全文获取类型
收费全文 | 88204篇 |
免费 | 1861篇 |
国内免费 | 1668篇 |
专业分类
化学 | 31597篇 |
晶体学 | 902篇 |
力学 | 7350篇 |
综合类 | 69篇 |
数学 | 33111篇 |
物理学 | 18704篇 |
出版年
2024年 | 62篇 |
2023年 | 281篇 |
2022年 | 451篇 |
2021年 | 458篇 |
2020年 | 470篇 |
2019年 | 498篇 |
2018年 | 10752篇 |
2017年 | 10552篇 |
2016年 | 6536篇 |
2015年 | 1368篇 |
2014年 | 891篇 |
2013年 | 1121篇 |
2012年 | 4649篇 |
2011年 | 11376篇 |
2010年 | 6234篇 |
2009年 | 6584篇 |
2008年 | 7261篇 |
2007年 | 9288篇 |
2006年 | 749篇 |
2005年 | 1690篇 |
2004年 | 1867篇 |
2003年 | 2227篇 |
2002年 | 1304篇 |
2001年 | 451篇 |
2000年 | 487篇 |
1999年 | 406篇 |
1998年 | 369篇 |
1997年 | 274篇 |
1996年 | 335篇 |
1995年 | 247篇 |
1994年 | 173篇 |
1993年 | 200篇 |
1992年 | 140篇 |
1991年 | 149篇 |
1990年 | 126篇 |
1989年 | 116篇 |
1988年 | 100篇 |
1987年 | 93篇 |
1986年 | 79篇 |
1985年 | 77篇 |
1984年 | 62篇 |
1983年 | 50篇 |
1982年 | 53篇 |
1981年 | 44篇 |
1980年 | 50篇 |
1979年 | 47篇 |
1914年 | 45篇 |
1912年 | 40篇 |
1909年 | 41篇 |
1908年 | 40篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
131.
Cai Mengmeng Yao Lijuan Zhu Man Tao Peng Nan Ruihua Jian Zengyun 《Journal of Thermal Analysis and Calorimetry》2021,143(4):2911-2918
Journal of Thermal Analysis and Calorimetry - Differential scanning calorimetry was used to investigate the non-isothermal crystallization kinetics of the Fe76.5Nb3B20Cu0.5 glassy alloys. The... 相似文献
132.
Hong-Jian Ji Jia-Yuan Li Shi-Fei Wu Wen-Yong Wu Chang-Liang Yao Shuai Yao Jian-Qing Zhang De-An Guo 《Molecules (Basel, Switzerland)》2021,26(1)
Twelve compounds, including two new aristolochic acid analogues with a formyloxy moiety (9–10) and 10 known aristolochic acid derivates (1–8 and 11–12), were obtained from the roots of Aristolochia contorta. Their structures were elucidated using extensive spectroscopic methods. Their cytotoxic activity in human proximal tubular cells HK-2 was evaluated by the MTT method, which has been widely used to assess cell viability. Among these molecules, compounds 3 and 9 were found to be more cytotoxic. Furthermore, molecular modeling was used to evaluate, for the first time, the interactions of compounds 3 and 9 with the target protein organic anionic transporter 1 (OAT1) that plays a key role in mediating aristolochic acid nephropathy. Structure–activity relationships are briefly discussed. 相似文献
133.
We review the notion of weighted quantum entropy and consider the weighted quantum entropy for bipartite and noncomposite quantum systems. We extend the subadditivity condition, the inequality known for the weighted entropy information, to the case of indivisible qudit system, such as a qutrit. We discuss the new inequality for the qutrit density matrix for different weights and states, as well as the role of weighted entropy with respect to nonlinear quantum channels. 相似文献
134.
With diffusion tensor imaging (DTI), more exquisite information on tissue microstructure is provided for medical image processing. In this paper, we present a locally adaptive topology preserving method for DTI registration on Lie groups. The method aims to obtain more plausible diffeomorphisms for spatial transformations via accurate approximation for the local tangent space on the Lie group manifold. In order to capture an exact geometric structure of the Lie group, the local linear approximation is efficiently optimized by using the adaptive selection of the local neighborhood sizes on the given set of data points. Furthermore, numerical comparative experiments are conducted on both synthetic data and real DTI data to demonstrate that the proposed method yields a higher degree of topology preservation on a dense deformation tensor field while improving the registration accuracy. 相似文献
135.
136.
Sparse representation (SR) and nonlocal technique (NLT) have shown great potential in low-level image processing. However, due to the degradation of the observed image, SR and NLT may not be accurate enough to obtain a faithful restoration results when they are used independently. To improve the performance, in this paper, a nonlocal supervised coding strategy-based NLT for image restoration is proposed. The novel method has three main contributions. First, to exploit the useful nonlocal patches, a nonnegative sparse representation is introduced, whose coefficients can be utilized as the supervised weights among patches. Second, a novel objective function is proposed, which integrated the supervised weights learning and the nonlocal sparse coding to guarantee a more promising solution. Finally, to make the minimization tractable and convergence, a numerical scheme based on iterative shrinkage thresholding is developed to solve the above underdetermined inverse problem. The extensive experiments validate the effectiveness of the proposed method. 相似文献
137.
Tatsuya Mori ATLAS Liquid Argon Calorimeter Group 《Physics of Particles and Nuclei Letters》2016,13(5):541-546
This article gives an overview of the Phase-I Upgrade of the ATLAS LAr Calorimeter Trigger Readout. The design of custom developed hardware for fast real-time data processing and transfer are presented. Performance results from the prototype boards operated in the demonstrator system, first measurements of noise behavior and responses on the test pulses to the demonstrator system are shown. 相似文献
138.
Numerous compounds containing urea bridge and biurea moieties are used in a variety of fields, especially as drugs and pesticides. To search for novel, environmentally benign and ecologically safe pesticides with unique modes of action, four series of novel triazone analogues containing urea, thiourea, biurea, and thiobiurea bridge, respectively, were designed and synthesized, according to various calcium ion channel inhibitors which act on transient receptor potential protein. Their structures were characterized by \({}^{1}\mathrm{H}\) NMR, \({}^{13}\mathrm{C}\) NMR, and HRMS. The insecticidal activities of the new compounds were obtained. The bioassay results indicated that compounds containing a thiourea bridge and a thiobiurea bridge exhibited excellent insecticidal activities against bean aphid. Specifically, compounds \({\mathbf{VIb}}_{15}\), \({\mathbf{VIIb}}_{8}\), and \({\mathbf{VIIb}}_{9}\) exhibited 85, 90, and 95 % activities, respectively, at 10 mg/kg. Compounds \({\mathbf{VIb}}_{14}\) (30 %), \({\mathbf{VIIb}}_{10}\) (35 %), \({\mathbf{VIIb}}_{11}\) (30 %), and \({\mathbf{VIIb}}_{12}\) (40 %) exhibited the approximate aphicidal activity of pymetrozine (30 %) at 5 mg/kg. In addition, some target compounds exhibited insecticidal activities against lepidopteran pests. From a molecular design standpoint, the information obtained in this study could help in the further design of new derivatives with improved insecticidal activities. 相似文献
139.
We study the mode solution to the Cauchy problem of the scalar wave equation □φ = 0 in Kasner spacetimes. As a first result, we give the explicit mode solution in axisymmetric Kasner spacetimes, of which flat Kasner spacetimes are special cases. Furthermore, we give the small and large time asymptotics of the modes in general Kasner spacetimes. Generically, the modes in non-flat Kasner spacetimes grow logarithmically for small times, while the modes in flat Kasner spacetimes stay bounded for small times. For large times, however, the modes in general Kasner spacetimes oscillate with a polynomially decreasing amplitude. This gives a notion of large time frequency of the modes, which we use to model the wavelength of light rays in Kasner spacetimes. We show that the redshift one obtains in this way actually coincides with the usual cosmological redshift. 相似文献
140.
Selenium nanoparticles (SeNPs) are considered to be the new selenium supplement forms with high biological activity and low toxicity; however, the molecular mechanism by which SeNPs exert the biological function is unclear. Here, we reported that biocompatibility SeNPs possessed intrinsic oxidase-like activity. Using Na2SeO3 as a precursor and glutathione as a reductant, biocompatibility SeNPs were synthesized by the wet chemical reduction method in the presence of bovine serum albumin (BSA). The results of structure characterization revealed that synthesized SeNPs were amorphous red elementary selenium with spherical morphology, and ranged in size from 25 to 70 nm size with a narrow distribution (41.4 ± 6.7 nm). The oxidase-like activity of the as-synthesized SeNPs was tested with 3,3′,5,5′-tetramethylbenzidine (TMB) as a substrate. The results indicated that SeNPs could catalyze the oxidization of TMB by dissolved oxygen. These SeNPs showed an optimum catalytic activity at pH 4 and 30 °C, and the oxidase-like activity was higher as the concentration of SeNPs increased and the size of SeNPs decreased. The Michaelis constant (K m) values and maximal reaction velocity (V max) of the SeNPs for TMB oxidation were 0.0083 mol/L and 3.042 μmol/L min, respectively. 相似文献