国产复合功能光纤实现万瓦激光输出

正作为长距离分布式侧面泵浦技术的典型代表,泵浦增益一体化复合功能激光光纤(Pump-gain integrated Functional Laser Fiber,PIFL-fiber)是包含单根增益光纤与多根泵浦光纤的多功能集成器件。基于倏逝波耦合效应巧妙地解决了超大泵浦功率注入的技术难题,已成为高功率光纤激光放大技术的主流技术方案之一。2018年2月,中国工程物理研究院激光聚变研究中心科研人员成功制备(8+1)型PIFL复合功能激光光     

Preparation and Luminescence Properties of the Ternary Europium Complex Incorporated into an Inorganic/Polymer Matrix by a Sol-Gel Method

Ternary europium complexes with thenoyltrifluoroacetone (TTA) and phenanthroline (phen) were incorporated into SiO₂/polymer matrix by a sol-gel method. The gels exhibit the characteristic emission bands of europium ion. In addition, Eu³⁺ presents a longer fluorescence lifetime in gel than in the corresponding pure complex powder. Concentration effects on the luminescence intensity were investigated. The reasons that are responsible for above results are also discussed in the context.     

Synthesis, crystal structures and magnetic properties of cyanide-bridged macrocyclic complexes

Three cyanide-bridged dodecanuclear macrocyclic wheel-like complexes [Cr(bpmb)(CN)₂]₆[Mn(5-Brsalpn)]₆·12H₂O (1), [Co(bpmb)(CN)₂]₆[Mn(5-Brsalpn)]₆·12H₂O (2) and [Co(bpmb)(CN)₂]₆[Mn(5-Clsalpn)]₆·24H₂O·8CH₃CN (3) [bpmb²⁻= 1,2-bis(pyridine-2-carboxamido)-4-methylbenzenate dianion; 5-Brsalpn²⁻ = N,N′-propylenebis(5-bromosalicylideneaminato) dianion; 5-Clsalpn²⁻ = N,N′-propylenebis(5-chlorosalicylideneaminato) dianion] have been synthesized and their crystal structures and magnetic properties have been investigated. The three compounds are structurally isomorphous and consist of alternating Mn(III)-Schiff base cations and [M(bpmb)(CN)₂]⁻ anions, generating cyanide-bridged nanosized dodecanuclear macrocyclic structures with an approximate diameter of 2 nm. The study of the magnetic properties of complex 1 reveals an antiferromagnetic interaction between the Cr(III) and Mn(III) ions through the cyanide bridges. A best-fit to the magnetic susceptibility of the complex leads to a magnetic coupling constant of J _CrMn = −2.65(6) cm⁻¹ on the basis of a one-dimensional alternating chain model with the Hamiltonian $ H = - J_{CrMn} \sum\limits_{i = 0}^N {S_i \cdot S_{i + 1} } $ H = - J_{CrMn} \sum\limits_{i = 0}^N {S_i \cdot S_{i + 1} } .     

Preparation of poly(vinylphenylboronic acid) chain grafted poly(glycidylmethacrylate‐co‐ethylenedimethacrylate) beads for the selective enrichment of glycoprotein

Surface‐initiated atom transfer radical polymerization was successfully used to prepare 4‐vinylphenylboronic acid functionalized poly(glycidylmethacrylate‐co‐ethylenedimethacrylate) beads for the selective enrichment of glycoprotein from complex biological samples in this study. The modified bead surfaces were characterized using Fourier transform infrared spectroscopy and X‐ray photoelectron spectroscopy. The sorption behaviors, including adsorption isotherms, incubation time, and pH effect, were investigated. The results demonstrated that the boronated beads have a high affinity for glycoprotein, which is due to the well‐defined boronic acid brushes on the beads surfaces. Furthermore, the polyvinylphenylboronic acid grafted poly(glycidylmethacrylate‐co‐ethylenedimethacrylate) beads were used to efficiently enrich and purify glycoprotein from real egg white samples and α‐fetoprotein from human serum samples. The mass spectrometry results demonstrated that the polyvinylphenylboronic acid grafted poly(glycidylmethacrylate‐co‐ethylenedimethacrylate) beads are a suitable material for the enrichment of glycosylated protein from complex biological samples.     

Mild and efficient CO-mediated eliminative deoxygenation of epoxides catalyzed by supported gold nanoparticles

Supported gold nanoparticles (NPs), which are well-known epoxidation catalysts, were found to be exceptionally active for the selective deoxygenation of epoxides into alkenes using cheap and easily accessible CO and H(2)O as the reductant.     

Experimental and simulation investigation of ion transfer in different sampling capillaries

Atmospheric pressure interfaces were a fundamental structure for transferring air generated ions into the vacuum manifold of a mass spectrometer. This work is devoted to the characterization of ion transfer in metal capillaries through both experimental and simulated investigations. The impact of capillary configurations on ion transmission efficiency was evaluated using an electrospray mass spectrometer with various bent capillaries as the transfer devices. In addition, a numerical model has been set up by coupling the SIMION 8.0 and the computational flow dynamics for simulation study of ion migration in the complex atmospheric system. The transfer efficiency was found to be highly affected by the variation in electric field and the capillary geometry, revealing that the hydrodynamic and electric force were both dominant and interactional during the transmission process. The consistency of the results from the experimental analysis and simulation modeling proved the validity of the model, which was helpful for understanding ion activity in transfer capillaries. Copyright © 2015 John Wiley & Sons, Ltd.     

用于弹道测量的实时测速同步触发仪设计

介绍了一种实时获取当发弹丸速度的同步触发系统.采用两台天幕靶和测时电路实时测量当发弹丸的速度,根据测得的速度和事先确定的靶距,计算输出测试仪器触发需要的延时值.同时,设计了滤除蚊虫、飞鸟等外界环境干扰的电路,确保输出的触发信号稳定可靠.详细介绍了系统组成、工作原理与逻辑电路的设计.设计的系统经过实弹射击试验验证,工作稳...     

A Lattice‐Oxygen‐Involved Reaction Pathway to Boost Urea Oxidation

The electrocatalytic urea oxidation reaction (UOR) provides more economic electrons than water oxidation for various renewable energy‐related systems owing to its lower thermodynamic barriers. However, it is limited by sluggish reaction kinetics, especially by CO₂ desorption steps, masking its energetic advantage compared with water oxidation. Now, a lattice‐oxygen‐involved UOR mechanism on Ni⁴⁺ active sites is reported that has significantly faster reaction kinetics than the conventional UOR mechanisms. Combined DFT, ¹⁸O isotope‐labeling mass spectrometry, and in situ IR spectroscopy show that lattice oxygen is directly involved in transforming *CO to CO₂ and accelerating the UOR rate. The resultant Ni⁴⁺ catalyst on a glassy carbon electrode exhibits a high current density (264 mA cm^?2 at 1.6 V versus RHE), outperforming the state‐of‐the‐art catalysts, and the turnover frequency of Ni⁴⁺ active sites towards UOR is 5 times higher than that of Ni³⁺ active sites.     

反丁烯二酸稀土配合物的合成及晶体结构

合成了反丁烯二酸C_4H_4O_4与六种稀土(Eu, Gd, Tb, Y, Er, Lu)的配合物M_2F_3·12H_2O(H_2F=C_4H_4O_4). 用X射线衍射法测定了它们的晶体学参数, 并测定了其中五种配合物的结构. 指出存在两类不同的结构, 其中铕配合物为三斜晶系, 空间群P(1), 铕离子配位数为10. 铽、钇、铒、镥配合物为单斜晶系, 空间群为P2_1/c, 配位数为8. 配合物均具有三维网状结构.     

η, h￠ \eta{^\prime} → πl+l- in a chiral unitary approach

The decays η, → π⁺π^- l ⁺ l ^- (with l = e,μ are investigated within a chiral unitary approach which combines the chiral effective Lagrangian with a coupled-channels Bethe-Salpeter equation. Predictions for the decay widths and spectra are given.