掺杂对碳纳米管拉曼光谱及场发射性能的影响

采用高温热解法在860℃分别制备出了镓、氮以及硼和氮掺杂的碳纳米管,提纯后利用丝网印刷工艺分别将它们制备成薄膜,并测试了它们的拉曼光谱与场发射性能。测试结果表明,掺杂纳米管的缺陷密集度比纯碳纳米管明显增大,而它们的场致电子发射性能则与掺杂元素的性质密切相关。镓和氮掺杂的纳米管均具有非常优异的场发射性能,而硼和氮共掺杂的纳米管的场发射性能很差。掺杂引起碳纳米管费米能级附近能态密度的变化及功函数的降低是其具有优异场致电子发射性能的主要原因。     

溶胀后的弹性印章进行毛细微模塑

用溶胀后的聚二甲基硅氧烷弹性印章进行毛细微模塑,得到了聚苯乙烯丙酮溶液的微四方点阵图案．较少的PS溶液滴加量会造成孤立不相连的微点阵图形．同时还获得了由于在收缩过程中各部分溶剂挥发速度不一造成的特殊的微点阵图案．     

A generalization of biorthogonal systems based on Drazin inverse

In this paper, the transformations of generating systems of Euclidean space are examined in connection with the Drazin inverse of their Gram matrices and the notion of biorthogonal systems is generalized. The results obtained in this paper can be considered as the extension of some recent results concerning Moore-Penrose biorthogonal systems and reflexiveg-inverse systems in Euclidean spaces.     

不同波长激发下YLiF_4∶Er~(3+),Tm~(3+),Yb~(3+)的发光

水热法合成了YL iF4∶Er3 ,Tm3 ,Yb3 ,其中Er3 、Yb3 和Tm3 的摩尔分数分别为1%、1.5%和2%。当用355 nm光激发时,其发光为蓝色,峰值位于450 nm,对应于Tm3 的1D2→3F4跃迁。用378 nm激发时,发光为绿色,主要发光峰位于552 nm。980 nm光激发时,发光为白色,发光峰分别位于665(651),552(543),484,450 nm处,并在648 nm处还观察到了一个发光峰,其中最强的发射为红光。YL iF4∶Er3 ,Tm3 ,Yb3 的蓝光来源于Tm3 的激发态1G4到基态3H6的跃迁,绿光来源于Er3 的4S3/2和2H11/2到基态4I15/2的跃迁,红光既来源于Tm3 的1G4→3F4的跃迁,也来源于Er3 的4F9/2→4I15/2的跃迁。在上转换发光中,还探测到了紫外光359 nm的发射。监测665 nm得到的激发光谱不同于监测552 nm的激发光谱,在665 nm的激发光谱中出现了对应Tm3 的1G4能级的峰。在双对数曲线中,蓝光484 nm、绿光552 nm和红光665 nm的斜率分别为2.25、2.28和2.21,紫外光359 nm的斜率为2.85。因此在980 nm激发下,蓝光484 nm、绿光552 nm和红光665 nm都是双光子过程,紫外光359 nm的发射是三光子过程。     

The Compactness of Commutators on the Heisenberg Group

We consider the commutators of the HSrmander multiplier with CMO-functions on the Heisenberg group. The result of compactness on L^P spaces is proved.     

椭圆波导FEM放大器的非线性特性研究

 以椭圆波导、平板摇摆器为FEM放大器的模型，导出了自洽的注波互作用三维非线性方程组。在此基础上编制了相应的程序。利用该程序分析了FEM放大器的饱和功率、效率以及带宽等高频特性。考虑了摇摆器渐变、空间电荷波、电子初始速度零散对高频特性的影响。     

Ab Initio Study on the Isomerization and Dehydrogenation of Methylnitrene

The ab initio calculations were performed at the RHF/4-31G level with the reaction pathways of the iso-merization and dehydrogenation of methylnitrene by the intrinsic reaction coordinate method. The results show that the transformation from methylnitrene to methylenimine would be very easy. This accountes for the experimental fact that one couldn' t find the methylnitrene, but only obtained the methylenimine in the pyrolysis of methyl azide. The mode-selective study reveals the reaction coordinates (IRC) of isomerization and dehydrogenation of methylnitrene are associated with the molecular deformation mode of 1191 cm-1 and the methyl group unsymmetrical stretch mode, respectively. The coupling between normal coordinates is favourable to select the reaction channel of isomerization.     

An inverse radiative transfer problem of simultaneously estimating profiles of temperature and radiative parameters from boundary intensity and temperature measurements

A parallel-plane space filled with absorbing, emitting, isotropically scattering, gray medium is studied in this paper. The boundary intensity and boundary temperature profiles are calculated for the inverse analysis. For the simultaneous estimation of temperature, absorption and scattering coefficient profiles in the medium, the sum of residuals of boundary intensity and temperature after being weighted by a balance factor is minimized through using a Newton-type iteration algorithm and the least-squares method. To avoid over-updating for the parameters, the relative updating magnitude during the iteration process is constrained not to be >0.5. It is shown that the boundary intensity measurement alone is not enough to estimate simultaneously the temperature (source) and the radiative properties (both absorption and scattering coefficients) when the measurement data contain sensitive random errors. The boundary temperature measurement can serve as a necessary supplementation to the boundary intensity to make this kind of inverse radiative transfer problem resolvable. It was shown that a compensation relationship between absorption and scattering coefficients makes it difficult to fix them accurately. Parabolic profiles for the three parameters are used to validate the estimation method. When the optical thickness approaches 4.0, the results for the radiative properties are not acceptable, although the result for temperature profile is reasonable. This means the method needs further improvements.     

用于快点火研究的超短脉冲的相干合成

 利用傅里叶光学方法，建立了一个基于远场的多束超短脉冲相干合成的理论模型。研究了一个口径为50 cm，脉宽为1 ps的超短脉冲相干合成系统的各种误差对脉冲远场时域和空域特性的影响。结果表明：若要求远场的一倍衍射极限区域的积分能量分布达到理想情况下的90％，该系统的相位延迟误差小于0.63，沿x方向角度误差小于0.37 μrad，沿y方向角度误差小于0.34 μrad；若要求远场叠加脉冲的时域展宽小于25％，系统的剩余啁啾因子应小于1.32(不考虑相位延迟)或1.52(考虑0.63的相位延迟)。     

一类Marangoni对流边界层方程的近似解析解

利用Adomain解析拆分和Padé逼近方法对由Marangoni对流诱发的层流边界层问题进行了研究, 提供了一种求解边界层方程的解析分析方法. 得到了问题的近似解析解并对相应的流动及传热特性进行了探讨. 本文所提出的思想方法可以用于解决其他科学和工程技术问题. 关键词： Marangoni对流 非线性 Adomain拆分法 近似解析解