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181.
57Fe Mössbauer effect study has been performed on intercalated compound 2H?Fe0.5TaSe2 over a temperature range between 14K and 500K. The highly concentrated intercalation samples 2H?FexTaSe2 with Fe atoms (x up to 2) are prepared by the electrochemical method for the first time. The Mössbauer measurement shows that iron is in Fe3+ high spin state and with the same probability occupies both octahedral and tetrahedral interstices of the Van der Waals gap. The fact that effective masses of iron ions in both sites are close to 57 amu and characteristic temperatures (ΘM =130K, 107K respectively) are found to be relatively small is attributed to the weak forces on Fe3+. 相似文献
182.
环境演算(MA)的模态逻辑AL进行了研究.在考虑了复制操作和限制操作的情况下,提出了逻辑等价的协归纳操作描述,并利用协归纳关系与进程结构同余关系进行比较,证明了若对MA加上约束条件得到子集MAIF^syn,此时逻辑等价(=L)与结构同余关系是等价的,即AL在MAIF^syn中是内涵的.同时发现由于复制操作的存在,AL的内涵性受到了影响,使得AL的区分能力被削弱,但通过对复制公式的构造验证了AL的表达能力. 相似文献
183.
架起传统与现代的桥梁--建筑历史与理论课程体系教学改革的思考 总被引:2,自引:0,他引:2
邱枫 《宁波大学学报(理工版)》2004,17(4):485-488
重新审视建筑历史理论教学的目标、内容、教学方式和手段,通过对国内几座有影响的建筑院校的调研,比较各个院校在这些问题及途径上的异同,分析其利弊,以期促进建筑历史与理论课程体系教学的建设和改革. 相似文献
184.
针对多元χ演算运行时刻通信安全的判定性问题进行了研究.通过从Lazyλ项到χ项的编码,将判定一个Lazyλ项是否有范式的问题归约为进程是否有通信错误的问题.证明了在多元χ演算中,通讯错误也是不可判定的.结论说明不存在算法直接来检测进程的通信安全性,而只有通过其他间接的手段(如构造类型系统)才能部分达到预防运行时错误的目的. 相似文献
185.
Y.-D Feng Y.-S. Wang Z.-M. Zhang 《Archive of Applied Mechanics (Ingenieur Archiv)》2003,73(5-6):337-347
Summary A 2D time-domain Boundary Element Method (BEM) is applied to solve the problem of transient scattering of plane waves by an inclusion with a unilateral smooth contact interface. The incident wave is assumed strong enough so that localized separations take place along the interface. The present problem is indeed a nonlinear boundary value problem since the mixed boundary conditions involve unknown intervals (separation and contact regions). In order to determine the unknown intervals, an iterative technique is developed. As an example, we consider the scattering of plane waves by the cross section of a circular cylinder embedded in an infinite solid. Numerical results for the near field solutions are presented. The distortion of the response waves and the variation of the interface states are discussed.
The financial support by the China National Natural Science Foundation under Grant No. 19872001 and No. 59878004 is gratefully acknowledged. The second author is also grateful to the support of the National Science Fund for Distinguished Young Scholars under Grant No. 10025211. 相似文献
186.
Yonggang Shangguan Li Zhao Liyang Tao Qiang Zheng 《Journal of Polymer Science.Polymer Physics》2007,45(13):1704-1712
The effects of preparation method, composition, and thermal condition on formation of β‐iPP in isotactic polypropylene/ethylene–propylene rubber (iPP/EPR) blends were studied using modulated differential scanning calorimeter (MDSC), wide angle X‐ray diffraction (WAXD), and phase contrast microscopy (PCM). It was found that the α‐iPP and β‐iPP can simultaneity form in the melt‐blended samples, whereas only α‐iPP exists in the solution‐blended samples. The results show that the formation of β‐iPP in the melt‐blended samples is related to the crystallization temperature and the β‐iPP generally diminishes and finally vanishes when the crystallization temperature moves far from 125 °C. The phenomena that the lower critical temperature of β‐iPP in iPP/EPR obviously increases to 114 °C and the upper critical temperature decreases to 134 °C indicate the narrowing of temperature interval, facilitating the formation of β‐iPP in iPP/EPR. Furthermore, it was found that the amount of β‐iPP in melt‐blended iPP/EPR samples is dependent on the composition and the maximum amount of β‐iPP formed when the composition of iPP/EPR blends is 85:15 in weight. The results through examining the effect of annealing for iPP/EPR samples at melt state indicate that this annealing may eliminate the susceptibility to β‐crystallization of iPP. However, only α‐iPP can be observed in solution‐blended samples subjected to annealing for different time. The PCM images demonstrate that an obvious phase‐separation happens in both melt‐blended and solution‐blended iPP/EPR samples, implying that compared with the disperse degree of EPR in iPP, the preparation method plays a dominant role in formation of β‐iPP. It is suggested that the origin of formation of β‐iPP results from the thermomechanical history of the EPR component in iPP/EPR. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1704–1712, 2007 相似文献
187.
1,6-烯炔底物在过渡金属催化剂作用下的化学行为得到了广泛的研究,重点是关于过渡金属催化的1,6-烯炔环异构化反应.从反应机理角度入手,把1,6-烯炔环异构化反应按启动方式总结为三类,并对这三种方式启动的1,6-烯炔环异构化反应进行了详细地总结和阐述. 相似文献
188.
189.
We report on Raman scattering of VO2 films prepared by radio frequency magnetron sputtering under different conditions. Our investigations revealed that the dominated Raman peaks shift towards high frequency for both V-rich and O-rich VO2 films, compared with the stoichiometry VO2 films. The experimental evidence is presented and the cause for nonstoichiometry dependence of Raman spectra of VO2 films is discussed. 相似文献
190.
Triterpenoid Constituents of Huperzia miyoshiana 总被引:1,自引:0,他引:1
Thirteen triterpenoids, including three new ones, miyoshianois A (1), B (2) and C (3), were isolated from Huperzia miyoshiana. The structures of these new compounds were established as 3-O-dihydroferuloyltohogenol (1), 16-oxo-3β,21β-dihydrox-y-serrat-14-en-24-ferulate (2) and 16-oxo-3a, 21β-dihydroxy-serrat-14-en-24-ferulate (3), respectively, on the basis of their spectroscopic analysis. 相似文献