideal materials with excellent mechanical property for artificial SEIs remain a challenge.Herein,a robust and stable interface is achieved by spinning soft polymer associated with few MoO3 into fibers,and thus mechanical property of fibers other than materials determines mechanical performance of the interface which can be optimized by adjusting parameters.Furthermore,lithium deposited underneath the layer is enabled by constructing an optimal resistance to make the membrane serve as an artificial SEI rather than lithium host.As a result,dendritefree lithium was observed underneath the membrane,and stable interface for long-term cycling was also indicated by EIS measurements.The lithium iron phosphate(LiFePO4)full-cell with coated electrode demonstrated an initial capacity of 155.2 m Ah g-1,and 80%of its original capacity was retained after 500 cycles at 2.0℃ without any additive in carbonate-based electrolyte. 相似文献
962.
In several previous studies, it was reported that a supported pipe with small geometric imperfections would lose stability when the internal flow velocity became sufficiently high. Recently, however, it has become clear that this conclusion may be at best incomplete. A reevaluation of the problem is undertaken here by essentially considering the flow-induced static deformation of a pipe. With the aid of the absolute nodal coordinate formulation(ANCF) and the extended Lagrange equations for dynam... 相似文献
963.
964.
Mass spectrometry imaging is a novel molecular imaging technique that has been developing rapidly in recent years. Air flow-assisted ionization mass spectrometry imaging (AFAI-MSI) has received wide attention in the biomedical field because of its features such as not needing a pretreatment sample, having high sensitivity, and wide coverage of metabolite detection. In this study, we set up a mass spectrometry imaging method for analyzing low molecular metabolites in mango fruits by the AFAI-MSI method. Compounds such as organic acids, vitamin C, and phenols were detected from mango tissue by mass spectrometry under the negative ion scanning mode, and their spatial distribution was analyzed. As a result, all the target compounds showed different distributions. Citric acid was mainly distributed in the pulp. Malic acid, quinic acid, and vitamin C universally existed in the pulp and peel. However, galloylglucose isomer and 5-galloylquinic acid were predominantly found in the peel. These results show that AFAI-MSI can be used for the analysis of mango fruit endogenous metabolites conveniently and directly, which will facilitate the rapid identification and in situ characterization of plant endogenous substances. 相似文献
965.
A theoretical model is developed for the vibration and stability of a vertical pipe subjected concurrently to two dependent axial flows. The external fluid, after exiting the outer annular region between the pipe and a rigid cylindrical channel, is conveyed upwards inside the pipe. This configuration thus resembles of a pipe that aspirating fluid. The equation of planar mo- tion is solved by means of the differential quadrature method (DQM). Calculations are conducted for a slender drill-string-like and a bench-top-size system, for different confinement conditions of the outer annular channel. It is shown that the vibrations of these two systems are closely related to the degree of confinement of the outer annular channel. For a drill-string-like system with narrow annuli, buckling instability may occur in the second and third modes. For a bench-top-size system, however, both buckling and flutter may occur in the lowest three modes. The form of instability depends on the annuli size. 相似文献
966.
967.
Miaomiao Ye Qiao Zhang Yongxing Hu Jianping Ge Dr. Zhenda Lu Le He Zhonglin Chen Prof. Yadong Yin Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(21):6243-6250
Core–shell structured Fe3O4/SiO2/TiO2 nanocomposites with enhanced photocatalytic activity that are capable of fast magnetic separation have been successfully synthesized by combining two steps of a sol–gel process with calcination. The as‐obtained core–shell structure is composed of a central magnetite core with a strong response to external fields, an interlayer of SiO2, and an outer layer of TiO2 nanocrystals with a tunable average size. The convenient control over the size and crystallinity of the TiO2 nanocatalysts makes it possible to achieve higher photocatalytic efficiency than that of commercial photocatalyst Degussa P25. The photocatalytic activity increases as the thickness of the TiO2 nanocrystal shell decreases. The presence of SiO2 interlayer helps to enhance the photocatalytic efficiency of the TiO2 nanocrystal shell as well as the chemical and thermal stability of Fe3O4 core. In addition, the TiO2 nanocrystals strongly adhere to the magnetic supports through covalent bonds. We demonstrate that this photocatalyst can be easily recycled by applying an external magnetic field while maintaining their photocatalytic activity during at least eighteen cycles of use. 相似文献
968.
Zhigang Xu Pengfei Li Weihong Qiao Zongshi Li Lubo Cheng 《Colloids and surfaces. A, Physicochemical and engineering aspects》2006,290(1-3):172-177
A novel kind of fluorescent surfactant having 7-hydroxylcoumarin group in the long alkyl chain was synthesized. The critical micelle concentration (CMC), surface tension (γcmc) at CMC and absorption, fluorescence properties of this product were determined. From the variations of fluorescence spectra in different solvents, it is observed that the polarity and dielectric constant of the solvents play important roles in the maximum fluorescence intensity and wavelength. Moreover, the surprised exhibition of two fluorescence bands in neutral and alkaline solutions has been attributed to the superexciplex formation of the product molecules. Also, the lower product concentration measuring the fluorescence properties as well as the supposed configuration of hydrogen bond of the product indicate that the larger aggregations cannot exist in alkaline solutions. The superexciplex is a possibility with two or more polar excited molecules together to form an excited state association. 相似文献
969.
Hô N Phillips MC Qiao H Allen PJ Krishnaswami K Riley BJ Myers TL Anheier NC 《Optics letters》2006,31(12):1860-1862
We demonstrate the design, fabrication, and characterization of single-mode low-loss waveguides for mid-infrared (MIR) wavelengths. Planar waveguide structures were fabricated from multilayer thin films of arsenic-based chalcogenide glasses followed by the creation of channel waveguides by using the photodarkening effect. Propagation losses as low as 0.5 dB/cm were measured for a quantum cascade laser end-fire coupled into the waveguides. This is a first step toward the design and fabrication of integrated optical components for MIR applications. 相似文献
970.
Mai Lu Zhide Hu Zheng Yang Fulin Wei 《International Journal of Infrared and Millimeter Waves》2000,21(6):965-977
In this paper, the electric field lines of the dominant mode in a closed V-groove guide as well as an open one are analysed by finite element method. The results show that the electric field lines are not parallel to the parallel plate region, but perpendicular to them. Since the attenuation increase with increasing frequency when the electric field lines are perpendicular to the mental walls, the V-groove is not suitable to be used in millimeter and submillimeter wavebands, and it is can't be regarded as low-loss wave guiding structures. 相似文献