全文获取类型
收费全文 | 10493篇 |
免费 | 1764篇 |
国内免费 | 2044篇 |
专业分类
化学 | 8025篇 |
晶体学 | 136篇 |
力学 | 626篇 |
综合类 | 184篇 |
数学 | 1363篇 |
物理学 | 3967篇 |
出版年
2024年 | 14篇 |
2023年 | 232篇 |
2022年 | 341篇 |
2021年 | 404篇 |
2020年 | 487篇 |
2019年 | 474篇 |
2018年 | 371篇 |
2017年 | 419篇 |
2016年 | 561篇 |
2015年 | 571篇 |
2014年 | 621篇 |
2013年 | 869篇 |
2012年 | 806篇 |
2011年 | 912篇 |
2010年 | 688篇 |
2009年 | 648篇 |
2008年 | 734篇 |
2007年 | 621篇 |
2006年 | 586篇 |
2005年 | 539篇 |
2004年 | 442篇 |
2003年 | 366篇 |
2002年 | 418篇 |
2001年 | 325篇 |
2000年 | 294篇 |
1999年 | 238篇 |
1998年 | 181篇 |
1997年 | 130篇 |
1996年 | 153篇 |
1995年 | 115篇 |
1994年 | 132篇 |
1993年 | 100篇 |
1992年 | 75篇 |
1991年 | 95篇 |
1990年 | 91篇 |
1989年 | 42篇 |
1988年 | 40篇 |
1987年 | 30篇 |
1986年 | 34篇 |
1985年 | 39篇 |
1984年 | 15篇 |
1983年 | 18篇 |
1982年 | 8篇 |
1981年 | 8篇 |
1980年 | 4篇 |
1979年 | 2篇 |
1971年 | 1篇 |
1957年 | 3篇 |
1936年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 187 毫秒
21.
22.
ZhongJunMA XianLI YangLU ChengWANG QiTaiZHENG 《中国化学快报》2003,14(6):594-596
A novel cycloartane,named sphaerophysone A,9,19-cycloart-7β,24β,25-triol-1-en-3-one,was isolated from the ethanol extract of Sphaerophysa salsula DC.The structure was elucidated on the basis of spectral evidences and confirmed by X-ray analysis,the stereochemistry of the compound was also defined by X-ray analysis. 相似文献
23.
Chengzhi Qi Mingyang Wang Qihu Qian Jianjie Chen 《Moscow University Mechanics Bulletin》2008,63(5):113-121
The formation mechanisms for the structural hierarchy in geological media are discussed. It is shown that the formation of such a hierarchy is caused by certain external and internal circumstances. The first ones consist in the fact that, because of external actions, the Earth’s poles continuously execute the translational and rotational motions responsible for a regular structure of rock fracture and for the appearance of the scale factor √2. The second ones consist in the fact that, under the action of many random factors and because of external actions, during the formation of geological media there appear dissipative structures and, hence, some self-similar fractal structures are formed. 相似文献
24.
25.
Xiao Qi ZHENG Yong Hui WANG Qing Xiang GUO* Li YANG You Cheng LIU Department of Chemistry University of Science Technology of China Hefei National Laboratory of Applied Organic Chemistry Lanzhou University Lanzhou 《中国化学快报》2003,(8)
As artificial enzymes, the binding constants of cyclodextrins (CDs) and their substrates are expected to be high1. For this purpose, many kinds of bridged cyclodextrin dimers2 whose two cyclodextrins are linked by various spacers have been constructed. It was of interest to make the dimers, whose binding constants would exceed 108dm3/mol3. Up to date, the bridged cyclodextrin dimers have been extensively studied as enzyme models and as molecular receptors4-6. Recently, we synthesized a brid… 相似文献
26.
Qi Wang Huaxiang Yang Zhiqiang Fan Hong Xu 《Journal of polymer science. Part A, Polymer chemistry》2004,42(5):1093-1099
Ethylisobutylaluminoxane (EBAO) and its analogues were synthesized by a reaction between an triethylaluminum (Et3Al)/triisobutylaluminum (i‐Bu3Al) mixture and 4‐fluorobenzeneboronic acid, phenylboronic acid, or n‐butaneboronic acid and subsequent hydrolysis with water. They were used as cocatalysts in ethylene polymerization catalyzed by an iron complex {[(ArN?C(Me))2C5H3N]FeCl2, where Ar is 2,6‐diisopropylphenyl}. Polyethylene with a high molecular weight and a narrow molecular weight distribution was prepared with modified EBAOs, and the performance of the iron complex at high polymerization temperatures was greatly improved. The activators for the iron complex also affected the polymerization activity and the molecular weight of the resultant polyethylene. It was suggested that the stereo and electronic effects of the substitute groups of aluminoxane contributed to the improved performance of the new activators. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 1093–1099, 2004 相似文献
27.
Raymond Mackay Jie Zhang Qi Wu Yuzhuo Li 《Colloids and surfaces. A, Physicochemical and engineering aspects》2004,250(1-3):343-348
The longitudinal relaxation times (T1) of water in concentrated silica and alumina slurries were measured as a function of solids content. It was shown that the results could be fit very well with a two-phase fast-exchange model between free and surface-bound water. As expected, values of T1 for bound water were in the order of 20–2000 times lower than that for free water, indicating a higher effective viscosity of the surface-bound water. The strength of the interaction depended on the particular surface, and all of the aluminas examined interacted more strongly with water than the two silicas studied, which themselves differed considerably. The chemical mechanical polishing (CMP) removal rate of tantalum by silica slurries was shown to be directly correlated with the interaction parameters, derived from the NMR relation times rather than with total surface hydroxyl group concentration. 相似文献
28.
29.
30.
ZHANG Lin-bo LIU Xiao-hua JIANG Yuan GUO Ping SHA Li-jin LI Yu 《高等学校化学研究》2006,22(2):139-144
After establishing hemi-Parkinsonian rat models, the relationships between neuron death and the expression of several proteins, such as c-Fos, GFAP, GDNF, NF-κB and some cytokines were determined. Therapeutics experiments with notoginsenoside-Rg1 were carried out. The research results show that the expressions of GFAP, NF-Kκ and c-Fos will obviously increase in the lesion side of the striatum and the expression of GDNF will decrease, which implies that the signal transduction pathway may participate in the apoptosis in neurons. The levels of some cytokines such as TNF-α, IL-1β in the striatum of PD rat models increased compared to those of normal rats. The results of the therapeutics experiments show that notoginsenoside-Rg1 may repress the immune inflammation response and regulate the immune function through the neuro-immune molecular network. Therefore, notoginsenoside-Rg1 can be used as an effective drug for anti-oxidation and anti-inflammation, and can be used in the therapy of Parkinson's disease(PD). 相似文献