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Yinhong Niu Jiale Liao Haitao Zhou Chih-chen Wang Lei Wang Yanli Fan 《Molecules (Basel, Switzerland)》2022,27(15)
Lycium barbarum leaves are a kind of vegetable, and modern nutrition studies have found that they have an anti-aging function. Our study aims to investigate the anti-aging effects of Lycium barbarum leaf flavonoid (LBLF) extracts and its underlying molecular mechanism. LBLFs were purified using D101 and polyamide resin, characterized by ultraperformance liquid chromatography coupled with mass spectrometry, and administered to hydrogen peroxide (H2O2)-treated human umbilical vein endothelial cells (HUVECs) and Caenorhabditis elegans. Appropriate enrichment conditions were optimized through dynamic adsorption and desorption experiments, the content of flavonoids reached 909.84 mg/g, rutin and kaempferol being the main ones. LBLFs attenuated H2O2-induced HUVEC apoptosis, decreased reactive oxygen species and malondialdehyde production levels, increased superoxide dismutase, glutathione peroxidase and catalase activities. Furthermore, pre-treatment with LBLF increased mRNA expression of erythropoietin (EPO) and heme oxygenase-1 (HO-1) via the mitogen-activated protein kinase (MAPK) signaling pathway in HUVECs. Compared with 100 µM rutin monomer, LBLF prolonged the lifespan of Caenorhabditis elegans, enhanced their mobility in middle life stages and upregulated expression of sod-2, gcs-1 and skn-1 genes, which indicated that the anti-aging effects of LBLF were due to its redox-modulation. 相似文献
44.
为了提高激光直写加工衍射光学元件时的线条质量,提出一种离焦激光直写的线宽稳定方法.该方法通过同时调节激光功率和离焦量,使光刻胶的曝光阈值处于线宽对曝光量的变化率较小位置,从而可以弱化线宽对实际曝光量或光刻胶阈值等变化的敏感度,提高利用离焦方法进行衍射光学元件制作时的线宽稳定性.推导了稳定线宽后的光功率控制模型和线宽模型,模型中的变量仅为离焦量,降低了光功率控制的复杂性.利用632.8 nm的He-Ne激光和NA-0.1的物镜在CCD上对采用该方法后的离焦线宽模型进行验证,实验结果与理论模型吻合较好.该方法对于线宽稳定度较高的衍射光学元件制作具有重要价值. 相似文献
45.
In this paper, two compounds [Zn_2~(2+)(2,6-bis(4'-pyridyl)-TTF)(TPA)_2~(2-)](1) and [Cd~(2+)(2,6(7)-bis(4'-pyridyl)-TTF)(TPA)~(2-)(H_2O)_2](TTF = tetrathiafulvalene, TPA = terephthalic acid)(2) were synthesized by using solvothermal method and characterized by single-crystal X-ray. The purity of the two compounds was confirmed by their PXRD data. We also tested the photocurrent responses of these two compounds, and found they could generate photocurrent signal when exposed to light, but the photocurrent intensity of compound 2 is significantly greater than that of 1. From the crystal structure analysis, the possible reason for this phenomenon is that 2 has a more compact ligand arrangement than 1, leading to a higher carrier density and easier excitation. 相似文献
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Partial discharge (PD) is the main feature that effectively reflects the internal insulation defects of gas-insulated switchgear (GIS). It is of great significance to diagnose the types of insulation faults by recognizing PD to ensure the normal operation of GIS. However, the traditional diagnosis method based on single feature information analysis has a low recognition accuracy of PD, and there are great differences in the diagnosis effect of various insulation defects. To make the most of the rich insulation state information contained in PD, we propose a novel multi-information ensemble learning for PD pattern recognition. First, the ultra-high frequency and ultrasonic data of PD under four typical defects of GIS are obtained through experiment. Then the deep residual convolution neural network is used to automatically extract discriminative features. Finally, multi-information ensemble learning is used to classify PD types at the decision level, which can complement the shortcomings of the independent recognition of the two types of feature information and has higher accuracy and reliability. Experiments show that the accuracy of the proposed method can reach 97.500%, which greatly improves the diagnosis accuracy of various insulation defects. 相似文献
48.
Facile construction of functional nanomaterials with laccase-like activity is important in sustainable chemistry since laccase is featured as an efficient and promising catalyst especially for phenolic degradation but still has the challenges of high cost, low activity, poor stability and unsatisfied recyclability. In this paper, we report a simple method to synthesize nanozymes with enhanced laccase-like activity by the self-assembly of copper ions with various imidazole derivatives. In the case of 1-methylimidazole as the ligand, the as-synthesized nanozyme (denoted as Cu-MIM) has the highest yield and best activity among the nanozymes prepared. Compared to laccase, the Km of Cu-MIM nanozyme to phenol is much lower, and the vmax is 6.8 times higher. In addition, Cu-MIM maintains excellent stability in a variety of harsh environments, such as high pH, high temperature, high salt concentration, organic solvents and long-term storage. Based on the Cu-MIM nanozyme, we established a method for quantitatively detecting phenol concentration through a smartphone, which is believed to have important applications in environmental protection, pollutant detection and other fields. 相似文献
49.
Xingxiu Yan Shengchun Wang Zhao Liu Yujie Luo Pengjie Wang Wenyan Shi Xiaotian Qi Zhiliang Huang Aiwen Lei 《中国科学:化学(英文版)》2022,65(4):762-770
Reported here is a precise electro-reduction strategy for radical defluorinative alkylation towards the synthesis of gem-difluoroalkenes from α-trifluoromethylstyrenes. According to the redox-potential difference of the radical precursors, direct or indirect electrolysis is respectively adopted to realize the precise reduction. An easy-to-handle, catalyst-and metal-free condition is developed for the reduction of alkyl radical precursors that are generally easier to be reduced than α-trifluorome... 相似文献
50.
刘磊 《中国光学与应用光学文摘》2011,(6)
为了满足高精度相机在外场环境下的检测要求,采用碳化硅光学材料制作反射镜,碳纤/环氧树脂基复合材料制作遮光筒,设计了一套重量轻、自身精度高、温度稳定性好的离轴平行光管。在二者线胀系数保持二倍关系的情况下,在一定温变范围内保持精度的稳定性。经检测,口径为400 mm,焦距为8 m的离轴平行光管的温变为(20±10)℃,系统波像差为1/5λ(P-V值,λ=632.8 nm)和1/27λ(RMS值),达到了设计要求,能够在外场环境下使用。 相似文献